PA612 Double Bubble Tubular Film Process – Processability and Structure Development
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S. Rhee
Abstract
Biaxially oriented Polyamide 612 (PA612) films made by double bubble tubular film extrusion were characterized. The processing characteristics of the polymer in the double bubble process were investigated. The development of crystallinity and orientation in the films was clearly considered. First bubble PA612 films showed a low level of crystallinity (X = 7.7%). Differential scanning calorimetry (DSC) indicated that the first bubble PA 612 films experienced a considerable increase in glass transition temperature (Tg), cold crystallization temperature (Tc) and crystallinity during aging at room conditions. The second bubble films were more highly crystalline (X = 22 to 28%) with poorly grown β unit cells. The WAXD and SAXS patterns showed that the crystallites of double bubble PA612 films became more perfect by annealing in a boiling 20% formic acid solution, resulting in a well-developed triclinic α crystals coexisting with minor proportion of β phase. The WAXD and SAXS patterns indicated that crystallography planes and lamellae in the second bubble films were oriented depending on SBUR × SDDR (second blow-up ratio x second draw down ratio). White-Spruiell biaxial orientation factors were calculated with the WAXD pole figure data. The hydrogen bonding (0k0) planes of biaxial double bubble films were found by WAXD to be aligned parallel to the sheet surface before and after annealing.
© 2001, Carl Hanser Verlag, Munich
Artikel in diesem Heft
- Editorial
- Tenth of a Series: Pioneer of The Polymer Thermoset Industry – Leo-Hendrik Baekeiand
- Screw Extrusion
- Effects of Process Conditions on the Dissolution of Carbon Dioxide in PS in Foaming Extruders
- The Design of Extrusion Screws: An Optimization Approach
- Generalized Flow of Ellis Fluid in the Screw Channel
- Generalized Flow of Ellis Fluid in the Screw Channel
- Experimental Study of Melting in an Intermeshing Counter-Rotating Twin Screw Extruder
- Reactive Extrusion
- A Dynamic Model for Multiple Steady States in Reactive Extrusion
- Fiber and Film
- PA612 Double Bubble Tubular Film Process – Processability and Structure Development
- Injection Molding
- Injection Molding Technology for High Speed Optical Disk
- Three-dimensional Filling and Post-filling Simulation of Polymer Injection Molding
- Cold Rolling
- Microstructure and Prediction of Stress-strain Behaviour of Cold-rolled PP Sheets
Artikel in diesem Heft
- Editorial
- Tenth of a Series: Pioneer of The Polymer Thermoset Industry – Leo-Hendrik Baekeiand
- Screw Extrusion
- Effects of Process Conditions on the Dissolution of Carbon Dioxide in PS in Foaming Extruders
- The Design of Extrusion Screws: An Optimization Approach
- Generalized Flow of Ellis Fluid in the Screw Channel
- Generalized Flow of Ellis Fluid in the Screw Channel
- Experimental Study of Melting in an Intermeshing Counter-Rotating Twin Screw Extruder
- Reactive Extrusion
- A Dynamic Model for Multiple Steady States in Reactive Extrusion
- Fiber and Film
- PA612 Double Bubble Tubular Film Process – Processability and Structure Development
- Injection Molding
- Injection Molding Technology for High Speed Optical Disk
- Three-dimensional Filling and Post-filling Simulation of Polymer Injection Molding
- Cold Rolling
- Microstructure and Prediction of Stress-strain Behaviour of Cold-rolled PP Sheets
