Startseite Preparation and Characterization of Hydrophobic Flat Sheet Membranes Based on a Recycled Polymer
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Preparation and Characterization of Hydrophobic Flat Sheet Membranes Based on a Recycled Polymer

  • H. Ajari , A. Zrelli , B. Chaouachi und M. Pontié
Veröffentlicht/Copyright: 19. Juni 2019
Veröffentlichen auch Sie bei De Gruyter Brill

Abstract

In this work, we used a recycled low-density polyethylene (LDPE) in order to prepare flat sheet membranes with different polymer concentrations (5 and 10%). The used chemical method for the membrane's preparation is the phase inversion. After obtaining the membranes, we characterized them by atomic force microscopy (AFM) and scanning electron microscopy (SEM) to study their structure and surface characteristics. Based on the SEM images, our membranes have a dense skin layer. In addition, we observed a decrease in the porosity with the increase in the polymer concentration. When the polymer concentration increases from 5 to 10% the porosity decreases from 35.54% to 20.28%. Furthermore, we remarked significant changes in the contact angle and the surface roughness with the increase of the polymer concentration. The roughness increases from 363 to 577 nm for the same evolution of the polymer concentration. These high values of roughness imply obtaining values of contact angles greater than 90° and hydrophobic membranes, which is beneficial for the membrane distillation. Furthermore, the use of our membranes in vacuum membrane distillation (VMD) experiments showed a permeate flux up to 1.503 kg/hm2; for the membrane with 35.54% of porosity and 5% of polymer concentration.


*Correspondence address, Mail address: Adel Zrelli, Environmental, Catalysis and Process Analysis Research Unity, National Engineering School of Gabes, University of Gabes, Omar Ibn. ElKhattab St. 6029 Gabes, Tunisia, E-mail:

References

Ahmad, A. L., Ideris, N., Ooi, B. S., Low, S. C. and Ismail, A., “Influence of Polymer Concentration on PVDF Membrane Fabrication for Immunoassay Analysis”, J. Appl. Sci., 14, 12991303 (2014) 10.3923/jas.2014.1299.1303Suche in Google Scholar

Akbari, A., Hamadanian, M., Jabbari, V., Lehi, A. Y. and Bojaran, M., “Influence of PVDF Concentration on the Morphology, Surface Roughness, Crystalline Structure, and Filtration Separation Properties of Semicrystalline Phase Inversion Polymeric Membranes”, Desalin. Water Treat., 46, 96106 (2012) 10.1080/19443994.2012.677524Suche in Google Scholar

Akbari, A., Yegani, R., “Study on the Impact of Polymer Concentration and Coagulation Bath Temperature on the Porosity of Polyethylene Membranes Fabricated via TIPS Method”, J. Membr. Sep. Technol., 1, 100107 (2012), ISSN: 1929-6037Suche in Google Scholar

Drioli, E., Ali, A. and Macedonio, F., “Membrane Distillation: Recent Developments and Perspectives”, Desalination, 356, 5684 (2015) 10.1016/j.desal.2014.10.028Suche in Google Scholar

Eykens, L., De Sitter, K., Dotremont, C., Pinoy, L. and Van der Bruggen, B., “Characterization and Performance Evaluation of Commercially Available Hydrophobic Membranes for Direct Contact Membrane Distillation”, Desalination, 392, 6373 (2016) 10.1016/j.desal.2016.04.006Suche in Google Scholar

Feng, C., Shi, B., Li, G. and Wu, Y., “Preparation and Properties of Microporous Membrane from Poly(vinylidene fluoride-co-tetrafluoroethylene) (F2. 4) for Membrane Distillation”, J. Membr. Sci., 237, 1524 (2004) 10.1016/j.memsci.2004.02.007Suche in Google Scholar

Fournier, J.-M.: L'eau dans les Villes d'Amérique Latine, Editions L'Harmattan, Paris (2001)Suche in Google Scholar

Garg, M. C., Joshi, H., “A Review on PV-RO Process: Solution to Drinking Water Scarcity due to High Salinity in non-Electrified Rural Areas”, Sep. Sci. Technol., 50, 12701283 (2015) 10.1080/01496395.2014.951725Suche in Google Scholar

Gryta, M., “Water Purification by Membrane Distillation Process”, Sep. Sci. Technol., 41, 17891798 (2006) 10.1080/01496390600674950Suche in Google Scholar

Khayet, M., “Membranes and Theoretical Modeling of Membrane Distillation: a Review”, Adv. Colloid Interface Sci., 164, 5688 (2011) 21067710 10.1016/j.cis.2010.09.005Suche in Google Scholar PubMed

Khayet, M., MatsuuraT.: Membrane Distillation: Principles and Applications, Elsevier, Amsterdam (2011) 10.1016/B978-0-444-53126-1.10012-0Suche in Google Scholar

Khulbe, K. C., Feng, C. Y. and Matsuura, T., “Synthetic Polymeric Membranes: Characterization by Atomic Force Microscopy”, Springer Science & Business Media, Berlin (2007) 10.1007/978-3-540-73994-4Suche in Google Scholar

Lawson, K. W., Lloyd, D. R., “Membrane Distillation”, J. Membr. Sci., 124, 125 (1997) 10.1016/S0376-7388(96)00236-0Suche in Google Scholar

Pontié, M., Diawara, C., Lhassani, A., Dach, H., Rumeau, M., Buisson, H. and Schrotter, J. C., “Water Defluoridation Processes: A Review. Application: Nanofiltration (NF) for Future Large-Scale Pilot Plants”, Adv. Fluor. Sci., 2, 4980 (2006) 10.1016/S1872-0358(06)02002-1Suche in Google Scholar

Santos, A. S. F., Teixeira, B. A. N., Agnelli, J. A. M. and Manrich, S., “Characterization of Effluents through a Typical Plastic Recycling Process: An Evaluation of Cleaning Performance and Environmental Pollution”, Resour. Conserv. Recycl., 45, 159171 (2005) 10.1016/j.resconrec.2005.01.011Suche in Google Scholar

Sehgal, T., Semwal, A., Maity, G. and Patel, S. P., “Hydrophilic Modifications of PVDF Membranes via Swift Heavy Ion Irradiations”, Surf. Eng., 34, 158164 (2018) 10.1080/02670844.2016.1274097Suche in Google Scholar

SigmundW. M., Hsu, S. H., “Young's Model”, in Encyclopedia of Membranes, Drioli, E., Giorno, L. (Eds.), Springer, Berlin, Heidelberg (2013) 10.1007/978-3-642-40872-4Suche in Google Scholar

Song, L., Ma, Z., Liao, X., Kosaraju, P. B., Irish, J. R. and Sirkar, K. K., “Pilot Plant Studies of Novel Membranes and Devices for Direct Contact Membrane Distillation-Based Desalination”, J. Membr. Sci., 323, 257270 (2008) 10.1016/j.memsci.2008.05.079Suche in Google Scholar

Received: 2018-05-30
Accepted: 2019-02-10
Published Online: 2019-06-19
Published in Print: 2019-07-03

© 2019, Carl Hanser Verlag, Munich

Heruntergeladen am 26.11.2025 von https://www.degruyterbrill.com/document/doi/10.3139/217.3717/html?lang=de
Button zum nach oben scrollen