Preparation and Characterization of Hydrophobic Flat Sheet Membranes Based on a Recycled Polymer
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H. Ajari
, A. Zrelli , B. Chaouachi und M. Pontié
Abstract
In this work, we used a recycled low-density polyethylene (LDPE) in order to prepare flat sheet membranes with different polymer concentrations (5 and 10%). The used chemical method for the membrane's preparation is the phase inversion. After obtaining the membranes, we characterized them by atomic force microscopy (AFM) and scanning electron microscopy (SEM) to study their structure and surface characteristics. Based on the SEM images, our membranes have a dense skin layer. In addition, we observed a decrease in the porosity with the increase in the polymer concentration. When the polymer concentration increases from 5 to 10% the porosity decreases from 35.54% to 20.28%. Furthermore, we remarked significant changes in the contact angle and the surface roughness with the increase of the polymer concentration. The roughness increases from 363 to 577 nm for the same evolution of the polymer concentration. These high values of roughness imply obtaining values of contact angles greater than 90° and hydrophobic membranes, which is beneficial for the membrane distillation. Furthermore, the use of our membranes in vacuum membrane distillation (VMD) experiments showed a permeate flux up to 1.503 kg/hm2; for the membrane with 35.54% of porosity and 5% of polymer concentration.
References
Ahmad, A. L., Ideris, N., Ooi, B. S., Low, S. C. and Ismail, A., “Influence of Polymer Concentration on PVDF Membrane Fabrication for Immunoassay Analysis”, J. Appl. Sci., 14, 1299–1303 (2014) 10.3923/jas.2014.1299.1303Suche in Google Scholar
Akbari, A., Hamadanian, M., Jabbari, V., Lehi, A. Y. and Bojaran, M., “Influence of PVDF Concentration on the Morphology, Surface Roughness, Crystalline Structure, and Filtration Separation Properties of Semicrystalline Phase Inversion Polymeric Membranes”, Desalin. Water Treat., 46, 96–106 (2012) 10.1080/19443994.2012.677524Suche in Google Scholar
Akbari, A., Yegani, R., “Study on the Impact of Polymer Concentration and Coagulation Bath Temperature on the Porosity of Polyethylene Membranes Fabricated via TIPS Method”, J. Membr. Sep. Technol., 1, 100–107 (2012), ISSN: 1929-6037Suche in Google Scholar
Drioli, E., Ali, A. and Macedonio, F., “Membrane Distillation: Recent Developments and Perspectives”, Desalination, 356, 56–84 (2015) 10.1016/j.desal.2014.10.028Suche in Google Scholar
Eykens, L., De Sitter, K., Dotremont, C., Pinoy, L. and Van der Bruggen, B., “Characterization and Performance Evaluation of Commercially Available Hydrophobic Membranes for Direct Contact Membrane Distillation”, Desalination, 392, 63–73 (2016) 10.1016/j.desal.2016.04.006Suche in Google Scholar
Feng, C., Shi, B., Li, G. and Wu, Y., “Preparation and Properties of Microporous Membrane from Poly(vinylidene fluoride-co-tetrafluoroethylene) (F2. 4) for Membrane Distillation”, J. Membr. Sci., 237, 15–24 (2004) 10.1016/j.memsci.2004.02.007Suche in Google Scholar
Fournier, J.-M.: L'eau dans les Villes d'Amérique Latine, Editions L'Harmattan, Paris (2001)Suche in Google Scholar
Garg, M. C., Joshi, H., “A Review on PV-RO Process: Solution to Drinking Water Scarcity due to High Salinity in non-Electrified Rural Areas”, Sep. Sci. Technol., 50, 1270–1283 (2015) 10.1080/01496395.2014.951725Suche in Google Scholar
Gryta, M., “Water Purification by Membrane Distillation Process”, Sep. Sci. Technol., 41, 1789–1798 (2006) 10.1080/01496390600674950Suche in Google Scholar
Khayet, M., “Membranes and Theoretical Modeling of Membrane Distillation: a Review”, Adv. Colloid Interface Sci., 164, 56–88 (2011) 21067710 10.1016/j.cis.2010.09.005Suche in Google Scholar PubMed
