Volume 36, Issue 5

Mechanically stirred slurry tanks are utilized in several industries to perform various unit operations such as crystallization, adsorption, ion-exchange, suspensions polymerization, dispersion of solid particles, leaching and dissolution, and activated sludge processes. The major goal of this review paper is to critically and thoroughly analyse the different aspects of previous research works reported in the literature in the field of liquid-solid mixing. This paper sheds light on the advantages and limitations of various particle concentration measurement methods employed to assess the suspension quality and the extent of solid suspensions in slurry reactors. Attempts are being made to identify and compare various mathematical models and methods to quantify particle dispersion and distribution in slurry reactors. It has been shown that various factors such as geometric configurations, agitation conditions, and physical characteristics of liquid and solid have pronounced influence on local suspension quality and power consumption. Computational fluid dynamics (CFD) modeling can be extremely useful in assessing the suspension of solid particles in slurry tanks. A critical review of different scale-up procedures employed for solid suspension and distribution in liquid-solid systems is presented as well. The findings of this review paper can be useful for future research works in liquid-solid mixing.

Ceramic-based photocatalytic membrane reactors (cPMRs) are becoming increasingly popular among researchers and will soon be seen on the water/wastewater-treatment market. This review provides a thorough analysis of the available data on cPMRs fabricated to date based on coating method, support and coating materials, membrane design, pore size and model compounds used to evaluate process efficiency and light source. While all of the studies describe cPMR preparation in great detail, over half do not provide any information about their performance. The rest used various dyes that can be conveniently detected by spectrophotometry/fluorimetry, or micropollutants that require analytical equipment available only in specialized laboratories. In addition, cPMRs are viewed as a convenient way of incorporating a photocatalyst on an inert surface assuming that the surface itself, i.e. the membrane, does not participate in the treatment process. A unified test for cPMR performance should be developed and implemented for all cPMRs that have the potential for commercialization. There is a need for standardization in cPMR testing; only then can the true performance of cPMRs be evaluated and compared. Such testing will also answer the question of whether the cPMR membrane is indeed an inert support or an active part of the treatment process.

The surge of knowledge among researchers pertaining to the excellent properties of graphene has led to the utilisation of graphene as a reinforced filler in polymer composites. Different methods of graphene preparation, either bottom-up or top-down methods, are important requirements of starting materials in producing reinforced properties in the composites. The starting graphene material produced is either further functionalised or directly used as a filler in thermoset polymer matrixes. An effective interaction between graphene and polymer matrixes is important and can be achieved by incorporating graphene into a thermoset polymer matrix through melt mixing, solution mixing or in situ polymerisation processes. In addition, by taking into consideration the importance of green and sustainable composites, the details of previous work on graphene reinforced bio-thermoset polymer matrixes is discussed. The resultant mechanical and thermal properties of the composites were associated to the chemical interaction between the graphene filler and a thermoset matrix. Exploration for further variations of graphene polymer composites are discussed by taking the reinforcement properties in graphene composite as a starting point.