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Thermodynamic properties of liquid silver–indium–tin alloys determined from emf measurements

  • Dominika Jendrzejczyk-Handzlik , Wojciech Gierlotka and Krzysztof Fitzner
Published/Copyright: June 11, 2013
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 99 Issue 11

Abstract

The thermodynamic properties of liquid Ag – Sn – In alloys were determined using solid oxide galvanic cells with zirconia electrolyte. The following galvanic cells were employed:

Re + kanthal, Agx – Iny – Sn(1−x−y),(In2O3)s.s//ZrO2 + (Y2O3)//NiO, Ni, Pt(I)

in the temperature range from 973 to 1273 K, and in the range of indium mole fraction from 0.3 to 0.8.

This limitation was imposed by the side reaction between tin in the liquid alloy and solid In2O3. It was also found that the liquid is in equilibrium with the solid solution of oxides. Calorimetric measurements of the heat of mixing were also carried out at constant temperature 1003 K and along one isopleth with XAg/XSn = 1/1.

The thermodynamic properties of the liquid phase were described by the Redlich – Kister – Muggianu formula and the phase relations in the ternary system were calculated. The results of calculations were compared with the experimental data which are available from different literature sources.

Keywords: Thermodynamic properties; Ag – In – Sn; Redlich – Kister – Muggianu formula; emf measurements
* Correspondence address, Dominika Jendrzejczyk-Handzlik, AGH University of Science and Technology, Mickiewicza Ave 30, 30-059 Krakow, Poland, Tel.: +48 12 617 41 25, E-mail:

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Received: 2007-7-15
Accepted: 2008-5-14
Published Online: 2013-06-11
Published in Print: 2008-11-01

© 2008, Carl Hanser Verlag, München

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https://doi.org/10.3139/146.101755
Keywords for this article
Thermodynamic properties; Ag – In – Sn; Redlich – Kister – Muggianu formula; emf measurements

Articles in the same Issue

  1. Contents
  2. Contents
  3. Basic
  4. A model to calculate the viscosity of silicate melts
  5. A model to calculate the viscosity of silicate melts
  6. A note on the application of the phase rule
  7. Thermodynamic properties of liquid silver–indium–tin alloys determined from emf measurements
  8. Unconstrained solidification and characterisation of near-eutectic Al–Cu–Ag alloys
  9. Tensile properties of L12 intermetallic foils fabricated by cold rolling
  10. Microstructural control of FeB-inoculated mottled low-alloy white iron by a design of experiments approach
  11. Applied
  12. Dislocation structure and crystallite size distribution in lath martensite determined by X-ray diffraction peak profile analysis
  13. Effect of minor addition of Pb upon interfacial reactions and mechanical properties at Sn-3.0Ag-0.5Cu/Cu and Sn-58Bi/Cu solder joints
  14. Elastic properties of braided ceramic matrix composites
  15. The influence of microstructural characteristics and contaminants on the mechanical properties and fracture topography of low cost Ti6Al4V alloy
  16. Microstructure and room temperature mechanical properties of Hf and Sn-doped Nb-20Ti-5Cr-3Al-18Si alloy
  17. The effect of alloying elements on constrained carbon equilibrium due to a quench and partition process
  18. Hardfacing behavior of Cr–Ni stainless steel with Co-based super alloys
  19. Development of SMD 32.768 kHz tuning fork-type crystals
  20. Notification
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