Band 1, Heft 2

The structure of a heterogeneous system influences diffusion of thermal neutrons. The thermal-neutron absorption in grained media is considered in the paper. A simple theory is presented for a two-component medium treated as grains embedded in the matrix or as a system built of two types of grains (of strongly differing absorption cross-sections). A grain parameter is defined as the ratio of the effective macroscopic absorption cross-section of the heterogeneous medium to the absorption cross-section of the corresponding homogeneous medium (consisting of the same components in the same proportions). The grain parameter depends on the ratio of the absorption cross-sections and contributions of the components and on the size of grains. The theoretical approach has been verified in experiments on prepared dedicated models which have kept required geometrical and physical conditions (silver grains distributed regularly in Plexiglas). The effective absorption cross-sections have been measured and compared with the results of calculations. A very good agreement has been observed. In certain cases the differences between the absorption in the heterogeneous and homogeneous media are very significant. A validity of an extension of the theoretical model on natural, two-component, heterogeneous mixtures has been tested experimentally. Aqueous solutions of boric acid have been used as the strongly absorbing component. Fine- and coarse-grained pure silicon has been used as the second component with well-defined thermal-neutron parameters. Small and large grains of diabase have been used as the second natural component. The theoretical predictions have been confirmed in these experiments.

Pseudoelasticity caused by pseudotwinning in short-range ordered In-Pb alloys (6, 8 and 11.6 at. % Pb) is studied in the temperature range 0.48–180 K. The mechanical hysteresis parameters, namely, the thermodynamic stress τT which provides the reversibility of plastic deformation and the frictional stress τf which characterizes the resistance offered by crystal lattice and its defects to twin boundaries motion are estimated. It is found that athermal processes determine the reversible deformation: the mechanical parameters τT and τf do not depend on temperature and strain rate. The stress τT increases and the stress τf decreases with increasing Pb content. One of the main conditions of the exhibition of superelasticity is the fulfillment of the inequality τT>τf.

The problem of determining the harmonic content in the voltage that appears on a superconducting wire carrying cosine-like AC current was resolved theoretically, using two approaches. First, the Fourier components of the voltage spectrum were found by numerical integration. Importance of individual terms was established, leading to two conclusions: a) it is the cosine component of the 3rd harmonic that represents the bulk of harmonic distortion, b) for the practical purposes it is sufficient to consider higher harmonics with n ≤ 7. Then, the analytical formulas were derived. While for the sine components a general expression containing an infinite series was found, closed-form formulas were derived for the cosine components of the harmonics 1, 3, 5, 7. Consequences of the results to the experimental technique used to study the AC transport properties of superconductors are discussed.

This paper attempts to answer Lyman's question (1990) on the non-uniqueness in defining the 3D measure of the boundary vorticity-creation rate. Firstly, a straightforward analysis of the vorticity equation introduces a definition of a general vorticity flux-density tensor and its ‘effective’ part. The approach is strictly based on classical field theory and is independent of the constitutive structure of continuous medium. Secondly, the fundamental question posed by Lyman dealing with the ambiguity of the 3D measure of the boundary vorticity-creation rate for incompressible flow is discussed. It is shown that the original 3D measure (for an incompressible Newtonian fluid defined by Panton 1984), which is reminiscent of an analogy to Fourier's law, is in its character ‘effective’ and plays a crucial role in the prognostic vorticity transport equation. The alternative 3D measure proposed by Lyman includes, on the other hand, a ‘non-effective’ part, which plays a role in the local determination of the ‘effective’ measure as well as in a certain diagnostic integral boundary condition.

