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Calorimetric investigations of the two ternary systems Al–Sn–Zn and Ag–Sn–Zn

  • Sabine Knott EMAIL logo , Hans Flandorfer and Adolf Mikula
Published/Copyright: December 9, 2021
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 96 Issue 1

Abstract

Using a Calvet type calorimeter, the enthalpy of mixing in the two ternary systems, Al –Sn–Zn and Ag–Sn–Zn was determined at 973 K. In the Al –Sn –Zn system, the investigations were carried out along three cross-sections with constant molar ratios of Sn : Zn = 1 : 2, 1 : 1 and 2 : 1 and an aluminium content between 0 and 100 at.%. For the Ag–Sn –Zn system, the measurements have been done at constant molar ratios of Ag : Sn = 1 : 3, 1 : 1 and 3 : 1 with zinc contents between 0 and 50 at.%. The substitutional solution model of Redlich – Kister according to the CALPHAD method was used for a least-square fit of the experimental data in order to get an analytical expression for the integral enthalpy of mixing. The ternary extrapolation models of Kohler, Muggianu, and Toop were applied on the binary data to compare measured, fitted, and extrapolated values.

Keywords: Al–Sn – Zn; Ag–Sn – Zn; Lead-free; Calorimetry
Sabine Knott, Mag. Währingerstr. 42, A-1090 Vienna, Austria Tel.: +43 142 775 2668 Fax: +43 142 775 2679

  1. The authors thank the Austrian Science Foundation (FWF) for financial support under the grant No. P 16491-N11.

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Received: 2004-05-18
Accepted: 2004-07-27
Published Online: 2021-12-09

© 2005 Carl Hanser Verlag, München

Articles in the same Issue

  1. Frontmatter
  2. Editorial
  3. Editorial
  4. Articles BBasic
  5. Interdiffusion, Kirkendall effect, and Al self-diffusion in iron–aluminium alloys
  6. Permanent magnet alloys based on Sm2Co17; phase evolution in the quinary system Sm–Zr–Fe–Co–Cu
  7. A unified equation for the viscosity of pure liquid metals
  8. Calorimetric Study of Mg2Zn3
  9. Calorimetric investigations of the two ternary systems Al–Sn–Zn and Ag–Sn–Zn
  10. Articles AApplied
  11. Precipitation of the β-phase in Al–Mg alloys
  12. Mechanical properties of saffil fiber reinforced Zinc–Aluminium alloy (ZA 27) produced by pressure die casting
  13. Deformation and fracture mechanisms of Al2O3/Nb/Al2O3 composites under compression
  14. Kinetics and dynamics of hot deformation of OFHC copper in extended temperature and strain rate ranges
  15. Mechanism and kinetics of aging of high-strength Cu-5 wt.% Ni-2.5 wt.% Ti
  16. Microstructural evolution of Al–Ni–Y powders with different sizes
  17. Thermodynamic investigations of Bi–Cd, In–Pb, and Ni–Pd liquid alloys
  18. Instructions for authors
  19. Notifications/Mitteilungen
  20. Richtlinien für autoren
  21. Personal/ Personelles
  22. Press / Presse
  23. Conferences /Konferenzen
https://doi.org/10.3139/ijmr-2005-0006
Keywords for this article
Al–Sn – Zn; Ag–Sn – Zn; Lead-free; Calorimetry

Articles in the same Issue

  1. Frontmatter
  2. Editorial
  3. Editorial
  4. Articles BBasic
  5. Interdiffusion, Kirkendall effect, and Al self-diffusion in iron–aluminium alloys
  6. Permanent magnet alloys based on Sm2Co17; phase evolution in the quinary system Sm–Zr–Fe–Co–Cu
  7. A unified equation for the viscosity of pure liquid metals
  8. Calorimetric Study of Mg2Zn3
  9. Calorimetric investigations of the two ternary systems Al–Sn–Zn and Ag–Sn–Zn
  10. Articles AApplied
  11. Precipitation of the β-phase in Al–Mg alloys
  12. Mechanical properties of saffil fiber reinforced Zinc–Aluminium alloy (ZA 27) produced by pressure die casting
  13. Deformation and fracture mechanisms of Al2O3/Nb/Al2O3 composites under compression
  14. Kinetics and dynamics of hot deformation of OFHC copper in extended temperature and strain rate ranges
  15. Mechanism and kinetics of aging of high-strength Cu-5 wt.% Ni-2.5 wt.% Ti
  16. Microstructural evolution of Al–Ni–Y powders with different sizes
  17. Thermodynamic investigations of Bi–Cd, In–Pb, and Ni–Pd liquid alloys
  18. Instructions for authors
  19. Notifications/Mitteilungen
  20. Richtlinien für autoren
  21. Personal/ Personelles
  22. Press / Presse
  23. Conferences /Konferenzen
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