Home Processability, Thermal and Mechanical Properties of Rigid PVC/Kaolin Coated with Liquid Macromolecular Modifier Composites
Article
Licensed
Unlicensed Requires Authentication

Processability, Thermal and Mechanical Properties of Rigid PVC/Kaolin Coated with Liquid Macromolecular Modifier Composites

  • H. Liu , J. Wang , S. Wen , C. L. Gong , G. W. Zheng and C. X. Xiong
Published/Copyright: May 5, 2015
Become an author with De Gruyter Brill

Abstract

In order to investigate the effect of kaolin coated with liquid macromolecular modifier (LKL) particles on the processability, thermal and mechanical properties of PVC materials, rigid poly(vinyl chloride) (PVC)/kaolin and PVC/kaolin coated with liquid macromolecular modifier (PVC/LKL) composites were both fabricated by melt mixing. The processability, dynamic mechanical behavior, mechanical properties and micro-structure of PVC/kaolin and PVC/LKL composites were studied by using torque rheometer, dynamic mechanical analysis (DMA), universal mechanical testing machine and scanning electron microscope (SEM). The results showed that the LKL particles improved the processability of PVC materials, while restrained the degradation of PVC materials during melt mixing due to the plasticization, toughening effect and compatibilization of the liquid macromolecular modifier (LMM). Moreover, the LMM could promote LKL particles uniformly dispersed in PVC matrix, and enhance the interface adhesion between LKL particles and PVC matrix. The notched impact strength and Tg of the PVC/LKL composites achieved 4.0 kJ/m2 and 95.2 °C, which enhanced 29% and 6 °C with respect to neat PVC materials, respectively.


* Mail address: Hai Liu, Faculty of Chemistry and Material Science, Hubei Engineering University, Xiaogan, Hubei, PRC, E-mail:

References

BharadwajR. K., “Modeling the Barrier Properties of Polymer Layered Silicate Nanocomposites”, Macromolecules, 34, 1989–1992 (2001) 10.1021/ma010780bSearch in Google Scholar

CarmodyO., FrostR. L. and KristofJ.Modification of Kaolinite Surfaces through Mechanochemical Activation with Quartz: A Diffuse Reflectance Infrared Fourier Transform and Chemometrics Study”, Appl. Spectrosc., 60, 1414–1422 (2006) 10.1366/000370206779321472Search in Google Scholar PubMed

FrostR. L., MakoE., KristofJ. and HorvathE., “Modification of Kaolinite Surfaces by Mechanochemical Treatment”, Langmuir, 17, 4731–4738 (2001) 10.1021/la001453kSearch in Google Scholar

GilmanJ. W., “Flammability and Thermal Stability Studies of Polymer-Layered Silicate (Clay) Nanocomposites”, Appl. Clay Sci., 15, 31–49 (1999) 10.1016/S0169-1317(99)00019-8Search in Google Scholar

GongF. L., FengM. and YangM. S., “Thermal Properties of Poly-(vinylchloride)/Montmorillonite Nanocomposites”, Polym. Degrad. Stab., 84, 289–294 (2004) 10.1016/j.polymdegradstab.2003.11.003Search in Google Scholar

HanE. H., LeonE., “Mechanical Performance of Polymer Systems: The Relation Between Structure and Properties”, Prog. Polym. Sci., 30, 915–938 (2005) 10.1016/j.progpolymsci.2005.06.009Search in Google Scholar

HuangJ. C., ChangD. C. and DeaninR. D., “Analysis of PVC Blends by Three-Dimensional Solubility Parameters”, Adv. Polym. Tech.12, 81–90 (1993). 10.1002/adv.1993.060120108Search in Google Scholar

KhandalR. K., ChenuC. and LamyI.Adsorption of Different Polymers on Kaolinite and their Effect on Flumequine Adsorption”, Appl. Clay Sci., 6, 343–357 (1992) 10.1016/0169-1317(92)90002-5Search in Google Scholar

LangeJ., WyserY., “Recent Innovations in Barrier Technologies for Plastic Packaging – A Review”, Packag. Technol. Sci., 16, 149–158 (2003) 10.1002/pts.621Search in Google Scholar

LiK. S., ChenY. H. and NiuH. M., “Preparation of PVC/Kaolin Nanocomposites through Solid State Shear Compounding Based on Pan-Milling”, Mater. Sci. Forum, 694, 350–354 (2011) 10.4028/www.scientific.net/MSF.689.350Search in Google Scholar

LiuH., DongL. J. and XiongC.X., “Novel Modified Kaolin for Enhancing the Mechanical and Thermal Properties of Poly(vinyl chloride)”, Polym. Eng. Sci., 52, 2071–2077 (2012) 10.1002/pen.23161Search in Google Scholar

LiuH., WangJ., WenS., “Processability, Morphology, Thermal, and Mechanical Properties of Rigid PVC Composites with Liquid Macromolecular Modifier-Coated CaCO3”, Polym. Comp., (2014) 10.1002/pc.23033Search in Google Scholar

