Enhanced Dispersive Mixing in Twin-Screw Extrusion via Extension-Dominated Static Mixing Elements of Varying Contraction Ratios
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H. Chen
Abstract
Twin screw extruders (TSE) are widely used in polymer blending and compounding operations, since the relatively high stresses they impart on melts and controllable residence times make them highly suitable for mixing operations. However, the mixing action in the industry-standard kneading blocks (KB) is shear-dominated and shear flows are inefficient for dispersive mixing compared with extensional flows. A novel static extensional mixing element (EME) was developed recently by our group with the objective of providing extension-dominated flow during blending and compounding. Dispersive mixing in the EME is provided by flow through stationary hyperbolic converging-diverging (C-D) channels placed along the screw. The improvements in dispersive mixing for immiscible blends using EMEs with wide hyperbolically channels, i.e., low contraction ratios, has been proved. In this work, we begin by performing computational investigations of more extreme contraction geometries to determine the design flexibility limits for the EME. The contractions again showed more extension-dominated flow patterns than the original EME, the drawback being the obvious increase in the pressure drop. However, at extremely high contraction ratios, the entry angle is so shallow that recirculation zones appear at the entrance, which are undesirable, implying that there are geometrical limits above which the EME ceases to be an effective dispersive mixer. Next, experimental validation on the EMEs with different degrees of aggressiveness of the C-D channel were performed and dramatic improvement in droplet breakup (dispersive mixing) in case of immiscible blends is clearly observed at all viscosity ratios and with increasing degree of EME aggressiveness.
References
Bouquey, M., Loux, C., Muller, R. and Bouchet, G., “Morphological Study of Two-Phase Polymer Blends during Compounding in a Novel Compounder on the Basis of Elongational Flows”, J. Appl. Polym. Sci., 119, 482–490 (2011) 10.1002/app.32645Search in Google Scholar
Bourry, D., Khayat, R. E., Ultracki, L. A., Godbille, F., Picot, J. and Luciani, A., “Extensional Flow of Polymeric Dispersions”, Polym. Eng. Sci., 39, 1072–1086 (1999) 10.1002/pen.11495Search in Google Scholar
Carson, S. O., Covas, J. A. and Maia, J. M., “A New Extensional Mixing Element for Improved Dispersive Mixing in Twin-Screw Extrusion, Part 1: Design and Computationcal Validation”, Adv. Polym. Tech., 36, 455–465 (2017) 10.1002/adv.21627Search in Google Scholar
Carson, S. O., Covas, J. A. and Maia, J. M., “A New Extensional Mixing Element for Improved Dispersive Mixing in Twin-Screw Extrusion, Part 2: Experimental Validation for Immiscible Polymer Blends”, Adv. Polym. Tech., 37, 167–175 (2018) 10.1002/adv.21653Search in Google Scholar
Cho, S., Hong, J. S., Lee, S. J., Ahn, K. H., Covas, J. A. and Mai, J. M., “Morphology and Rheology of Polypropylene/Polystyrene/Clay Nanocomposites in Batch and Continuous Melt Mixing Processes”, Macromol. Mat. Eng., 296, 341–348 (2011) 10.1002/mame.201000194Search in Google Scholar
Covas, J. A., Carneiro, O. S., Costa, P., Machado, A. V. and Maia, J. M., “Online Monitoring Techniques for Studying Evolution of Physical, Rheological and Chemical Effects along The Extruder”, Plast. Rubber Compos., 33, 55–61 (2004) 10.1179/146580104225018300Search in Google Scholar
Covas, J. A., Carneiro, O. S., Maia, J. M., Filipe, S. A. and Machado, A. V., “Evolution of Chemistry, Morphology and Rheology of Various Polymer Systems along a Twin-Screw Extruder”, Can. J. Chem. Eng., 80, 1065–1074 (2002) 10.1002/cjce.5450800608Search in Google Scholar
Covas, J. A., Maia, J. M., Machado, A. V. and Costa, P., “On-Line Rotational Rheometry for Extrusion and Compounding Operations”, J. Non-Newtonian Fluid Mech., 148, 88–96 (2008) 10.1016/j.jnnfm.2007.04.009Search in Google Scholar
Covas, J. A., Nobrega, J. M. and Maia, J. M., “Rheological Measurements along an Extruder with an On-Line Capillary Rheometer”, Polym. Test., 19, 165–176 (2000) 10.1016/S0142-9418(98)00086-5Search in Google Scholar
Cox, W., Merz, E., “Correlation of Dynamic and Steady Flow Viscosities”, J. Polym. Sci., 28, 619–622 (1958) 10.1002/pol.1958.1202811812Search in Google Scholar
Filipe, S., Cidade, M. T., Wilhelm, M. and Maia, J. M., “Evolution of the Morphological and Rheological Properties along the Extruder Length for Compatibilized Blends of a Commercial Liquid-Crystalline Polymer and Polypropylene”, J. Appl. Polym. Sci., 99, 347–359 (2006) 10.1002/app.22393Search in Google Scholar
Garcia, M., van Vliet, G., Jain, S., Schrauwen, B., Sarkissov, A., van Zyl, W. and Boukamp, B., “Polypropylene/SiO2 Nanocomposites with Improved Mechanical Properties”, Rev. Adv. Mater. Sci., 6, 169–175 (2004)Search in Google Scholar