The article presents the results of a study of characteristic X-ray spectra of free atoms by means of a new simple technique. A pulsed electron beam was used for evaporation and to create inner-shell vacancies in free atoms of metals. The spectra were obtained with the help of an X-ray monochromator which allowed precise comparison between the free-atoms spectra and corresponding solid-state spectra. The shifts of the peaks were measured and found to be in the range Δλ/λ≈10−5–10−4. The K-, L- and M-series spectra were studied. A number of the free-atoms spectra revealed structure which was not resolved in the solid-state spectra and which is of interest for atomic structure calculation applications. This electron beam technique for the investigation of X-ray characteristic spectra of free atoms can be used for the refinement of X-ray wavelength standards.

We study properties of entangled systems in the (mainly non-relativistic) second quantization formalism. This is then applied to interacting and non-interacting bosons and fermions and the differences between the two are discussed. We present a general formalism to show how entanglement changes with the change of modes of the system. This is illustrated with examples such as the Bose condensation and the Unruh effect. It is then shown that a non-interacting collection of fermions at zero temperature can be entangled in spin, providing that their distances do not exceed the inverse Fermi wavenumber. Beyond this distance all bipartite entanglement vanishes, although classical correlations still persist. We compute the entanglement of formation as well as the mutual information for two spin-correlated electrons as a function of their distance. The analogous, non-interacting collection of bosons displays no entanglement in the internal degrees of freedom. We show how to generalize our analysis of the entanglement in the internal degrees of freedom to an arbitrary number of particles.

The energy spectra of traps in NaCl crystals have been studied in detail by the method of thermoluminescence. Crystals of NaCl were undoped but treated thermally in different ways. The activation energies of traps form a single oscillator series, E n=ℏωTL(n+1/2), ℏωTL=903 cm-1. Contrary to other previously studied crystals with complex lattices, the corresponding line ℏωRam=ℏωTL was not found in Raman spectra of NaCl. It is assumed that the oscillator rule is governed by the polaron nature of traps. The trap activation energy is determined by the vibration level from which the transition of the charge carrier to the excited luminescence centre is made possible and depends on the distance between these centres.

An “almost diagonal” reduced density matrix (in coordinate representation) is usually a result of environment induced decherence and is considered the sign of classical behavior. We show that the proton of a ground state hydrogen atom can indeed possess such a density matrix. This example demonstrates that the “almost diagonal” structure may be derived from an interaction with a low number of degrees of freedom which play the role of the environment. We also show that decoherence effects in our example can only be observed if the interaction with the measuring device is significantly faster than the interaction with the environment (the electron). In the opposite case, when the interaction with the environment is significant during the measurement process, coherence is maintained. Finally, we propose a neutron scattering experiment on cold He atoms to observe decoherence which shows up as an additional positive contribution to the differential scattering cross section. This contribution is inversely proportional to the bombarding energy.

Thermodynamic stability conditions for nanoparticles (resulting from non-negativity of the second variation of the free energy) have been analyzed for two cases: (i) a nonvolatile nanosized particle with the size-dependent surface tension; (ii) the limiting case of larger objects when the surface tension takes its macroscopic value. It has been shown that the mechanical stability of a nanoparticle, i.e. its stability relative to the volume fluctuations, is defined by an interplay between the excess (“surface”) free energy and the volumetric elastic energy. According to the results obtained, noble gas clusters and metal nanoparticles satisfy the mechanical stability condition. At the same time, water nanodrops, as well as nanoparticles presented by nonpolar organic molecules, correspond to the stability limit. Among the investigated systems, the stability condition is not carried out for n-Pentane clusters.

Based on a solution of the polymer excluded volume problem, a technique is proposed to estimate some parameters at the isotropic-nematic liquid crystal phase transition (the product of the volume fraction of hard sticks and the ratio of the stick length, L, to its diameter, D; the maximum value of this ratio at which one cannot regard the stick as hard). The critical exponents are estimated. The transition of a swelling polymer coil to ideal is revealed as the polymerization degree of a macromolecule increases. The entanglement concentration obtained agrees with experimental data for polymers with flexible chains. The number of monomers between neighbor entanglements is assumed to be the ratio L/D. A comparison of the theory with other ones and recent experimental data is made.