Khayet, M., MatsuuraT.: Membrane Distillation: Principles and Applications, Elsevier, Amsterdam (2011) 10.1016/B978-0-444-53126-1.10012-0Suche in Google Scholar
Khulbe, K. C., Feng, C. Y. and Matsuura, T., “Synthetic Polymeric Membranes: Characterization by Atomic Force Microscopy”, Springer Science & Business Media, Berlin (2007) 10.1007/978-3-540-73994-4Suche in Google Scholar
Lawson, K. W., Lloyd, D. R., “Membrane Distillation”, J. Membr. Sci., 124, 1–25 (1997) 10.1016/S0376-7388(96)00236-0Suche in Google Scholar
Pontié, M., Diawara, C., Lhassani, A., Dach, H., Rumeau, M., Buisson, H. and Schrotter, J. C., “Water Defluoridation Processes: A Review. Application: Nanofiltration (NF) for Future Large-Scale Pilot Plants”, Adv. Fluor. Sci., 2, 49–80 (2006) 10.1016/S1872-0358(06)02002-1Suche in Google Scholar
Santos, A. S. F., Teixeira, B. A. N., Agnelli, J. A. M. and Manrich, S., “Characterization of Effluents through a Typical Plastic Recycling Process: An Evaluation of Cleaning Performance and Environmental Pollution”, Resour. Conserv. Recycl., 45, 159–171 (2005) 10.1016/j.resconrec.2005.01.011Suche in Google Scholar
Sehgal, T., Semwal, A., Maity, G. and Patel, S. P., “Hydrophilic Modifications of PVDF Membranes via Swift Heavy Ion Irradiations”, Surf. Eng., 34, 158–164 (2018) 10.1080/02670844.2016.1274097Suche in Google Scholar
SigmundW. M., Hsu, S. H., “Young's Model”, in Encyclopedia of Membranes, Drioli, E., Giorno, L. (Eds.), Springer, Berlin, Heidelberg (2013) 10.1007/978-3-642-40872-4Suche in Google Scholar
Song, L., Ma, Z., Liao, X., Kosaraju, P. B., Irish, J. R. and Sirkar, K. K., “Pilot Plant Studies of Novel Membranes and Devices for Direct Contact Membrane Distillation-Based Desalination”, J. Membr. Sci., 323, 257–270 (2008) 10.1016/j.memsci.2008.05.079Suche in Google Scholar
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Artikel in diesem Heft
- Contents
- Contents
- Regular Contributed Articles
- Synthesis of a Novel Ladder Poly(azomethine-ester) Based on PET Waste Bottles
- Identifying Melt Processing Conditions for a Polyacrylonitrile Copolymer Plasticized with Water, Acetonitrile and their Mixtures
- Optimization of Injection Stretch Blow Molding: Part I – Defining Part Thickness Profile
- Damping, Thermal and Mechanical Analyses of Polycarbonate/Cerium Oxide Composites for Structural Applications
- On Induced Properties and Self Heating during Free Blowing of PET Preform
- Study of Rheology and Plug Assist Thermoforming of Linear and Branched PP Homopolymer and Impact Copolymer
- Micro-Residual Stress Measurement in Nanocomposite Reinforced Polymers
- Influence of Process Parameters on the Morphologies of Micro-Injection Molded Polyformaldehyde Parts
- Preparation and Characterization of Hydrophobic Flat Sheet Membranes Based on a Recycled Polymer
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei-Kakou Abstracts
Artikel in diesem Heft
- Contents
- Contents
- Regular Contributed Articles
- Synthesis of a Novel Ladder Poly(azomethine-ester) Based on PET Waste Bottles
- Identifying Melt Processing Conditions for a Polyacrylonitrile Copolymer Plasticized with Water, Acetonitrile and their Mixtures
- Optimization of Injection Stretch Blow Molding: Part I – Defining Part Thickness Profile
- Damping, Thermal and Mechanical Analyses of Polycarbonate/Cerium Oxide Composites for Structural Applications
- On Induced Properties and Self Heating during Free Blowing of PET Preform
- Study of Rheology and Plug Assist Thermoforming of Linear and Branched PP Homopolymer and Impact Copolymer
- Micro-Residual Stress Measurement in Nanocomposite Reinforced Polymers
- Influence of Process Parameters on the Morphologies of Micro-Injection Molded Polyformaldehyde Parts
- Preparation and Characterization of Hydrophobic Flat Sheet Membranes Based on a Recycled Polymer
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei-Kakou Abstracts