Experimental measurement and thermodynamic model predictions of the distributions of Cu, As, Sb and Sn between liquid lead and PbO–FeO–Fe2O3–SiO2 slag

Denis Shishin; Taufiq Hidayat; Ummul Sultana; Maksym Shevchenko; Evgueni Jak

doi:10.3139/146.111942

Artikel

Experimental measurement and thermodynamic model predictions of the distributions of Cu, As, Sb and Sn between liquid lead and PbO–FeO–Fe₂O₃–SiO₂ slag

Denis Shishin , Taufiq Hidayat , Ummul Sultana , Maksym Shevchenko und Evgueni Jak

Veröffentlicht/Copyright: 7. September 2020

Veröffentlicht von

Veröffentlichen auch Sie bei De Gruyter Brill

Informationen für Autor*innen

Aus der Zeitschrift International Journal of Materials Research Band 111 Heft 9

Abstract

Due to the increasing complexity of materials processed in primary and secondary lead smelting, better control of impurity elements is required. In the present study, distributions of Cu, As, Sb and Sn between PbO–FeO–Fe₂O₃–SiO₂ slag and Pb metal are characterized experimentally and analyzed using thermodynamic calculations. Experimental methodology involved closed-system equilibration of sample mixtures at high temperature followed by rapid quenching. The compositions of phases were measured using electron probe X-ray microanalysis and laser ablation inductively coupled plasma mass spectrometry. Thermodynamic calculations were performed using the FactSage software coupled with an internal thermodynamic database. Experimentally obtained distribution coefficients wt.% in slag/wt.% in metal at 1 200 °C (1 473 K) follow the sequence Sn >> Cu > As ≈ Sb at P(O₂) < 10^−9.5 atm and Sn >> As ≈ Sb > Cu at P(O₂) > 10^−8.5 atm. Model predictions are in good agreement with the experiment.

Keywords: Lead recycling; Lead smelting; Arsenic distribution; Antimony distribution; FactSage; Minor elements

∗ Correspondence address, Denis Shishin, Pyrometallurgy Innovation Center, School of Chemical Engineering, The University of Queensland, Brisbane QLD 4072, Australia, Tel.: +61 7 3443 2714, d.shishin@uq.edu.au, ORCIDs: Denis Shishin 0000-0003-2734-1078, Taufiq Hidayat 0000-0002-1326-2427, Ummul Khair Sultana 0000-0002-9535-384X, Maksym Shevchenko 0000-0002-9420-9336, Evgueni Jak 0000-0002-7768-1874

References

[1] R.J. Sinclair : The Extractive Metallurgy of Lead, AusIMM (2009).Suche in Google Scholar

[2] A. Siegmund , in: F.Kongoli, K.Itagaki, C.Yamaguchi, H.Y.Sohn (Eds.), Metallurgical and Materials Processing, Vol 2, TMS (2003) 43.Suche in Google Scholar

[3] S. Yan , D.R.Swinbourne: Trans. Inst. Min. Metall., Sect. C.112 (2003) C75. 10.1179/037195503225002763Suche in Google Scholar

[4] D.R. Swinbourne , S.Yan, A.Yazawa, in: F.Kongoli, K.Itagaki, C.Yamaguchi, H.Y.Sohn (Eds.), Metallurgical and Materials Processing, Vol 2, TMS (2003) 1111.Suche in Google Scholar

[5] E.A. Johnson , L.L.Oden, J.N.Koch: Report of Investigations 8753, U.S. Department of the Interior, Bureau of Mines, Albany (1983).Suche in Google Scholar

[6] G.B. Hoang , D.R.Swinbourne: Trans. Inst. Min. Metall., Sect. C.116 (2007) 133. 10.1179/174328507x163850Suche in Google Scholar

[7] D. Shishin , T.Hidayat, U.Sultana, M.Shevchenko, E.Jak: J. Sustain. Metall.6 (2019) 68. 10.1007/s40831-019-00257-3Suche in Google Scholar

[8] M. Perez , A.Romero, A.Hernandez, I.Almaguer, R.Benavides: Revista de Metalurgia48 (2012) 213. 10.3989/revmetalm.1150Suche in Google Scholar

[9] J. Chaidez-Felix , A.Romero-Serrano, A.Hernandez-Ramirez, M.Peraz-Labra, I.Almaguer-Guzman, R.Benavides-Perez, M.Flores-Favela: Trans. Nonferrous Met. Soc. China.24 (2014) 1202. 10.1016/s1003-6326(14)63180-0Suche in Google Scholar

[10] G.T. Fisher, II, K.O.Bennington: Report of Investigations 9369, U.S. Department of the Interior, Bureau of Mines, Albany (1991).Suche in Google Scholar

[11] T. Rytkonen , A.Taskinen: Scand. J. Metall.15 (1986) 25.Suche in Google Scholar

[12] T.K. Rytkonen , A.I.Klarin: Scand. J. Metall.16 (1987) 210. 10.3109/01050398709074942Suche in Google Scholar