PagaczJ., PielichowskiK., “Preparation and Characterization of PVC/Montmorillonite Nanocomposites – A Review”, J. Vinyl Addi. Techn., 15, 61–76 (2009)10.1002/vnl.20186Search in Google Scholar

PanM. W., ShiX. D., “Morphology and Properties of PVC/Clay Nanocomposites via in situ Emulsion Polymerization”, J. Appl. Polym. Sci., 94, 277–286 (2004) 10.1002/app.20896Search in Google Scholar

PavlidouS., PapaspyridesC. D., “A Review on Polymer-Layered Silicate Nanocomposites”, Prog. Polym. Sci., 33, 1119–1198 (2008) 10.1016/j.progpolymsci.2008.07.008Search in Google Scholar

RobaidiA. Al, MousaA., MassadehS., RawabdehI. Al and AnagrehN., “The Potential of Silane Coated Calcium Carbonate on Mechanical Properties of Rigid PVC Composites for Pipe Manufacturing”, Mater. Sci. Appl., 2, 481–485 (2011)10.4236/msa.2011.25065Search in Google Scholar

SterkyK., HjertbergT. and JacobsenH.Effect of Montmorillonite Treatment on the Thermal Stability of Poly(vinyl chloride) Nanocomposites”. Polym. Degrad. Stab., 94, 1564–1570 (2009) 10.1016/j.polymdegradstab.2009.04.036Search in Google Scholar

TsunematsuK., TateyamaH., “Delamination of Urea-Kaolinite Complex by Using Intercalation Procedures”, J. Am. Ceram. Soc., 82, 1589–1591 (1999) 10.1111/j.1151-2916.1999.tb01963.xSearch in Google Scholar

ValaskovaM., RiederM. and MatejkaV., “Exfoliation/Delamination of Kaolinite by Low-Temperature Washing of Kaolinite-Urea Intercalates”, Appl. Clay Sci., 35, 108–118 (2007) 10.1016/j.clay.2006.07.001Search in Google Scholar

YarahmadiN., JakubowiczI. and GevertT., “Effects of Repeated Extrusion on the Properties and Durability of Rigid PVC Scrap”, Polym. Degrad. Stab., 73, 93–99 (2001) 10.1016/S0141-3910(01)00073-8Search in Google Scholar

ZbikM., RogerSt. C., “Nanomorphology of Kaolinites; Comparative SEM and AFM Studies”, Clay. Clay Miner., 46, 153–160 (1998) 10.1346/CCMN.1998.0460205Search in Google Scholar

Received: 2014-08-25
Accepted: 2015-02-08
Published Online: 2015-05-05
Published in Print: 2015-05-29

© 2015, Carl Hanser Verlag, Munich

Articles in the same Issue

  1. Contents
  2. Contents
  3. Regular Contributed Articles
  4. Multilayer Coextrusion of Polymer Composites to Develop Organic Capacitors
  5. Heat Flow Analysis and Efficiency Optimization of Rotational Molding Equipment for Large Plastic Products
  6. Thermorheology of Polyethylene Wax Modified Sulfur Asphalt
  7. Thermoplastic Cellulose Stearate and Cellulose Laurate: Melt Rheology, Processing and Application Potential
  8. Crystallization Kinetics for PP/EPDM/Nano-CaCO3 Composites – The Influence of Nanoparticles Distribution
  9. The Effect of ZnO Nanoparticle Filler on the Attenuation of ZnO/PCL Nanocomposites Using Microstrip Line at Microwave Frequency
  10. Synthesis and Properties of Nitrogen Heterocycle-Functionalized Core-Shell Hyperbranched Polyester
  11. Morphology Tuning of Conducting Polyaniline via Static, Liquid-Liquid Interfacial Polymerization Process and its Application for Optical pH Sensing
  12. Tuning of Final Performances of Soybean Oil–Based Polymer Nanocomposites: Effect of Styryl/Oil Functionalized Intercalant of Montmorillonite Reinforcer
  13. Processability, Thermal and Mechanical Properties of Rigid PVC/Kaolin Coated with Liquid Macromolecular Modifier Composites
  14. Numerical Analysis and Evaluation of Process and Geometry Specific Transient Temperature Fields for a New Variation of Gas-Assisted Injection Molding
  15. Effect of Feeding Strategy on the Properties of PP/Recycled EPDM Blends
  16. Analysis of a Single Screw Extruder with a Grooved Plasticating Barrel – Part I: The Melting Model
  17. Melt Elongation Strength and Drawability of LDPE/LLDPE Blends
  18. PPS News
  19. PPS News
  20. Seikei Kakou Abstracts
  21. Seikei Kakou Abstracts
Downloaded on 11.9.2025 from https://www.degruyterbrill.com/document/doi/10.3139/217.3009/html
Scroll to top button