Startseite Preparation of Poly(acrylic acid)-Poly(ethylene oxide) Nanofibers via Electrospinning and Investigation of Their Morphology
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Preparation of Poly(acrylic acid)-Poly(ethylene oxide) Nanofibers via Electrospinning and Investigation of Their Morphology

  • Z. Shami und N. Sharifi-Sanjani
Veröffentlicht/Copyright: 6. April 2013
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Abstract

The poly(acrylic acid)/poly(ethylene oxide) (PAA/PEO) blend nanofibers at 100/0, 80/20, 50/50, 20/80 and 0/100 weight ratios were obtained via electrospinning process. Intermolecular interactions, miscibility and compatibility of polymer blends were studied by Fourier transform infrared (FT-IR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and UV-visible spectrophotometer. The results suggest that intermolecular interactions have occurred between pure PAA and PEO in PAA/PEO blend. These interactions made PAA/PEO blend miscible at above-mentioned weight ratios. Additionally, the morphology and the fibers diameter were investigated using scanning electron microscope (SEM) analysis, which indicated beadless fibers with diameter range of about 120 to 300 nm. It was observed that the homogenous nanofibers with the smaller diameter were obtained in PAA/PEO blend with PAA dominant content. Finally, SEM results suggest that the formation of pure PAA nanofibers with concentration of 5.0 wt.% would not occur. Whereas, in the same concentration, pure PEO and PAA/PEO blend nanofibers with no bead defects were obtained. However, in higher pure PAA concentrations electrospun fibers were formed.


Mail address: Zahed Shami, School of Chemistry, University College of Science, University of Tehran, Tehran, Iran. E-mail:

References

Ahn, H. J., et al., “Complexation Behavior of Poly(acrylic acid) and Poly(ethylene oxide) in Water and Water-methanol”, Chem A., 37, 573590(2000)Suche in Google Scholar

Ajao, J. A., “Preparation and Characterization of Electrospun Poly(2,5-dicyclohexylphenylene-1,4-ethynylene) (C24H30)n/poly(ethylene oxide) (PEO) Hybrid Nanofibers”, J. Mater. Sci., 45, 713718(2010), DOI: 10.1007/s10853-009-3989-3Suche in Google Scholar

Bailey, F. E., et al., “Some Factors Affecting the Molecular Association Of Poly(ethy1ene oxide) and Poly(acry1ic acid) in Aqueous Solution”, J. Polymer. Sci.A2.2, 845851(1964)10.1002/pol.1964.100020221Suche in Google Scholar

Chen, H., “Electrospinning and Solution Properties of Nafion and Poly(acrylic acid)”, Macromolecules., 41, 128135(2008), DOI: 10.1021/ma070893gSuche in Google Scholar

Deitzel, J. M., et al., “The Effect of Processing Variables on the Morphology of Electrospun Nanofibers and Textiles”, Polymer., 42, 26172(2001), DOI: 10.1016/S0032-3861(00)00250-0Suche in Google Scholar

Halina, K., Aleksandra, S., “Photochemical Transformation in Poly(acrylic acid)/poly(ethylene oxide) Complexes”, J. Phtochem. Phtobio A: Chem., 180, 4653(2006), DOI: 10.1016/j.jphotochem.2005.09.014Suche in Google Scholar

Huang, Z. M., et al., “A Review on Polymer Nanofibers by Electrospinning and Their Applications in Nanocomposites”, Compos. Sci. Technol., 63, 22232253(2003), DOI: 10.1016/S0266-3538(03)00178-7Suche in Google Scholar

Jin, H. J., et al., “Electrospinning Bombyx Mori silk with Poly(ethylene oxide)”, Biomacromolecules., 3, 12331239(2002), PMid:12425660 DOI: 10.1021/bm025581uSuche in Google Scholar PubMed

Khutoryanskiy, V. V., et al., “pH Effects in the Complex Formation and Blending of Poly(acrylic acid) with Poly(ethylene oxide)”, Langmuir., 20, 37853790(2004), PMid:15875416 DOI: 10.1021/la049807lPMid:15875416Suche in Google Scholar

Kim, B., et al., “Poly(acrylic acid) Nanofibers by Electrospinning”, Mater. Lett., 59, 82932(2005), DOI: 10.1016/j.matlet.2004.11.032Suche in Google Scholar

