Processability, Thermal and Mechanical Properties of Rigid PVC/Kaolin Coated with Liquid Macromolecular Modifier Composites
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H. Liu
Abstract
In order to investigate the effect of kaolin coated with liquid macromolecular modifier (LKL) particles on the processability, thermal and mechanical properties of PVC materials, rigid poly(vinyl chloride) (PVC)/kaolin and PVC/kaolin coated with liquid macromolecular modifier (PVC/LKL) composites were both fabricated by melt mixing. The processability, dynamic mechanical behavior, mechanical properties and micro-structure of PVC/kaolin and PVC/LKL composites were studied by using torque rheometer, dynamic mechanical analysis (DMA), universal mechanical testing machine and scanning electron microscope (SEM). The results showed that the LKL particles improved the processability of PVC materials, while restrained the degradation of PVC materials during melt mixing due to the plasticization, toughening effect and compatibilization of the liquid macromolecular modifier (LMM). Moreover, the LMM could promote LKL particles uniformly dispersed in PVC matrix, and enhance the interface adhesion between LKL particles and PVC matrix. The notched impact strength and Tg of the PVC/LKL composites achieved 4.0 kJ/m2 and 95.2 °C, which enhanced 29% and 6 °C with respect to neat PVC materials, respectively.
References
BharadwajR. K., “Modeling the Barrier Properties of Polymer Layered Silicate Nanocomposites”, Macromolecules, 34, 1989–1992 (2001) 10.1021/ma010780bSearch in Google Scholar
CarmodyO., FrostR. L. and KristofJ. “Modification of Kaolinite Surfaces through Mechanochemical Activation with Quartz: A Diffuse Reflectance Infrared Fourier Transform and Chemometrics Study”, Appl. Spectrosc., 60, 1414–1422 (2006) 10.1366/000370206779321472Search in Google Scholar PubMed
FrostR. L., MakoE., KristofJ. and HorvathE., “Modification of Kaolinite Surfaces by Mechanochemical Treatment”, Langmuir, 17, 4731–4738 (2001) 10.1021/la001453kSearch in Google Scholar
GilmanJ. W., “Flammability and Thermal Stability Studies of Polymer-Layered Silicate (Clay) Nanocomposites”, Appl. Clay Sci., 15, 31–49 (1999) 10.1016/S0169-1317(99)00019-8Search in Google Scholar
GongF. L., FengM. and YangM. S., “Thermal Properties of Poly-(vinylchloride)/Montmorillonite Nanocomposites”, Polym. Degrad. Stab., 84, 289–294 (2004) 10.1016/j.polymdegradstab.2003.11.003Search in Google Scholar
HanE. H., LeonE., “Mechanical Performance of Polymer Systems: The Relation Between Structure and Properties”, Prog. Polym. Sci., 30, 915–938 (2005) 10.1016/j.progpolymsci.2005.06.009Search in Google Scholar
HuangJ. C., ChangD. C. and DeaninR. D., “Analysis of PVC Blends by Three-Dimensional Solubility Parameters”, Adv. Polym. Tech.12, 81–90 (1993). 10.1002/adv.1993.060120108Search in Google Scholar
KhandalR. K., ChenuC. and LamyI. “Adsorption of Different Polymers on Kaolinite and their Effect on Flumequine Adsorption”, Appl. Clay Sci., 6, 343–357 (1992) 10.1016/0169-1317(92)90002-5Search in Google Scholar
LangeJ., WyserY., “Recent Innovations in Barrier Technologies for Plastic Packaging – A Review”, Packag. Technol. Sci., 16, 149–158 (2003) 10.1002/pts.621Search in Google Scholar
LiK. S., ChenY. H. and NiuH. M., “Preparation of PVC/Kaolin Nanocomposites through Solid State Shear Compounding Based on Pan-Milling”, Mater. Sci. Forum, 694, 350–354 (2011) 10.4028/www.scientific.net/MSF.689.350Search in Google Scholar
LiuH., DongL. J. and XiongC.X., “Novel Modified Kaolin for Enhancing the Mechanical and Thermal Properties of Poly(vinyl chloride)”, Polym. Eng. Sci., 52, 2071–2077 (2012) 10.1002/pen.23161Search in Google Scholar
