Startseite Investigation of polymers pyrolysis in a solid-gas conical spouted bed: CFD simulation
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Investigation of polymers pyrolysis in a solid-gas conical spouted bed: CFD simulation

  • Sobhan Jafari , Hadi Soltani EMAIL logo und Mortaza Gholizadeh
Veröffentlicht/Copyright: 3. April 2024
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Abstract

The hydrodynamics of a conical spouted bed was simulated utilizing the Eulerian–Eulerian Two-Fluid Model (TFM) incorporating a kinetic theory of granular flows. The simulations were confirmed with experimental data. To accurately examine the pyrolysis process, the hydrodynamics of the solid bed as well as the heat transfer inside it were analysed separately by considering a precise synthetic model. The effects of gas velocity, particle size, bed length, and temperature were thoroughly investigated. The results indicated that the amount of relative standard deviation increases with an increase in the inlet velocity into the bed. This amount of deviation at the inlet velocity (0.6 m/s for tar and gas flow to its maximum value of 9.1 and 9.4) is not desirable in product production and should be modified so that the amount of gas flow increases and the tar produced reaches the minimum possible amount. Also, the graphs of the relative standard deviation in terms of temperature indicate that the increase in temperature from 730 to 950 K is associated with a relatively smaller fluctuation of the relative standard deviation so that at the temperature of 730 K, it is 7.2 % for tar and 6.4 % for gas flow, while at temperature of 950 K, it is 6.5 % for wire and 6.8 % for gas flow. Finally, the results determined that small-diameter particles have a more significant fountain height and also higher velocity in the spout section.


Corresponding author: Hadi Soltani, Department of Chemical Engineering, Faculty of Engineering, University of Maragheh, P.O. Box: 55181-83111, Maragheh, Iran, E-mail:

  1. Research ethics: Not applicable.

  2. Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  3. Competing interests: The authors state no conflict of interest.

  4. Research funding: None declared.

  5. Data availability: Not applicable.

Nomenclature

d s

The diameter of the solid particles

g

The gravitational acceleration

g 0,ss

The lateral distribution function

K fs and K sf

The momentum exchange coefficient between fluid phase f and solid phase s

k Θs

The diffusion coefficient

P

The static pressure shared by both phases

P s

The solid pressure source term

S s

The solid phase source term

v q

The velocity of phase q

α q

The volume fraction of phase q

θ ss

The coefficient of restitution

Θ s

The granular temperature

∇Θ s

The collisional dissipation of energy

λ q

The bulk viscosity of phase q

μ q

The shear viscosity of phase q

μ s,kin

The kinetic viscosity

ρ q

The density of phase q

τ

The phase stress-strain tensor

Φ fs

The momentum transfers due to heterogeneous gas−solid reactions

Indices

f

stand for fluid phase

s

stand for solid phase

References

[1] S. Budsaereechai, A. J. Hunt, and Y. Ngernyen, “Catalytic pyrolysis of plastic waste for the production of liquid fuels for engines,” RSC Adv., vol. 9, no. 10, pp. 5844–5857, 2019, https://doi.org/10.1039/c8ra10058f.Suche in Google Scholar PubMed PubMed Central

[2] R. Miandad, M. A. Barakat, A. S. Aburiazaiza, M. Rehan, and A. S. Nizami, “Catalytic pyrolysis of plastic waste: a review,” Process Saf. Environ. Prot., vol. 102, pp. 822–38, 2016. https://doi.org/10.1016/j.psep.2016.06.022.Suche in Google Scholar

[3] I. Barbarias, G. Lopez, M. Artetxe, A. Arregi, J. Bilbao, and M. Olazar, “Valorisation of different waste plastics by pyrolysis and in-line catalytic steam reforming for hydrogen production,” Energy Convers. Manage., vol. 156, pp. 575–84, 2018, https://doi.org/10.1016/j.enconman.2017.11.048.Suche in Google Scholar