Grace, H. P., “Dispersion Phenomena in High Viscosity Immiscible Fluid Systems and Application of Static Mixers as Dispersion Devices in Such Systems”, Chem. Eng. Commun., 14, 225–277 (1982) 10.1080/00986448208911047Search in Google Scholar
Guido, S., “Shear-Induces Droplet Deformation: Effects of Confined Geometry and Viscoelasticity”, Curr. Opin. Colloid Interface Sci., 16, 61–70 (2011) 10.1016/j.cocis.2010.12.001Search in Google Scholar
Hyun, G. O., Doo, H. K., Kyung, H. A., Seung, J. L. and Maia, J. M., “Effect of Organoclay as a Compatibilizer in Poly (lactic acid) and Natural Rubber Blends”, Eur. Polym. J., 76, 216–227 (2016) 10.1016/j.eurpolymj.2016.01.042Search in Google Scholar
Ibarra-Gómez, R., Muller, R., Bouquey, M., Rondin, J., Serra, C. A., Hassouna, F., Mouedden, Y. E., Toniazzo, V. and Ruch, D., “Processing of Nanocomposites PLA/Graphite Using a Novel Elongationcal Mixing Device”, Polym. Eng. Sci., 55, 214–222 (2014) 10.1002/pen.23869Search in Google Scholar
Khayat, R. E., Luciani, A., Utracki, L. A., Godbille, F. and Picot, J., “Influence of Shear and Elongation on Drop Deformation in Convergent-Divergent Flows”, Int. J. Multiphase Flow, 26, 17–44 (2000) 10.1016/S0301-9322(98)00083-4Search in Google Scholar
Luciani, A., Utracki, L. A., “The Extensional Flow Mixer, EFM”, Int. Polym. Proc., 11, 299–309 (1996) 10.3139/217.960299 Search in Google Scholar
Manas-Zloczower, I.: Mixing and Compounding of Polymers: Theory and Practice; Hanser, Cincinnati, OH (2009) 10.3139/9783446433717Search in Google Scholar
Milliken, W. J., Leal, L. G., “Deformation and Breakup of Viscoelastic Drops in Planar Extensional Flows”, J. Non-Newtonian Fluid Mech., 40, 355–379 (1991) 10.1016/0377-0257(91)87018-SSearch in Google Scholar
Rauwendaal, C., “New Development in Mixing and Screw Design”, Plastics, Additives and Compounding, 10, 32–36 (2008), (08) 70227–7 10.1016/S1464-391XSearch in Google Scholar
Rauwendaal, C., Osswald, T. A., Gramann, P. and Davis, B., “Design of Dispersive Mixing Devices”, Int. Polym. Proc., 14, 28–34 (1999) 10.3139/217.1524Search in Google Scholar
Rauwendaal, C., Osswald, T. A., Tellez, G. and Gramann, P. J., “Flow Analysis in Screw Extruders-Effect of Kinematic Conditions”, Int. Polym. Proc., 13, 327–333 (1998) 10.3139/217.980327Search in Google Scholar
Rondin, J., Bouquey, M., Muller, R., Serra, C. A., Martin, G. and Sonntag, P., “Dispersive Mixing Efficiency of an Elongational Flow Mixer on PP/EPDM Blends: Morphological Analysis and Correlation with Viscoelastic Properties”, Polym. Eng. Sci., 54, 1444–1457 (2013) 10.1088/1742-6596/774/1/012026Search in Google Scholar
Senouci, A., Smith, A. C., “An Experimental Study of Food Melt Rheology. I. Shear Viscosity Using a Slit Die Viscometer and a Capillary Rheometer”, Rheol. Acta, 27, 546–554 (1988) 10.1007/BF01329355Search in Google Scholar
Tokihisa, M., Yakemoto, K., Sakai, T., Utracki, L. A., Sepehr, M., Li, J. and Simard, Y., “Extensional Flow Mixer for Polymer Nanocomposites”, Polym. Eng. Sci., 46, 1040–1050 (2006) 10.1002/pen.20542Search in Google Scholar
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Articles in the same Issue
- Contents
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- Review Article
- Fluid-Powered Projectile-Assisted Injection Molding: Principles and Developments
- Regular Contributed Articles
- Correlations between the Hysteresis Parameters Determining the Rolling Resistance in Rubber Composites
- Global Modeling for Single Screw Extrusion of Viscoplastics
- Enhanced Dispersive Mixing in Twin-Screw Extrusion via Extension-Dominated Static Mixing Elements of Varying Contraction Ratios
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- PPS News
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Articles in the same Issue
- Contents
- Contents
- Review Article
- Fluid-Powered Projectile-Assisted Injection Molding: Principles and Developments
- Regular Contributed Articles
- Correlations between the Hysteresis Parameters Determining the Rolling Resistance in Rubber Composites
- Global Modeling for Single Screw Extrusion of Viscoplastics
- Enhanced Dispersive Mixing in Twin-Screw Extrusion via Extension-Dominated Static Mixing Elements of Varying Contraction Ratios
- EPDM-G-GMA Toughening of Straw/Polypropylene Composites: Mechanical Properties, Thermal Stability and Rheological Properties
- In Situ Assembly of LDPE/PA6 Multilayer Structure by Stirring
- Modeling and Estimation of the Pressure and Temperature dependent Bulk Density of Polymers
- Influence of ABS Type and Compatibilizer on the Thermal and Mechanical Properties of PC/ABS Blends
- Analysis of Self-Reinforced Mechanism of Over-Molding Polypropylene Parts
- Grafting of Biodegradable Polyesters on Cellulose for Biocomposites: Characterization and Biodegradation
- PPS News
- PPS News