Correlation between Injection Molding Parameters, Morphology and Mechanical Properties of PPS/SEBS Blend Using Artificial Neural Networks
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C. Lotti
Abstract
The objectives of this work were to identify the injection molding processing variables with the greatest effect on the morphology and mechanical properties of an injection molded blend made of poly (p-phenylene sulphide), PPS and block copolymer styrene-ethylene-butadiene-styrene ‘SEBS’. Artificial Neural Networks, ANNs, are used as an alternative method to constitutive and empirical models, to predict morphological features and mechanical properties from the injection molding conditions, and to predict mechanical properties from the morphological features.
The quantification of SEBS dispersion in the PPS matrix was done using a dispersion function. Mold temperature and flow rate were the processing variables with the highest influence on the entire morphology, while the holding pressure influenced mainly the inner layers. Impact strength and toughness were most influenced by mold temperature, holding pressure and the outer layers. The flexural modulus was influenced by all processing variables and the intermediate layers.
Three different ANNs were evaluated: one (ANN-1) to predict morphology from processing conditions and another two to predict mechanical properties from morphology and from processing conditions (ANN-2 and ANN-3, respectively). These latter ANN models had similar results, indicating that both inputs could be successfully used to predict mechanical properties, as the mean residuals were close to experimental errors. On the other hand, ANN-1 showed a lower performance, with a mean error smaller than the experimental error, suggesting that ANNs could overtake some inherent uncertainties.
In this case, it was concluded that the distribution of data along output domain was more important than a high number of training data in the ANN's performance.
References
1Deyrail, Y., Fulchiron, R., Cassagnau, P.: Polym. 43, p. 3311 (2002)10.1016/S0032-3861(02)00134-9Search in Google Scholar
2Osswald, T. A., Menges, G.: Materials Science of Polymers for Engineers. Hanser Publishers, Munich, Vienna, New York (1995)Search in Google Scholar
3Son, Y., Ahn, K. N., Char, K.: Polym. Eng. Sci. 40, p. 1376 (2000)10.1002/pen.11267Search in Google Scholar
4Son, Y., Ahn, K. N., Char, K.: Polym. Eng. Sci. 40, p. 1385 (2000)10.1002/pen.11268Search in Google Scholar
5Hage, E., Hale, W., Keskkula, H., Paul, D. R.: Polym. 38, p. 3237 (1997)10.1016/S0032-3861(96)00879-8Search in Google Scholar
6Li, Z., Narh, K. A.: Compos. Part B32, p. 103 (2001)10.1016/S1359-8368(00)00046-9Search in Google Scholar
7Hay, J. N., Luck, D. A.: Polym. 42, p. 8297 (2001)10.1016/S0032-3861(01)00335-4Search in Google Scholar
8Lotti, C., Bretas, R. E. S.: Intern. Polym. Process. 2, p. 104 (2006)Search in Google Scholar
9Moldflow user's manual, v. 4. 1 (2004)Search in Google Scholar
10Bretas, R. E. S., Colias, D., Baird, D. G.: Polym. Eng. Sci. 34, p. 1492 (1994).10.1002/pen.760341909Search in Google Scholar
11Ito, E. N., Pessan, L. A., Covas, J. A., HageJr., E.: Intern. Polym. Process. 4, p. 376 (2003)10.3139/217.1780Search in Google Scholar
12ScobboJr., J. J., in: Polymer blends: Performance. Paul, D. R., Bucknall, C. B. (Eds.), John Wiley & Sons, New York, Chichester, Weinhein, Brisbane, Singapore, Toronto (2000)Search in Google Scholar
13SNNS – “Stuttgart Neural Network Simulator”, User's guide, version 4.2, University of Tübingen, Denmark, www-ra.informatik.uni-tuebingen.de/SNNSSearch in Google Scholar
14Twomwy, J. M., Smith, A. E., in: Artificial Neural Networks for Civil Engineers: Fundamentals and Applications, ASCE Press (1996)Search in Google Scholar
© 2007, Carl Hanser Verlag, Munich
Articles in the same Issue
- Contents
- Contents
- Editorial
- International Polymer Processing Special Issue: European Coating Symposium 2005, University of Bradford, UK
- Invited Papers
- Coating and Polymer Processing
- Practical Limitations to Carrier Layer Formation on Inclined Planes
- Simulation of 3D Crystallization of Colloidal Nanoparticles on a Substrate during Drying
- Asymmetric Surface Roughness Formationon Moving Non-isothermal Liquid Coatings
- Inkjet Printing of Conductive and Resistive Coatings
- Moisture Sorption and Transport in Polylactide
- 10.3139/217.0992
- Review Article
- Welding of Plastics: Fundamentals and New Developments
- Regular Contributed Articles
- Numerical Simulation of Viscous Flow in a Partially filled Co-rotating Twin Screw Extruder
- Invited Papers
- A New Calculation Model and Optimization Method for Maddock Mixers in Single Screw Plasticising Technology
- Regular Contributed Articles
- Residual Wall Thickness Distribution at the Transition and Curve Sections of Water-assisted Injection Molded Tubes
- Numerical Simulation of Extrusion Coating
- Correlation between Injection Molding Parameters, Morphology and Mechanical Properties of PPS/SEBS Blend Using Artificial Neural Networks
- PPS News
- PPS News
- Seikei-Kakou Abstracts
- Seikei-Kakou Abstracts
Articles in the same Issue
- Contents
- Contents
- Editorial
- International Polymer Processing Special Issue: European Coating Symposium 2005, University of Bradford, UK
- Invited Papers
- Coating and Polymer Processing
- Practical Limitations to Carrier Layer Formation on Inclined Planes
- Simulation of 3D Crystallization of Colloidal Nanoparticles on a Substrate during Drying
- Asymmetric Surface Roughness Formationon Moving Non-isothermal Liquid Coatings
- Inkjet Printing of Conductive and Resistive Coatings
- Moisture Sorption and Transport in Polylactide
- 10.3139/217.0992
- Review Article
- Welding of Plastics: Fundamentals and New Developments
- Regular Contributed Articles
- Numerical Simulation of Viscous Flow in a Partially filled Co-rotating Twin Screw Extruder
- Invited Papers
- A New Calculation Model and Optimization Method for Maddock Mixers in Single Screw Plasticising Technology
- Regular Contributed Articles
- Residual Wall Thickness Distribution at the Transition and Curve Sections of Water-assisted Injection Molded Tubes
- Numerical Simulation of Extrusion Coating
- Correlation between Injection Molding Parameters, Morphology and Mechanical Properties of PPS/SEBS Blend Using Artificial Neural Networks
- PPS News
- PPS News
- Seikei-Kakou Abstracts
- Seikei-Kakou Abstracts