[4] M. Al-asadi, N. Miskolczi, and Z. Eller, “Pyrolysis-gasification of wastes plastics for syngas production using metal modified zeolite catalysts under different ratio of nitrogen/oxygen,” J Clean. Prod., vol. 271, p. 122186, 2020. https://doi.org/10.1016/j.jclepro.2020.122186.Suche in Google Scholar

[5] A. K. Awasthi, M. Shivashankar, and S. Majumder, “Plastic solid waste utilization technologies: a review,” IOP Conf. Ser. Mater. Sci. Eng., vol. 263, no. 2, p. 022024, 2017. https://doi.org/10.1088/1757-899x/263/2/022024.Suche in Google Scholar

[6] S.-H. Jung, M.-H. Cho, B.-S. Kang, and J.-S. Kim, “Pyrolysis of a fraction of waste polypropylene and polyethylene for the recovery of BTX aromatics using a fluidized bed reactor,” Fuel Process. Technol., vol. 91, no. 3, pp. 277–84, 2010. https://doi.org/10.1016/j.fuproc.2009.10.009.Suche in Google Scholar

[7] M. Artetxe, G. Lopez, M. Amutio, G. Elordi, M. Olazar, and J. Bilbao, “Operating conditions for the pyrolysis of poly-(ethylene terephthalate) in a conical spouted-bed reactor,” Ind. Eng. Chem. Res., vol. 49, no. 5, pp. 2064–9, 2010. https://doi.org/10.1021/ie900557c.Suche in Google Scholar

[8] J. M. Saad, M. A. Nahil, and P. T. Williams, “Influence of process conditions on syngas production from the thermal processing of waste high density polyethylene,” J. Anal. Appl. Pyrol., vol. 113, pp. 35–40, 2015. https://doi.org/10.1016/j.jaap.2014.09.027.Suche in Google Scholar

[9] G. Lopez, M. Artetxe, M. Amutio, J. Bilbao, and M. Olazar, “Thermochemical routes for the valorization of waste polyolefnic plastics to produce fuels and chemicals. A review,” Renew. Sustain. Energy Rev., vol. 73, pp. 346–68, 2017. https://doi.org/10.1016/j.rser.2017.01.142.Suche in Google Scholar

[10] M. S. Qureshi, et al.., “Pyrolysis of plastic waste: opportunities and challenges,” J. Anal. Appl. Pyrol., vol. 152, p. 104804, 2020. https://doi.org/10.1016/j.jaap.2020.104804.Suche in Google Scholar

[11] H. Sun, G. Bao, S. Yang, J. Hu, and H. Wang, “Numerical investigation of the reactive gas–solid characteristics in biomass fast pyrolysis of conical spouted reactor equipped with draft tube,” AIChE J., vol. 69, no. 11, p. e18200, 2023. https://doi.org/10.1002/aic.18200.Suche in Google Scholar

[12] O. Santiago, J. Alvarez, G. Lopez, M. Artetxe, J. Bilbao, and M. Olazar, “a Pyrolysis of plastic wastes in a fountain confned conical spouted bed reactor: Determination of stable operating conditions,” Energy Convers. Manage., vol. 229, p. 113768, 2021. https://doi.org/10.1016/j.enconman.2020.113768.Suche in Google Scholar

[13] E. Fernandez, et al.., “Role of temperature in the biomass steam pyrolysis in a conical spouted bed reactor,” Energy, vol. 238, p. 122053, 2022, https://doi.org/10.1016/j.energy.2021.122053.Suche in Google Scholar

[14] B. Hooshdaran, M. Haghshenasfard, S. H. Hosseini, M. N. Esfahany, G. Lopez, and M. Olazar, “CFD modeling and experimental validation of biomass fast pyrolysis in a conical spouted bed reactor,” J. Anal. Appl. Pyrol., vol. 154, p. 105011, 2021, https://doi.org/10.1016/j.jaap.2020.105011.Suche in Google Scholar

[15] T. Kawaguchi, M. Sakamoto, T. Tanaka, and Y. Tsuji, “Quasi-three-dimensional numerical simulation of spouted beds in cylinder,” Powder Technol., vol. 109, no. 1, pp. 3–12, 2000, https://doi.org/10.1016/s0032-5910(99)00222-3.Suche in Google Scholar

