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Studies on NBR-ZDMA-OMMT Nanocomposites Prepared by Reactive Mixing Intercalation Method

  • L. Liu , Y. Luo , D. Jia and B. Guo
Published/Copyright: May 2, 2013
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International Polymer Processing
From the journal International Polymer Processing Volume 19 Issue 4

Abstract

Two kinds of nanocomposites of nitrile-butadiene rubber (NBR), zinc methacrylate (ZDMA) and organomontmorillonite (OMMT), NBR-ZDMA-HMMTand NBR-ZDMA-USMMT, were prepared by the reactive mixing intercalation method with ZDMA and two kinds of organomontmorillonite, hexadecyltrimethylammonium bromide modified montmorillonite (HMMT) and unsaturated chemical modified montmorillonite (USMMT). The structure and properties of the nanocomposites were investigated by X-ray diffraction, transmission electron microscopy, differential scanning calorimetry and determination of crosslinking density and mechanical properties. The results showed that the interlayer galleries of HMMT and USMMT were enlarged as ZDMA polymerized in situ in rubber matrix and between the interlayer of the silicates. The layered silicates were dispersed disorderly in rubber matrix at a nanometer level. The crosslinking density of the NBR vulcanizates was increased by the addition of ZDMA and HMMT or USMMT. The glass transition temperatures of the NBR-ZDMA-OMMT nanocomposites were higher than that of the neat NBR. The mechanical properties of the NBR-ZDMA-HMMTand NBR-ZDMA-USMMT nanocomposites are remarkably superior to those of the neat NBR vulcanizate.

∗ Mail address: D. Jia, College of Material Science and Engineering, South China University of Technology, Guangzhou, 510640 China E-mail:

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Received: 2004-2-27
Accepted: 2004-10-25
Published Online: 2013-05-02
Published in Print: 2004-12-01

© 2004, Carl Hanser Verlag, Munich

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. Polymer Processing Society at 20
  5. Mixing and Screw Extrusion
  6. Index for Simultaneous Dispersive and Distributive Mixing Characterization in Processing Equipment
  7. Determination of the Residence Time Distribution in Twin Screw Extruders via Free Radical Modification of PE
  8. On-line Visualization of PS/PP Melting Mechanisms in a Co-rotating Twin Screw Extruder
  9. Die Extrusion
  10. Influence of Filler Particle Geometry on Die Swell
  11. Reactive Processing
  12. Side Chain Extension of Maleated Polypropylene with Diamine
  13. Reactive Batch Mixing for Improved Silica-Silane Coupling
  14. Studies on NBR-ZDMA-OMMT Nanocomposites Prepared by Reactive Mixing Intercalation Method
  15. Fiber and Film
  16. High-speed Melt Spinning of Polyethylene terephthalate with Periodic Oscillation of Take-up Velocity
  17. A Constitutive Analysis of Extensional Flow of EVA Nanocomposites
  18. Laser Sintering
  19. Laser Sintering of High Temperature Resistant Polymers with Carbon Black Additives
  20. Molding
  21. Flow Visualization of Filling with Aid of Colored Billets During Impact Micro-Injection Molding
  22. Modelling of Cyclic 3-Dimensional Heat Transfer in Injection Moulding
  23. PPS News
  24. PPS News
https://doi.org/10.3139/217.1851

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. Polymer Processing Society at 20
  5. Mixing and Screw Extrusion
  6. Index for Simultaneous Dispersive and Distributive Mixing Characterization in Processing Equipment
  7. Determination of the Residence Time Distribution in Twin Screw Extruders via Free Radical Modification of PE
  8. On-line Visualization of PS/PP Melting Mechanisms in a Co-rotating Twin Screw Extruder
  9. Die Extrusion
  10. Influence of Filler Particle Geometry on Die Swell
  11. Reactive Processing
  12. Side Chain Extension of Maleated Polypropylene with Diamine
  13. Reactive Batch Mixing for Improved Silica-Silane Coupling
  14. Studies on NBR-ZDMA-OMMT Nanocomposites Prepared by Reactive Mixing Intercalation Method
  15. Fiber and Film
  16. High-speed Melt Spinning of Polyethylene terephthalate with Periodic Oscillation of Take-up Velocity
  17. A Constitutive Analysis of Extensional Flow of EVA Nanocomposites
  18. Laser Sintering
  19. Laser Sintering of High Temperature Resistant Polymers with Carbon Black Additives
  20. Molding
  21. Flow Visualization of Filling with Aid of Colored Billets During Impact Micro-Injection Molding
  22. Modelling of Cyclic 3-Dimensional Heat Transfer in Injection Moulding
  23. PPS News
  24. PPS News
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