Thermorheology of Polyethylene Wax Modified Sulfur Asphalt
-
M. A. Parvez
, H. I. Al-Abdul Wahhab , I. A. Hussein and M. Al-Mehthel
Abstract
The possibility of using polyethylene (PE) wax to modify the rheology of sulfur asphalt binders is investigated. In this study, two industrial wastes namely sulfur and PE wax are used to modify asphalt for pavement applications. Asphalt binders with different amounts of sulfur and wax content are prepared in a high shear blender and rheological tests were carried out in ARES rheometer. PE wax content was varied from 2 to 8 % and sulfur of up to 40 % is used in asphalt binder. Melt rheology is characterized by dynamic frequency sweep, temperature sweep and artificial ageing techniques. Pure and modified asphalt binders are also characterized by Fourier transform infrared spectra (FTIR). Improvement in the viscoelastic properties (G′ and G″) of the sulfur asphalt binders is obtained due to the addition of PE wax. PE wax modification has reduced temperature susceptibility of sulfur asphalt and increased the upper performance temperature. In addition, this wax modification has increased the activation energy and the zero shear viscosity of sulfur asphalt. Optimum sulfur and PE wax contents of the asphalt binder are recommended. Utilization of PE wax and sulfur wastes in asphalt modification proved to enhance asphalt pavement life.
References
Al-Abdul WahhabH. I., AsiI. M., Al-DubabeI.A. and AliM. F., “Development of Performance-Based Bitumen Specifications for the Gulf Countries”, Constr. Build. Mater.11, 15–22 (1997) 10.1016/S0950-0618(97)00002-0Search in Google Scholar
Al-Abdul WahhabH. I., HusseinI. A., ParvezM. A. and ShawabkehR. A., “Use of modified Oil Fly Ash to Enhance Asphalt Concrete Performance”, Mater. Struct. (2014) 10.1617/s11527-014-0393-5Search in Google Scholar
BahiaH., ZengM., ZhaiH. and KhatriM. A., “Superpave Protocols for Modified Asphalt Binders, 15th Quarterly Progress Report for NCHRP Project 9–10”, National Cooperative Highway Research Program, Washington, D. C. (1999)Search in Google Scholar
BenzowitzJ., BoeE. S., “Effect of Sulfur upon some of the Properties of Asphalt”, Proceedings of ASTM38, 539–549 (1938)Search in Google Scholar
EdwardsY., TasdemirY. and ButtA. A., “Energy Saving and Environmental Friendly Wax Concept for Polymer Modified Mastic Asphalt”, Mater. Struct., 43, 123–131 (2010) 10.1617/s11527-010-9603-ySearch in Google Scholar
EdwardsY., TasdemirY. and IsacssonU., “Influence of Commercial Waxes and Polyphosphoric Acid on Bitumen and Asphalt Concrete Performance at Low and Medium Temperatures”, Mater. Struct., 39, 725–737 (2006) 10.1617/s11527-006-9134-8Search in Google Scholar
EdwardsY., TasdemirY. and IsacssonU., “Rheological Effects of Commercial Waxes and Polyphosphoric Acid in Bitumen 160/220 – High and Medium Temperature Performance”, Constr. Build. Mater.21, 1899–1908 (2007) 10.1016/j.conbuildmat.2006.07.012Search in Google Scholar
HusseinI. A., IqbalM. H. and Al-Abdul WahhabH. I., “Influence of Mw of LDPE and Vinyl Acetate Content of EVA on the Rheology of Polymer Modified Asphalt”, Rheol. Acta, 45, 92–104 (2005) 10.1007/s00397-005-0455-2Search in Google Scholar
HusseinI. A., WahhabH. I. and IqbalM. H., “Influence of Polymer Type and Structure on Polymer Modified Asphalt Concrete Mix”, Can. J. Chem. Eng., 84, 480–487 (2006) 10.1002/cjce.5450840409Search in Google Scholar
IqbalM. H., HusseinI. A., Al-Abdul WahhabH. I. and AminB., “Influence of Mw of LDPE and Vinyl Acetate Content of EVA on the Rheology of Polymer Modified Asphalt”, J. Appl. Polym. Sci., 102, 3446–3456 (2006) 10.1002/app.24408Search in Google Scholar
KennepohlG., MillerL., “Sulfur-Asphalt Binder Technology for Pavements-New Uses of Sulfur II”, Proceedings in Advances in Chemistry, Ontario, Canada (1978)10.1021/ba-1978-0165.ch007Search in Google Scholar
KokB. V., YilmazM., “The Effects of Using Lime and Styrene-Butadiene-Styrene on Moisture Sensitivity Resistance of Hot Mix Asphalt”, Constr. Build. Mater.23, 1999–2006 (2009) 10.1016/j.conbuildmat.2008.08.019Search in Google Scholar
LeeD. Y., “Modification of Asphalt and Asphalt Paving Mixtures by Sulfur”, Ind. Eng. Chem. Prod. Res. Dev., 14, 171–177 (1975) 10.1021/i360055a009Search in Google Scholar
MerusiF., GiulianiF., “Rheological Characterization of Wax-Modified Asphalt Binders at High Service Temperatures”, Mater. Struct., 44, 1809–1820 (2011) 10.1617/s11527-011-9739-4Search in Google Scholar
ParvezM. A., Al-Abdul WahhabH. I., ShawabkehR. A. and HusseinI. A., “Asphalt Modification Using Acid Treated Waste Oil Fly Ash”, Constr. Build. Mater., 70, 201–209 (2014) 10.1016/j.conbuildmat.2014.07.045Search in Google Scholar
ParvezM. A., Al-MehthelM., Al-Abdul WahhabH. I. and HusseinI. A., “Utilization of Sulfur and Crumb Rubber in Asphalt Modification”, J. Appl. Polym. Sci., 131(2014) 10.1002/APP.40046Search in Google Scholar