[13] A.G. Matyas , in: Z.A.Foroulis, W.W.Smeltzer (Eds.), Metal–Slag–Gas reactions and processes, The Electrochemical Society Inc., Princeton, (1975) 999.Suche in Google Scholar

[14] A.E. Shiel , D.Weis, K.J.Orians: Science of the Total Environment48 (2010) 2357. PMid:20206962; 10.1016/j.scitotenv.2010.02.016Suche in Google Scholar PubMed

[15] N. Moon , M.Hino, Y.Lee, K.Itagaki: Metallurgical Review for MMIJ.15 (1998) 38. 10.2473/shigentosozai.114.121Suche in Google Scholar

[16] E. Jak , M.Shevchenko, D.Shishin, T.Hidayat, P.C.Hayes, in: A.Siegmund, S.Alam, J.Grogan, U.Kerney, E.Shibata (Eds.) PbZn 2020: 9th International Symposium on Lead and Zinc Processing. The Minerals, Metals & Materials Series. Springer, Cham (2020) 337. 10.1007/978-3-030-37070-1_30Suche in Google Scholar

[17] D. Shishin , M.Shevchenko, V.Prostakova, P.C.Hayes, E.Jak, in: MOLTEN 2020, 11th Molten Slags, Fluxes and Salts (accepted for publication 2020).Suche in Google Scholar

[18] E. Jak , P.C.Hayes, H.-G.Lee: Korean Journal of Minerals and Materials Institute (Seoul).1 (1995) 1. 10.1007/BF03055319Suche in Google Scholar

[19] E. Jak in: 9th Intl. Conf. on Molten Slags, Fluxes and Salts (MOLTEN12), The Chinese Society for Metals (2012).Suche in Google Scholar

[20] M. Shevchenko , E.Jak: Metall. Mater. Trans. B49 (2018) 159. 10.1007/s11663-017-1136-0Suche in Google Scholar

[21] C.W. Bale , E.Belisle, P.Chartrand, S.A.Decterov, G.Eriksson, A.E.Gheribi, K.Hack, I.H.Jung, Y.B.Kang, J.Melancon, A.D.Pelton, S.Petersen, C.Robelin, J.Sangster, P.Spencer, M.A.Van Ende: CALPHAD.54 (2016) 35. 10.1016/j.calphad.2016.05.002Suche in Google Scholar

[22] A. Fallah-Mehrjardi , T.Hidayat, P.C.Hayes, E.Jak: Metall. Mater. Trans. B48 (2017). 10.1007/s11663-017-1073-ySuche in Google Scholar

[23] J. Chen , C.M.Allen, T.Azekenov, L.A.Ushkov, P.Hayes, E.Jak, in: Copper 2016, Kobe, Japan, (2016). 10.1145/2854065.2854075Suche in Google Scholar

[24] L. Klemettinen , K.Avarmaa, H.O'Brien, P.Taskinen: Minerals.9 (2019) 1. 10.3390/min9010039Suche in Google Scholar

[25] D. Shishin , P.C.Hayes, E.Jak, in: Davis, B., Moats, M., Wang, S., Gregurek, D., Kapusta, J., Battle, Th.P., Schlesinger, M., Alvear Flores, G.R., Jak, E., Goodall, G., Free, M.L., Asselin, E., Chagnes, A., Dreisinger, D., Jeffrey, M., Lee, J., Miller, G., Petersen, J., Ciminelli, V., Xu, Q., Molnar, R., Adams, J., Liu, W., Verbaan, N., Goode, J., London, I., Azimi, G., Forstner, A., Kappes, R., Bhambhani, T. (Eds.), Extraction 2018, The Minerals, Metals & Materials Series. Springer, Cham (2018) 853. 10.1007/978-3-319-95022-8_68Suche in Google Scholar

[26] A.D. Pelton , S.A.Decterov, G.Eriksson, C.Robelin, Y.Dessureault: Metall. Mater. Trans. B.31 (2000) 651. 10.1007/s11663-000-0103-2Suche in Google Scholar

[27] A.D. Pelton , P.Chartrand: Metall. Mater. Trans. A32 (2001) 1355. 10.1007/s11661-001-0226-3Suche in Google Scholar

[28] M. Hillert : J. Alloys Compd.320 (2001) 161. 10.1016/S0925-8388(00)01481-XSuche in Google Scholar

[29] T. Hidayat , D.Shishin, E.Jak, S.Decterov: CALPHAD48 (2015) 131. 10.1016/j.calphad.2014.12.005Suche in Google Scholar

[30] G. Eriksson , A.D.Pelton: Metall. Trans.24 (1993) 807. 10.1007/BF02663141Suche in Google Scholar

[31] D. Shishin , J.Chen, T.Hidayat, E.Jak: J. Phase Equilib. Diff.40 (2019) 758. 10.1007/s11669-019-00764-6Suche in Google Scholar

[32] F.H. Hayes , H.L.Lukas, G.Effenberg, G.Petzow: Z. Metallkd.77 (1986) 749.Suche in Google Scholar

[33] H. Ohtani , K.Okuda, K.Ishida: J. Phase Equilib.16 (1995) 416. 10.1007/BF02645349Suche in Google Scholar

