Band 38, Heft 2

Kinetics, as a fundamental requirement of nearly all industrial activities and engineering researches, plays a great role in leaching processes. Although there are many pieces of research on its application, there is not a clear pathway for investigating the kinetics of leaching and researchers usually follow different strategies in their studies. The conventional investigation techniques, which usually do not consider the mixed mechanisms and possibility of any change in the mechanism, normally include many calculations, plots, and inadequate capabilities to detect changes in the controlling mechanism of leaching. In this review, the main mathematical models of leaching and all possible scenarios are presented and discussed. The effect of various leaching parameters (including leaching agent, temperature, particle size, agitation, and solid to liquid ratio) on the rate of dissolution is summarized. Besides, two main approaches of rate determination step (single controlling mechanism and combined resistances method) are described and compared by reporting related equations and suitable examples. A technique to detect any changes in the leaching controlling mechanism is introduced and the alternatives to confirm the results are described. Additional models and equations were suggested for the cases that there is no agreement between data and the conventional models. Also, situations which are ignored in simple models (e.g., reversibility of the leaching reactions, adsorption and desorption of leached species, influence of charge and surface potential, existence of multiple reactants in the solid, galvanic effect, wide particle size distribution, etc.) to develop more legalistic models are discussed. Considering various possible mechanisms in the kinetics of leaching, equations are derived for industrial leaching reactors.

Any scientific behavior is best represented by nondimensional numbers. However, in many cases, for pneumatic conveying systems, dimensional equations are developed and used. In some cases, many of the nondimensional equations include Reynolds (Re) and Froude (Fr) numbers; they are usually defined for a limited range of materials and operating conditions. This study demonstrates that most of the relevant flow types, whether in horizontal or vertical pipes, can be better described by Re and Archimedes (Ar) numbers. Ar can also be used in hydraulic conveying systems. This paper presents many threshold velocities that are accurately defined by Re as a simple power function of Ar. Many particulate materials are considered by Ar, thereby linking them to a common behavior. Using various threshold velocities, a flow regime chart for horizontal conveying is presented in this paper.

A special attention is currently focused on the recovery of Au, Ag, Pt, Pd and Rh from both primary and secondary sources. From the wide range of sorbents that have been used in this respect, the required selectivity is proved only by the chelating polymers containing donor N, O and S atoms in their functional groups. This work presents the recent published researches on this topic, pointing out the capabilities of chelating sorbents based on organic synthetic polymers for a sustainable development. The chelating sorbents are differentiated and reviewed according to their synthesis strategy and compatibility with synthetic and real matrices. First, an overview on the novel functionalized polymers and impregnated resins with good selectivity for the recovery of most valuable precious metals from synthetic leach solutions is given. Subsequently, the performances of these materials in the selective and preconcentrative recovery of Au, Ag, Pt, Pd and Rh from simulated and real leachates are discussed. The viability of an integrated approach for the determination of precious metals from simulated solutions by solid phase spectrometry is highlighted. The transposition of chelating polymers’ potential in challenging technologies for precious metal recovery-reuse-recycling needs further research on directions that are proposed.

The economic value of bioethylene produced from bioethanol dehydration is remarkable due to its extensive usage in the petrochemical industry. Bioethylene is produced through several routes, such as steam cracking of hydrocarbons from fossil fuel and dehydration of bioethanol, which can be produced through fermentation processes using renewable substrates such as glucose and starch. The rise in oil prices, environmental issues due to toxic emissions caused by the combustion of fossil fuel and depletion of fossil fuel resources have led a demand for an alternative pathway to produce green ethylene. One of the abundant alternative renewable sources for bioethanol production is biomass. Bioethanol produced from biomass is alleged to be a competitive alternative to bioethylene production as it is environmentally friendly and economical. In recent years, many studies have investigated catalysts and new reaction engineering pathways to enhance the bioethylene yield and to lower reaction temperature to drive the technology toward economic feasibility and practicality. This paper critically reviews bioethylene production from bioethanol in the presence of different catalysts, reaction conditions and reactor technologies to achieve a higher yield and selectivity of ethylene. Techno-economic and environmental assessments are performed to further development and commercialization. Finally, key issues and perspectives that require utmost attention to facilitate global penetration of technology are highlighted.

In this review paper, a complete study and analysis of the research articles dealing with the removal of various organic and inorganic pollutants using solvent impregnated resins (SIR) is carried out. The method of impregnation, characterizations of prepared resin, and regeneration techniques of different SIRs for batch and continuous fixed bed columns are presented. The effects of different operating parameters (e.g., loading of solvent on the resin, dosage of adsorbent, initial solute concentration, pH, temperature, time, ionic strength) on the separation efficiency of SIR in the batch mode are discussed. Thermodynamic parameters (change in Gibbs free energy, enthalpy, and entropy) are tabulated from the data available in the literature, and if not given, then their values are calculated and presented. The influence of parameters (flow rate, bed height, pH, concentration of the solution, etc.) on the fixed bed column performance is analyzed. Design aspects of the column are also discussed, and the dimensions of fixed bed columns for industrial applications are proposed.