LiuH., WangJ., WenS., “Processability, Morphology, Thermal, and Mechanical Properties of Rigid PVC Composites with Liquid Macromolecular Modifier-Coated CaCO3”, Polym. Comp., (2014) 10.1002/pc.23033Search in Google Scholar
PagaczJ., PielichowskiK., “Preparation and Characterization of PVC/Montmorillonite Nanocomposites – A Review”, J. Vinyl Addi. Techn., 15, 61–76 (2009)10.1002/vnl.20186Search in Google Scholar
PanM. W., ShiX. D., “Morphology and Properties of PVC/Clay Nanocomposites via in situ Emulsion Polymerization”, J. Appl. Polym. Sci., 94, 277–286 (2004) 10.1002/app.20896Search in Google Scholar
PavlidouS., PapaspyridesC. D., “A Review on Polymer-Layered Silicate Nanocomposites”, Prog. Polym. Sci., 33, 1119–1198 (2008) 10.1016/j.progpolymsci.2008.07.008Search in Google Scholar
RobaidiA. Al, MousaA., MassadehS., RawabdehI. Al and AnagrehN., “The Potential of Silane Coated Calcium Carbonate on Mechanical Properties of Rigid PVC Composites for Pipe Manufacturing”, Mater. Sci. Appl., 2, 481–485 (2011)10.4236/msa.2011.25065Search in Google Scholar
SterkyK., HjertbergT. and JacobsenH. “Effect of Montmorillonite Treatment on the Thermal Stability of Poly(vinyl chloride) Nanocomposites”. Polym. Degrad. Stab., 94, 1564–1570 (2009) 10.1016/j.polymdegradstab.2009.04.036Search in Google Scholar
TsunematsuK., TateyamaH., “Delamination of Urea-Kaolinite Complex by Using Intercalation Procedures”, J. Am. Ceram. Soc., 82, 1589–1591 (1999) 10.1111/j.1151-2916.1999.tb01963.xSearch in Google Scholar
ValaskovaM., RiederM. and MatejkaV., “Exfoliation/Delamination of Kaolinite by Low-Temperature Washing of Kaolinite-Urea Intercalates”, Appl. Clay Sci., 35, 108–118 (2007) 10.1016/j.clay.2006.07.001Search in Google Scholar
YarahmadiN., JakubowiczI. and GevertT., “Effects of Repeated Extrusion on the Properties and Durability of Rigid PVC Scrap”, Polym. Degrad. Stab., 73, 93–99 (2001) 10.1016/S0141-3910(01)00073-8Search in Google Scholar
ZbikM., RogerSt. C., “Nanomorphology of Kaolinites; Comparative SEM and AFM Studies”, Clay. Clay Miner., 46, 153–160 (1998) 10.1346/CCMN.1998.0460205Search in Google Scholar
© 2015, Carl Hanser Verlag, Munich
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Articles in the same Issue
- Contents
- Contents
- Regular Contributed Articles
- Multilayer Coextrusion of Polymer Composites to Develop Organic Capacitors
- Heat Flow Analysis and Efficiency Optimization of Rotational Molding Equipment for Large Plastic Products
- Thermorheology of Polyethylene Wax Modified Sulfur Asphalt
- Thermoplastic Cellulose Stearate and Cellulose Laurate: Melt Rheology, Processing and Application Potential
- Crystallization Kinetics for PP/EPDM/Nano-CaCO3 Composites – The Influence of Nanoparticles Distribution
- The Effect of ZnO Nanoparticle Filler on the Attenuation of ZnO/PCL Nanocomposites Using Microstrip Line at Microwave Frequency
- Synthesis and Properties of Nitrogen Heterocycle-Functionalized Core-Shell Hyperbranched Polyester
- Morphology Tuning of Conducting Polyaniline via Static, Liquid-Liquid Interfacial Polymerization Process and its Application for Optical pH Sensing
- Tuning of Final Performances of Soybean Oil–Based Polymer Nanocomposites: Effect of Styryl/Oil Functionalized Intercalant of Montmorillonite Reinforcer
- Processability, Thermal and Mechanical Properties of Rigid PVC/Kaolin Coated with Liquid Macromolecular Modifier Composites
- Numerical Analysis and Evaluation of Process and Geometry Specific Transient Temperature Fields for a New Variation of Gas-Assisted Injection Molding
- Effect of Feeding Strategy on the Properties of PP/Recycled EPDM Blends
- Analysis of a Single Screw Extruder with a Grooved Plasticating Barrel – Part I: The Melting Model
- Melt Elongation Strength and Drawability of LDPE/LLDPE Blends
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