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Thermorheology of Polyethylene Wax Modified Sulfur Asphalt

  • M. A. Parvez , H. I. Al-Abdul Wahhab , I. A. Hussein and M. Al-Mehthel
Published/Copyright: May 5, 2015
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Abstract

The possibility of using polyethylene (PE) wax to modify the rheology of sulfur asphalt binders is investigated. In this study, two industrial wastes namely sulfur and PE wax are used to modify asphalt for pavement applications. Asphalt binders with different amounts of sulfur and wax content are prepared in a high shear blender and rheological tests were carried out in ARES rheometer. PE wax content was varied from 2 to 8 % and sulfur of up to 40 % is used in asphalt binder. Melt rheology is characterized by dynamic frequency sweep, temperature sweep and artificial ageing techniques. Pure and modified asphalt binders are also characterized by Fourier transform infrared spectra (FTIR). Improvement in the viscoelastic properties (G′ and G″) of the sulfur asphalt binders is obtained due to the addition of PE wax. PE wax modification has reduced temperature susceptibility of sulfur asphalt and increased the upper performance temperature. In addition, this wax modification has increased the activation energy and the zero shear viscosity of sulfur asphalt. Optimum sulfur and PE wax contents of the asphalt binder are recommended. Utilization of PE wax and sulfur wastes in asphalt modification proved to enhance asphalt pavement life.


* Mail address: Ibnelwaleed A. Hussein, KFUPM, P.O. Box 1399, Dhahran 31261, Saudi Arabia, E-mail:

References

Al-Abdul WahhabH. I., AsiI. M., Al-DubabeI.A. and AliM. F., “Development of Performance-Based Bitumen Specifications for the Gulf Countries”, Constr. Build. Mater.11, 15–22 (1997) 10.1016/S0950-0618(97)00002-0Search in Google Scholar

Al-Abdul WahhabH. I., HusseinI. A., ParvezM. A. and ShawabkehR. A., “Use of modified Oil Fly Ash to Enhance Asphalt Concrete Performance”, Mater. Struct. (2014) 10.1617/s11527-014-0393-5Search in Google Scholar

BahiaH., ZengM., ZhaiH. and KhatriM. A., “Superpave Protocols for Modified Asphalt Binders, 15th Quarterly Progress Report for NCHRP Project 9–10”, National Cooperative Highway Research Program, Washington, D. C. (1999)Search in Google Scholar

BenzowitzJ., BoeE. S., “Effect of Sulfur upon some of the Properties of Asphalt”, Proceedings of ASTM38, 539–549 (1938)Search in Google Scholar

EdwardsY., TasdemirY. and ButtA. A., “Energy Saving and Environmental Friendly Wax Concept for Polymer Modified Mastic Asphalt”, Mater. Struct., 43, 123–131 (2010) 10.1617/s11527-010-9603-ySearch in Google Scholar

EdwardsY., TasdemirY. and IsacssonU., “Influence of Commercial Waxes and Polyphosphoric Acid on Bitumen and Asphalt Concrete Performance at Low and Medium Temperatures”, Mater. Struct., 39, 725–737 (2006) 10.1617/s11527-006-9134-8Search in Google Scholar

EdwardsY., TasdemirY. and IsacssonU., “Rheological Effects of Commercial Waxes and Polyphosphoric Acid in Bitumen 160/220 – High and Medium Temperature Performance”, Constr. Build. Mater.21, 1899–1908 (2007) 10.1016/j.conbuildmat.2006.07.012Search in Google Scholar

HusseinI. A., IqbalM. H. and Al-Abdul WahhabH. I., “Influence of Mw of LDPE and Vinyl Acetate Content of EVA on the Rheology of Polymer Modified Asphalt”, Rheol. Acta, 45, 92–104 (2005) 10.1007/s00397-005-0455-2Search in Google Scholar

HusseinI. A., WahhabH. I. and IqbalM. H., “Influence of Polymer Type and Structure on Polymer Modified Asphalt Concrete Mix”, Can. J. Chem. Eng., 84, 480–487 (2006) 10.1002/cjce.5450840409Search in Google Scholar