[16] Y. L. He, C. J. Lim, J. R. Grace, J. X. Zhu, and S. Z. Qzn, “Measurements of voidage profiles in spouted beds,” Can. J. Chem. Eng., vol. 72, no. 2, pp. 229–234, 1994a, https://doi.org/10.1002/cjce.5450720208.Suche in Google Scholar

[17] Y. L. He, S. Z. Qin, C. J. Lim, and J. R. Grace, “Particle velocity profiles and solid flow patterns in spouted beds,” Can. J. Chem. Eng., vol. 72, no. 4, pp. 561–568, 1994b, https://doi.org/10.1002/cjce.5450720402.Suche in Google Scholar

[18] L. Huilin, H. Yurong, L. Wentie, J. Ding, D. Gidaspow, and J. Bouillard, “Computer simulations of gas–solid flow in spouted beds using kinetic–frictional stress model of granular flow,” Chem. Eng. Sci., vol. 59, no. 4, pp. 865–878, 2004, https://doi.org/10.1016/j.ces.2003.10.018.Suche in Google Scholar

[19] M.A. José, M. Olazar, S. Alvarez, M. Izquierdo, and J. Bilbao, “Solid cross-flow into the spout and particle trajectories in conical spouted beds,” Chem. Eng. Sci., vol. 53, no. 20, pp. 3561–3570, 1998. https://doi.org/10.1016/s0009-2509(98)00170-5.Suche in Google Scholar

[20] C. R. Duarte, V. V. Murata, and M. A. S. Barrozo, “A study of the fluid dynamics of the spouted bed using CFD,” Brazil. J. Chem. Eng., vol. 22, no. 2, pp. 263–270, 2005. https://doi.org/10.1590/s0104-66322005000200014.Suche in Google Scholar

[21] S. Jalalifar, M. Ghiji, R. Abbassi, V. Garaniya, and K. Hawboldt, “Numerical modelling of a fast pyrolysis process in a bubbling fluidized bed reactor,” IOP Conf. Ser. Earth Environ. Sci., vol. 73, p. 012032, 2017, https://doi.org/10.1088/1755-1315/73/1/012032.Suche in Google Scholar

[22] S. M. Al-Salem, “Thermal pyrolysis of high density polyethylene (HDPE) in a novel fixed bed reactor system for the production of high value gasoline range hydrocarbons (HC),” Process Saf. Environ. Prot., vol. 127, pp. 171–179, 2019, https://doi.org/10.1016/j.psep.2019.05.008.Suche in Google Scholar

[23] W. Du, X. Bao, J. Xu, and W. Wei, “Computational fluid dynamics (CFD) modeling of spouted bed: Assessment of drag coefficient correlations,” Chem. Eng. Sci., vol. 61, no. 5, pp. 1401–1420, 2006, https://doi.org/10.1016/j.ces.2005.08.013.Suche in Google Scholar

[24] D. Gidaspow, Multiphase Flow and Fluidization: Continuum and Kinetic Theory Descriptions, San Diego, CA, Academic Press, 1994, pp. 1–488.10.1016/B978-0-08-051226-6.50005-4Suche in Google Scholar

[25] C. K. K. Lun, S. B. Savage, D. J. Jeffrey, and N. Chepurniy, “Kinetic theories for granular flow: inelastic particles in Couette flow and slightly inelastic particles in a general flow field,” J. Fluid Mech., vol. 140, pp. 223–256, 1984, https://doi.org/10.1017/s0022112084000586.Suche in Google Scholar

[26] X. L. Zhao, S. Q. Li, G. Q. Liu, Q. Song, and Q. Yao, “Flow patterns of solids in a two-dimensional spouted bed with draft plates: PIV measurement and DEM simulations,” Powder Technol., vol. 183, no. 1, pp. 79–87, 2008, https://doi.org/10.1016/j.powtec.2007.11.021.Suche in Google Scholar

Received: 2023-11-09
Accepted: 2024-03-16
Published Online: 2024-04-03

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