[34] G. Ghosh : Metall. Mater. Trans. A30 (1999) 1481. 10.1007/s11661-999-0085-xSuche in Google Scholar

[35] D. Shishin , E.Jak: CALPHAD60 (2018) 134. 10.1016/j.calphad.2017.12.005Suche in Google Scholar

[36] X.J. Liu , C.P.Wang, I.Ohnuma, R.Kainuma, K.Ishida: J. Phase Equilib.21 (2000) 432. 10.1361/105497100770339608Suche in Google Scholar

[37] W. Gierlotka , S.-W.Chen, S.-K.Lin: J. Mater. Res.22 (2007) 3158. 10.1557/jmr.2007.0396Suche in Google Scholar

[38] D. Risold , J.-I.Nagata, R.O.Suzuki: J. Phase Equilib.19 (1998) 213. 10.1361/105497198770342238Suche in Google Scholar

[39] D. Shishin , S.A.Decterov: CALPHAD38 (2012) 59. 10.1016/j.calphad.2012.04.002Suche in Google Scholar

[40] I. Vaajamo , P.Taskinen: Thermochimica Acta.524 (2011) 56. 10.1016/j.tca.2011.06.014Suche in Google Scholar

[41] D. Shishin , V.Prostakova, E.Jak, S.Decterov: Metall. Mater. Trans. B47 (2016) 397. 10.1007/s11663-015-0493-9Suche in Google Scholar

[42] T. Hidayat , D.Shishin, S.A.Decterov, E.Jak: J. Phase Equilib. Diffus.38 (2017) 477. 10.1007/s11669-017-0535-xSuche in Google Scholar

[43] M. Shevchenko , E.Jak: Calphad.64 (2019) 318. 10.1016/j.calphad.2019.01.011Suche in Google Scholar

[44] M. Shevchenko : PhD thesis, Integrated experimental and thermodynamic modelling research on the multicomponent Pb–Cu–Fe–Zn–Ca–Si–O system, The University of Queensland, Australia, (2019). 10.14264/uql.2019.410Suche in Google Scholar

[45] M. Shevchenko , E.Jak: Calphad.67 (2019). 10.1016/j.calphad.2019.101670Suche in Google Scholar

[46] T. Hidayat , E.Jak: Int. J. Mater. Res.105 (2014) 249. 10.3139/146.111023Suche in Google Scholar

[47] U. Kuxmann , K.Kurre: Erzmetall.21 (1968) 199.Suche in Google Scholar

[48] D. Shishin , T.Hidayat, J.Chen, P.C.Hayes, E.Jak: J. Chem. Thermodyn.135 (2018) 175. 10.1016/j.jct.2019.02.029Suche in Google Scholar

[49] D. Shishin , T.Hidayat, J.Chen, P.C.Hayes, E.Jak: Calphad.65 (2019) 16. 10.1016/j.calphad.2019.01.016Suche in Google Scholar

[50] S. Firoozi , R.Harris: Metall. Mater. Trans. B38, (2007) 425. 10.1007/s11663-007-9054-1Suche in Google Scholar

[51] S. Firoozi : PhD thesis, Thermodynamics and mechanisms of lead softening, McGill University, Canada, (2005).Suche in Google Scholar

[52] Y. Takeda , S.Ishiwata, A.Yazawa: Trans. Jpn. Inst. Met.24 (1983) 518. 10.2320/matertrans1960.24.518Suche in Google Scholar

[53] T. Hidayat , D.Shishin, S.Decterov, E.Jak: CALPHAD.58 (2017) 101. 10.1016/j.calphad.2017.06.003Suche in Google Scholar

[54] I. Barin : Thermochemical Data of Pure Substances, Third Edition, Wiley-VCH, Germany (1995). 10.1002/9783527619825Suche in Google Scholar

[55] M. Kopyto , W.Przybylo, B.Onderka, K.Fitzner: Arch. Metall. Mater.54 (2009) 811.Suche in Google Scholar

[56] T. Yin : PhD thesis, Coupled thermodynamic modeling and experimental study of SnO₂–SnO–CaO–SiO₂ system, McGill University, Canada (2017).Suche in Google Scholar

[57] M. Shevchenko , E.Jak: J. Phase Equilib. Diff.40 (2019) 319. 10.1007/s11669-019-00727-xSuche in Google Scholar

[58] M.J. Hollitt , G.M.Willis, J.M.Floyd, in: H.A.Fine, D.R.Gaskell (Eds.), 2nd Intl. Symp. on Metallurgical Slags and Fluxes, The Metallurgical Society of AIME, (1984) 497.Suche in Google Scholar

Received: 2020-02-16

Accepted: 2020-06-15

Published Online: 2020-09-07

Published in Print: 2020-09-16

Sie haben derzeit keinen Zugang zu diesem Inhalt.

Artikel in diesem Heft

https://doi.org/10.3139/146.111942

Schlagwörter für diesen Artikel

Lead recycling; Lead smelting; Arsenic distribution; Antimony distribution; FactSage; Minor elements