IqbalM. H., HusseinI. A., Al-Abdul WahhabH. I. and AminB., “Influence of Mw of LDPE and Vinyl Acetate Content of EVA on the Rheology of Polymer Modified Asphalt”, J. Appl. Polym. Sci., 102, 3446–3456 (2006) 10.1002/app.24408Search in Google Scholar

KennepohlG., MillerL., “Sulfur-Asphalt Binder Technology for Pavements-New Uses of Sulfur II”, Proceedings in Advances in Chemistry, Ontario, Canada (1978)10.1021/ba-1978-0165.ch007Search in Google Scholar

KokB. V., YilmazM., “The Effects of Using Lime and Styrene-Butadiene-Styrene on Moisture Sensitivity Resistance of Hot Mix Asphalt”, Constr. Build. Mater.23, 1999–2006 (2009) 10.1016/j.conbuildmat.2008.08.019Search in Google Scholar

LeeD. Y., “Modification of Asphalt and Asphalt Paving Mixtures by Sulfur”, Ind. Eng. Chem. Prod. Res. Dev., 14, 171–177 (1975) 10.1021/i360055a009Search in Google Scholar

MerusiF., GiulianiF., “Rheological Characterization of Wax-Modified Asphalt Binders at High Service Temperatures”, Mater. Struct., 44, 1809–1820 (2011) 10.1617/s11527-011-9739-4Search in Google Scholar

ParvezM. A., Al-Abdul WahhabH. I., ShawabkehR. A. and HusseinI. A., “Asphalt Modification Using Acid Treated Waste Oil Fly Ash”, Constr. Build. Mater., 70, 201–209 (2014) 10.1016/j.conbuildmat.2014.07.045Search in Google Scholar

ParvezM. A., Al-MehthelM., Al-Abdul WahhabH. I. and HusseinI. A., “Utilization of Sulfur and Crumb Rubber in Asphalt Modification”, J. Appl. Polym. Sci., 131(2014) 10.1002/APP.40046Search in Google Scholar

PfeifferJ., van DoormalP., “The Rheological Properties of Asphaltic Bitumens”, J. Instn. Petrol. Tech., 22, 414–440 (1936)Search in Google Scholar

PolaccoG., StastnaJ., BiondiD., AntonelliF., VlachovicovaZ. and ZanzottoL., “Rheology of Asphalts Modified with Glycidylmethacrylate Functionalized Polymers”, J. Colloid Interface Sci., 280, 366–373 (2004) 10.1016/j.jcis.2004.08.043Search in Google Scholar PubMed

TimmD., TranN., TaylorA., RobbinsM. and PowellB., “Evaluation of Mixture Performance and Structural Capacity of Pavements Utilizing Shell Thiopave”, Report No.09–05 National Center for Asphalt Technology, Auburn University, Auburn, Alabama, USA (2009)Search in Google Scholar

TimmD., TranN., TaylorA., RobbinsM. and PowellB., “Evaluation of Mixture Performance and Structural Capacity of Pavements Utilizing Shell Thiopave”, Report No. 11–03 National Center for Asphalt Technology, Auburn University, Auburn, Alabama, USA (2011)Search in Google Scholar

ZhangF., YuJ. and HanJ., “Effects of Thermal Oxidative Ageing on Dynamic Viscosity, TG/DTG, DTA and FTIR”, Constr. Build. Mater., 25, 129–137 (2011) 10.1016/j.conbuildmat.2010.06.048Search in Google Scholar

ZhangF., YuJ. and WuS., “Effect of Ageing on Rheological Properties of Storage-Stable SBS/Sulfur-Modified Asphalt”, J. Hazard. Mater., 182, 507–517 (2010) 10.1016/j.jhazmat.2010.06.061Search in Google Scholar PubMed

Received: 2014-05-31
Accepted: 2014-11-19
Published Online: 2015-05-05
Published in Print: 2015-05-29

© 2015, Carl Hanser Verlag, Munich

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