PfeifferJ., van DoormalP., “The Rheological Properties of Asphaltic Bitumens”, J. Instn. Petrol. Tech., 22, 414–440 (1936)Search in Google Scholar
PolaccoG., StastnaJ., BiondiD., AntonelliF., VlachovicovaZ. and ZanzottoL., “Rheology of Asphalts Modified with Glycidylmethacrylate Functionalized Polymers”, J. Colloid Interface Sci., 280, 366–373 (2004) 10.1016/j.jcis.2004.08.043Search in Google Scholar PubMed
TimmD., TranN., TaylorA., RobbinsM. and PowellB., “Evaluation of Mixture Performance and Structural Capacity of Pavements Utilizing Shell Thiopave”, Report No.09–05 National Center for Asphalt Technology, Auburn University, Auburn, Alabama, USA (2009)Search in Google Scholar
TimmD., TranN., TaylorA., RobbinsM. and PowellB., “Evaluation of Mixture Performance and Structural Capacity of Pavements Utilizing Shell Thiopave”, Report No. 11–03 National Center for Asphalt Technology, Auburn University, Auburn, Alabama, USA (2011)Search in Google Scholar
ZhangF., YuJ. and HanJ., “Effects of Thermal Oxidative Ageing on Dynamic Viscosity, TG/DTG, DTA and FTIR”, Constr. Build. Mater., 25, 129–137 (2011) 10.1016/j.conbuildmat.2010.06.048Search in Google Scholar
ZhangF., YuJ. and WuS., “Effect of Ageing on Rheological Properties of Storage-Stable SBS/Sulfur-Modified Asphalt”, J. Hazard. Mater., 182, 507–517 (2010) 10.1016/j.jhazmat.2010.06.061Search in Google Scholar PubMed
© 2015, Carl Hanser Verlag, Munich
Articles in the same Issue
- Contents
- Contents
- Regular Contributed Articles
- Multilayer Coextrusion of Polymer Composites to Develop Organic Capacitors
- Heat Flow Analysis and Efficiency Optimization of Rotational Molding Equipment for Large Plastic Products
- Thermorheology of Polyethylene Wax Modified Sulfur Asphalt
- Thermoplastic Cellulose Stearate and Cellulose Laurate: Melt Rheology, Processing and Application Potential
- Crystallization Kinetics for PP/EPDM/Nano-CaCO3 Composites – The Influence of Nanoparticles Distribution
- The Effect of ZnO Nanoparticle Filler on the Attenuation of ZnO/PCL Nanocomposites Using Microstrip Line at Microwave Frequency
- Synthesis and Properties of Nitrogen Heterocycle-Functionalized Core-Shell Hyperbranched Polyester
- Morphology Tuning of Conducting Polyaniline via Static, Liquid-Liquid Interfacial Polymerization Process and its Application for Optical pH Sensing
- Tuning of Final Performances of Soybean Oil–Based Polymer Nanocomposites: Effect of Styryl/Oil Functionalized Intercalant of Montmorillonite Reinforcer
- Processability, Thermal and Mechanical Properties of Rigid PVC/Kaolin Coated with Liquid Macromolecular Modifier Composites
- Numerical Analysis and Evaluation of Process and Geometry Specific Transient Temperature Fields for a New Variation of Gas-Assisted Injection Molding
- Effect of Feeding Strategy on the Properties of PP/Recycled EPDM Blends
- Analysis of a Single Screw Extruder with a Grooved Plasticating Barrel – Part I: The Melting Model
- Melt Elongation Strength and Drawability of LDPE/LLDPE Blends
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei Kakou Abstracts
Articles in the same Issue
- Contents
- Contents
- Regular Contributed Articles
- Multilayer Coextrusion of Polymer Composites to Develop Organic Capacitors
- Heat Flow Analysis and Efficiency Optimization of Rotational Molding Equipment for Large Plastic Products
- Thermorheology of Polyethylene Wax Modified Sulfur Asphalt
- Thermoplastic Cellulose Stearate and Cellulose Laurate: Melt Rheology, Processing and Application Potential
- Crystallization Kinetics for PP/EPDM/Nano-CaCO3 Composites – The Influence of Nanoparticles Distribution
- The Effect of ZnO Nanoparticle Filler on the Attenuation of ZnO/PCL Nanocomposites Using Microstrip Line at Microwave Frequency
- Synthesis and Properties of Nitrogen Heterocycle-Functionalized Core-Shell Hyperbranched Polyester
- Morphology Tuning of Conducting Polyaniline via Static, Liquid-Liquid Interfacial Polymerization Process and its Application for Optical pH Sensing
- Tuning of Final Performances of Soybean Oil–Based Polymer Nanocomposites: Effect of Styryl/Oil Functionalized Intercalant of Montmorillonite Reinforcer
- Processability, Thermal and Mechanical Properties of Rigid PVC/Kaolin Coated with Liquid Macromolecular Modifier Composites
- Numerical Analysis and Evaluation of Process and Geometry Specific Transient Temperature Fields for a New Variation of Gas-Assisted Injection Molding
- Effect of Feeding Strategy on the Properties of PP/Recycled EPDM Blends
- Analysis of a Single Screw Extruder with a Grooved Plasticating Barrel – Part I: The Melting Model
- Melt Elongation Strength and Drawability of LDPE/LLDPE Blends
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei Kakou Abstracts