Dry Spinning of Polymer Fibers in Ternary Systems
-
Z. Gou
Abstract
In this work, predictions based on the 2D dry spinning model developed in Part I of this work [2] along with a die swell subroutine supplied by an industrial company, are used to compare with fiber concentration and elongation to break data from an industrial spinline. Die swell ratio predictions agree well with measured values and solidification along the spinline is shown to be due to homogeneous glass transition in the absence of phase separation. Concentration profiles along the spinline are well fit by the model using previously determined prefactors for the diffusion coefficients. A good correlation of elongation at break data is found to occur with a characteristic variable σGTP, the ratio of the rheological force of the viscoelastic Giesekus contribution to the total rheological force (Giesekus + viscous) at the glass transition point. Moreover, the regression obtained from this fit can be further used to make predictions for elongation at break under different operating conditions. Finally, the effects of spinning conditions and model parameters on fiber mechanical properties were investigated.
References
1 Gou, Z., McHugh, A. J.: J. Non-Newtonian Fluid Mech., 118, p. 121 (2004).10.1016/j.jnnfm.2004.03.003Search in Google Scholar
2 Gou, Z., McHugh, A. J.: Int. Polym. Process., 19, p. 244 (2004).Search in Google Scholar
3 Fallon, D. G.: Personal communication (2003).Search in Google Scholar
4 Cappuccio, V., Coen, A., Bertinotti, F., Conti, W.: Chimica e l'Industria (Milan, Italy)44, p. 463 (1962).Search in Google Scholar
5 Bagley, E. B., Storey, S. H., West, D. C.: Journal of Applied Polymer Science7, p. 1661 (1963).10.1002/app.1963.070070508Search in Google Scholar
6 Gaskins, F. H., Philippoff, W.: Transactions of the Society of Rheology3, p. 181 (1959).10.1122/1.548851Search in Google Scholar
7 Walczak, Z. K.: Processes of Fiber Formation. ElsevierAmsterdam (2002).10.1016/B978-008044040-8/50004-XSearch in Google Scholar
8 Cogswell, F. N.: Rheol. Acta8, p. 187 (1969).10.1007/BF01984657Search in Google Scholar
9 Huerlimann, H. P., Knappe, W.: Rheol. Acta11, p. 292 (1972).10.1007/BF01974772Search in Google Scholar
10 Beverly, C. R., Tanner, R. I.: Journal of Rheology33, p. 989 (1989).10.1122/1.550042Search in Google Scholar
11 Sugeng, F., Phan-Thien, N., Tanner, R. I.: Journal of Rheology32, p. 215 (1988).10.1122/1.549970Search in Google Scholar
12 Brazinsky, I., Williams, A. G., Lanieve, H. L.: Polym. Eng. Sci.15, p. 834 (1975).10.1002/pen.760151204Search in Google Scholar
13 Yilmaz, L., McHugh, A. J.: J. Appl. Polym. Sci.31, p. 997 (1986).10.1002/app.1986.070310404Search in Google Scholar
14 Sano, Y.: Drying technology19, p. 1335 (2001).10.1081/DRT-100105292Search in Google Scholar
15 Gou, Z.: Ph. D. Thesis, University of Illinois, Urbana (2003).Search in Google Scholar
© 2004, Carl Hanser Verlag, Munich
Articles in the same Issue
- Contents
- Contents
- Editorial
- Polymer Processing Society Annual Meeting 21
- Screw Extrusion
- Parametric Study of the Mixing Efficiency in a Kneading Block Section of a Twin-screw Extruder
- Experiments on Characteristic Deformation and Breakup Behaviors of an Immiscible Drop in a Screw Channel Flow
- Die Extrusion
- Flow Balancing in Extrusion Dies for Thermoplastic Profiles
- Fiber
- Effects of Sparse Long Chain Branching on the Spinning Stability of LLDPEs
- Dry Spinning of Polymer Fibers in Ternary Systems
- Dry Spinning of Polymer Fibers in Ternary Systems
- Studies on Methacrylate-hydroethyl Methacrylate Oil-absorptive Fiber
- Film
- Numerical and Physical Modeling of Polymer Crystallization
- Numerical and Physical Modeling of Polymer Crystallization
- Modeling
- Study on Viscoelastic Behavior and Extrusion Blow Molding Processability of PP/PE Blends
- Simulation of Thermal Phenomena on the Interface Molten Polymer/Powder Polymer During Rotational Molding
- Effect of Mold Temperature on Structure and Property Variations of PBT Injection Moldings in the Thickness Direction
- Tensile and Flexural Properties of β-Nucleated Polypropylenes
- Predicting the Long-term Creep Behavior of Plastics Using the Short-term Creep Test
- PPS News
- PPS News
Articles in the same Issue
- Contents
- Contents
- Editorial
- Polymer Processing Society Annual Meeting 21
- Screw Extrusion
- Parametric Study of the Mixing Efficiency in a Kneading Block Section of a Twin-screw Extruder
- Experiments on Characteristic Deformation and Breakup Behaviors of an Immiscible Drop in a Screw Channel Flow
- Die Extrusion
- Flow Balancing in Extrusion Dies for Thermoplastic Profiles
- Fiber
- Effects of Sparse Long Chain Branching on the Spinning Stability of LLDPEs
- Dry Spinning of Polymer Fibers in Ternary Systems
- Dry Spinning of Polymer Fibers in Ternary Systems
- Studies on Methacrylate-hydroethyl Methacrylate Oil-absorptive Fiber
- Film
- Numerical and Physical Modeling of Polymer Crystallization
- Numerical and Physical Modeling of Polymer Crystallization
- Modeling
- Study on Viscoelastic Behavior and Extrusion Blow Molding Processability of PP/PE Blends
- Simulation of Thermal Phenomena on the Interface Molten Polymer/Powder Polymer During Rotational Molding
- Effect of Mold Temperature on Structure and Property Variations of PBT Injection Moldings in the Thickness Direction
- Tensile and Flexural Properties of β-Nucleated Polypropylenes
- Predicting the Long-term Creep Behavior of Plastics Using the Short-term Creep Test
- PPS News
- PPS News