Kunawan, A., et al., “Effects of Poly(ethylene glycol), Inorganic Salt, Sodium Dodecyl Sulfate, and Solvent System on Electrospinning of Poly(ethylene oxide)”, Macromo. Mater. Eng., 291, 58191(2006), DOI: 10.1002/mame.200500419Suche in Google Scholar

Kyoon, M., et al., “Enhanced Conductivity of Aligned PANi/PEO/MWNT Nanofibers by Electrospinning”, Sensors and Actuators B., 134, 122126(2008), DOI: 10.1016/j.snb.2008.04.021Suche in Google Scholar

Lau, C. M. Y., “A Study of Blending and Complexation of Poly(acrylic acid)/poly(vinyl pyrrolidone)”, Polymer., 43, 823829(2002), DOI: 10.1016/S0032-3861(01)00641-3Suche in Google Scholar

Li, L., Hsieh, Y. L., “Ultra-fine Polyelectrolyte Hydrogel Fibres from Poly(acrylic acid)/poly(vinyl alcohol)”, Nanotechnology., 16, 28522860(2005), DOI: 10.1088/0957-4484/16/12/020Suche in Google Scholar

Li, L., Hsieh, Y. L., “Ultra-fine Polyelectrolyte Fibers from Electrospinning of Poly(acrylic acid)”, Polymer., 46, 51335139(2005), DOI: 10.1016/j.polymer.2005.04.039Suche in Google Scholar

Luo, Y., et al., “Synthesis and Characterization of a Poly(acrylic acid)-graft-methoxy-poly(ethylene oxide) Comblike Copolymer”, J. App. Polym. Sci., 109, 32863291(2008), DOI: 10.1002/app.28272Suche in Google Scholar

Maunu, S. L., “Interpolymer Complexation between Poly(ethylene oxide) and Poly(acrylic acid)”, Polymer Bulletin., 19, 171177(1988), DOI: 10.1007/BF00257012Suche in Google Scholar

RamakrishnaS.: An Introduction to Electrospinning and Nanofibers, World Scientific, Singapore(2005)Suche in Google Scholar

Shin, J. W., “Hybrid Nanofiber Scaffolds of Polyurethane and Poly(ethylene oxide) Using Dual Electrospinning for Vascular Tissue Engineering”, IFMBE Proceedings., 15, 692695(2007), DOI: 10.1007/978-3-540-68017-8_174Suche in Google Scholar

Son, W. K., et al., “The Effects of Solution Properties and Polyelectrolyte on Electrospinning of Ultrafine Poly(ethylene oxide) Fibers”, Polymer., 45, 29592966(2004), DOI: 10.1016/j.polymer.2004.03.006Suche in Google Scholar

Tang, S., et al., “Electrospun Nanofibers of Poly(ethylene oxide)/Ttraaminophthalocyanine Copper (II) Hybrids and its Photoluminescence Properties”, J. Phys. Chem. Solids., 68, 23372340(2007), DOI: 10.1016/j.jpcs.2007.07.014Suche in Google Scholar

Theron, S. A., et al., “Experimental Investigation of the Governing Parameters in the Electrospinning of Polymer Solutions”, Polymer., 45, 201730(2004), DOI: 10.1016/j.polymer.2004.01.024Suche in Google Scholar

Valencia, J., et al., “The Influence of Electrospinning Parameters on the Structural Morphology and Diameter of Electrospun Nanofibers”, J. Appl. Polym. Sci., 115, 31303136(2010), DOI: 10.1002/app.31396Suche in Google Scholar

Wang, X., et al., “Electrospun Nanofibrous Membranes for Highly Sensitive optical Sensors”, Nano Letters., 11, 12731275(2002), DOI: 10.1021/nl020216uSuche in Google Scholar

Wunderlich, B.: Thermal Analysis, Academic Press, San Diego(1990)10.1016/B978-0-12-765605-2.50008-XSuche in Google Scholar

Zhang, J. F., et al., “Electrospun Core-shell Structure Nanofibers from Homogeneous Solution of Poly(ethylene oxide)/chitosan”, Macromolecules., 42, 52785284(2009), DOI: 10.1021/ma900657ySuche in Google Scholar

Received: 2010-01-02
Accepted: 2011-01-19
Published Online: 2013-04-06
Published in Print: 2011-09-01

© 2011, Carl Hanser Verlag, Munich

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