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Phase equilibria in the Sn–Zn–Ni system

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Veröffentlicht/Copyright: 11. Juni 2013
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International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 102 Heft 3

Abstract

The objective of this study is to elucidate the phase equilibria of the Sn–Zn–Ni system. For this purpose, ternary alloys were synthesized using quartz ampoules and annealing. The samples were characterized using differential scanning calorimetry, X-ray diffraction, optical and scanning electron microscopy and microhardness measurements. The results show relatively significant solubility of tin or zinc (about 10 at.% roughly) in Ni–Zn and Ni–Sn phases, respectively. Moreover, evidence of the presence of two formerly unknown ternary compounds denoted as T1 and T2 was found. The first one has a composition (mole fraction) of about: XSn = 0.38 ± 0.04, XNi = 0.36 ± 0.02, XZn = 0.26 ± 0.03 while the approximate composition of the second is XSn = 0.26 ± 0.03, XNi = 0.55 ± 0.00, XZn = 0.19 ± 0.03. Three unidentified compositions were observed: U1 (XSn = 0.26 ± 0.07, XNi = 0.29 ± 0.03, XZn = 0.45 ± 0.04), U2 (XSn = 0.55 ± 0.01, XNi = 0.21 ± 0.00, XZn = 0.24 ± 0.01), and U3 (XSn = 0.48 ± 0.05, XNi = 0.08 ± 0.00, XZn = 0.44 ± 0.05) but there was still a lack of evidence to categorize any of them as a ternary compound. A tentative isothermal section of the Sn–Zn–Ni phase diagram at 600 °C was constructed.

Keywords: Phase diagram; Sn–Zn–Ni system; Lead-free solders; Ternary compounds
* Correspondence address, Professor Gueorgui Penev Vassilev, University of Plovdiv, Faculty of Chemistry, Dept. Inorganic Chemistry, Tzar Asen str., 24, 4000 Plovdiv, Bulgaria. Tel.: +359 32 261 403, Fax: +359 32 261 402, E-mail:

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Received: 2010-2-21
Accepted: 2010-12-12
Published Online: 2013-06-11
Published in Print: 2011-03-01

© 2011, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Experimental investigation and thermodynamic calculation of the Zn–Al–Sb system
  5. Determination of liquidus temperature in Ti-rich alloys of the Fe–Ni–Ti system obtained by DTA, electrical conductivity and XRD measurements
  6. Phase equilibria in the Sn–Zn–Ni system
  7. Phase equilibria studies in alumina-containing high zinc fayalite slags with CaO/SiO2 = 0.55 Part 2
  8. Mixing enthalpies in liquid alloys of manganese with the lanthanides
  9. Some thermophysical properties of the intermetallic Ti40Al60 alloy in the melting-solidification temperature range
  10. Thermodynamic modelling of the Ag–Cu–Ti ternary system
  11. Reaction synthesis and wear resistance of a TiCp/Ni3Al-Fe composite coating on steel
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  14. A micromechanical analysis of local contact at die compaction of powder materials
  15. Numerical simulation for the determination of the limit drawing ratio of a cold rolled and solution treated Nimonic C-263 alloy sheet
  16. One-dimensional red photoluminescence of (Y,Gd)BO3 nanofibers doped with Eu3+
  17. Chloride penetration and corrosion resistance of ground fly ash blended cement mortar
  18. Optical and thermodynamic studies of silver nanoparticles stabilized by Daxad 19 surfactant
  19. DGM News
  20. DGM News
https://doi.org/10.3139/146.110481
Schlagwörter für diesen Artikel
Phase diagram; Sn–Zn–Ni system; Lead-free solders; Ternary compounds

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Experimental investigation and thermodynamic calculation of the Zn–Al–Sb system
  5. Determination of liquidus temperature in Ti-rich alloys of the Fe–Ni–Ti system obtained by DTA, electrical conductivity and XRD measurements
  6. Phase equilibria in the Sn–Zn–Ni system
  7. Phase equilibria studies in alumina-containing high zinc fayalite slags with CaO/SiO2 = 0.55 Part 2
  8. Mixing enthalpies in liquid alloys of manganese with the lanthanides
  9. Some thermophysical properties of the intermetallic Ti40Al60 alloy in the melting-solidification temperature range
  10. Thermodynamic modelling of the Ag–Cu–Ti ternary system
  11. Reaction synthesis and wear resistance of a TiCp/Ni3Al-Fe composite coating on steel
  12. A novel method for Al/SiC composite fabrication: Lost foam casting
  13. Three-dimensional braided fabrics-reinforced composites for load-bearing orthopedic applications Part I: mechanical performance
  14. A micromechanical analysis of local contact at die compaction of powder materials
  15. Numerical simulation for the determination of the limit drawing ratio of a cold rolled and solution treated Nimonic C-263 alloy sheet
  16. One-dimensional red photoluminescence of (Y,Gd)BO3 nanofibers doped with Eu3+
  17. Chloride penetration and corrosion resistance of ground fly ash blended cement mortar
  18. Optical and thermodynamic studies of silver nanoparticles stabilized by Daxad 19 surfactant
  19. DGM News
  20. DGM News
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