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Thermodynamics of liquid Au–Sb–Sn

  • Peter Terzieff , Michael Hindler , Adolf Mikula and Herbert Ipser
Published/Copyright: May 31, 2013
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 103 Issue 12

Abstract

The thermodynamic properties of liquid Au–Sb–Sn are discussed with regard to the energetics of the system. The analysis in terms of the partial excess Gibbs energies and the partial enthalpies of mixing indicates that the presence of Sb in the alloys is energetically unfavourable. In addition, this is found also to be reflected by the concentration–concentration correlations in the long-wavelength limit, Sccij, which are representative of the fluctuations in local composition occuring in the system. It is suggested that the analysis of the partial quantities in the system might give an extremely helpful contribution to understanding the energetics of multi-component systems.

Keywords: Liquid alloys; Thermodynamic properties; Concentration fluctuations
* Correspondence address, Peter Terzieff, Institut für Anorganische Chemie/Materialchemie, Universität Wien, Währingerstrasse 42, A-1090 Wien, Austria. Tel.: +431427752908, Fax: +43142779529, E-mail:

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Received: 2011-11-2
Accepted: 2012-6-18
Published Online: 2013-05-31
Published in Print: 2012-12-01

© 2012, Carl Hanser Verlag, München

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https://doi.org/10.3139/146.110818
Keywords for this article
Liquid alloys; Thermodynamic properties; Concentration fluctuations

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. Effect of texture on grain growth in an interstitial-free steel sheet
  5. Nanoindentation of pseudoelastic NiTi containing Ni4Ti3 precipitates
  6. Isochronal annealing of a deformed Fe-7.5 mass.% Si-steel
  7. Modelling of three powder compaction laws for cold die pressing
  8. Surface tension and density of liquid Sn–Ag–Cu alloys
  9. Thermodynamics of liquid Au–Sb–Sn
  10. Phase relations in the ZrO2-Sm2O3-Y2O3-Al2O3 system: experimental investigation and thermodynamic modelling
  11. Contributions of phase composition and defect structure to the long term stability of Li/MgO catalysts
  12. First and second differentials of the ultrasonic parameter as an effective tool to identify phase transitions in R1-xAxMnO3 perovskites
  13. Surface oxide layer formation on Au-Pt-Pd-Si alloys for dental resin restorations
  14. On the high temperature stability of γ-Al2O3/Ti0.33Al0.67N coated WC–Co cutting inserts
  15. Optimizing composition for (Nd, Pr)–Nb–Fe–B hard magnetic nanocomposites
  16. Simple ionic-liquid assisted method for preparation of Cd1-xZnxS nanoparticles with improved photocatalytic activity
  17. A low-cost route for synthesizing tungsten disulfide film composites from abundant sprayed oxides: Technique and characterization
  18. Anodic behavior of Al–Zn–In sacrificial anodes at different concentration of zinc and indium
  19. Short Communications
  20. Effect of molybdenum addition on fracture toughness and hardness of Fe2B in Fe–B–C cast alloy
  21. DGM News
  22. DGM News
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