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A model to calculate the viscosity of silicate melts

Part I: Viscosity of binary SiO2#x2013;MeOx systems (Me = Na, K, Ca, Mg, Al)
  • A. Nicholas Grundy , Honqin Liu , In-Ho Jung , Sergei A. Decterov und Arthur D. Pelton
Veröffentlicht/Copyright: 11. Juni 2013
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International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 99 Heft 11

Abstract

A model has been developed that links the viscosities of silicate melts to their thermodynamic properties. Over the past several years, through critical evaluation of all available thermodynamic and phase equilibrium data, we have developed a quantitative thermodynamic description of multicomponent silicate melts using the Modified Quasichemical Model for short-range ordering. The local structure of the liquid, in terms of the bridging behavior of oxygen, calculated using our thermodynamic model allows us to characterize the structure of the liquid semi-quantitatively using the concepts of Q-species and connectivity of Q-species. The viscosity is modeled by optimizing viscosity parameters that are related to the structure of the liquid. The viscosity of pure liquid silica is modeled using four model parameters and every other unary liquid is modeled using two. The viscosity of all binary liquids is reproduced within experimental accuracy by optimizing one or at most two binary viscosity parameters for each system. In the present article the equations for the viscosity model are derived and analyses for the experimentally well-established systems CaO – SiO2 MgO – SiO2, NaO0.5 – SiO2, KO0.5 – SiO2 and AlO1.5 – SiO2 are presented. This is the first step in the development of a predictive model for the viscosity of multicomponent silicate melts that will be presented in part II.

Keywords: Viscosity; Thermodynamic modeling; Silicates; Slags; Glass melts
* Correspondence address, Prof. Dr. Arthur D. Pelton, Centre de Recherche en Calcul Thermochimique, Genie Chimique, École Polytechnique de Montréal, C.P. 6079, Station Centre-ville, Montréal (QC), Canada. H3C 3A7, Tel.: +1 514 340 4770, Fax: +1 514 340 5840, E-mail:

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Received: 2007-10-2
Accepted: 2008-2-20
Published Online: 2013-06-11
Published in Print: 2008-11-01

© 2008, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Basic
  4. A model to calculate the viscosity of silicate melts
  5. A model to calculate the viscosity of silicate melts
  6. A note on the application of the phase rule
  7. Thermodynamic properties of liquid silver–indium–tin alloys determined from emf measurements
  8. Unconstrained solidification and characterisation of near-eutectic Al–Cu–Ag alloys
  9. Tensile properties of L12 intermetallic foils fabricated by cold rolling
  10. Microstructural control of FeB-inoculated mottled low-alloy white iron by a design of experiments approach
  11. Applied
  12. Dislocation structure and crystallite size distribution in lath martensite determined by X-ray diffraction peak profile analysis
  13. Effect of minor addition of Pb upon interfacial reactions and mechanical properties at Sn-3.0Ag-0.5Cu/Cu and Sn-58Bi/Cu solder joints
  14. Elastic properties of braided ceramic matrix composites
  15. The influence of microstructural characteristics and contaminants on the mechanical properties and fracture topography of low cost Ti6Al4V alloy
  16. Microstructure and room temperature mechanical properties of Hf and Sn-doped Nb-20Ti-5Cr-3Al-18Si alloy
  17. The effect of alloying elements on constrained carbon equilibrium due to a quench and partition process
  18. Hardfacing behavior of Cr–Ni stainless steel with Co-based super alloys
  19. Development of SMD 32.768 kHz tuning fork-type crystals
  20. Notification
  21. DGM News
https://doi.org/10.3139/146.101752
Schlagwörter für diesen Artikel
Viscosity; Thermodynamic modeling; Silicates; Slags; Glass melts

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Basic
  4. A model to calculate the viscosity of silicate melts
  5. A model to calculate the viscosity of silicate melts
  6. A note on the application of the phase rule
  7. Thermodynamic properties of liquid silver–indium–tin alloys determined from emf measurements
  8. Unconstrained solidification and characterisation of near-eutectic Al–Cu–Ag alloys
  9. Tensile properties of L12 intermetallic foils fabricated by cold rolling
  10. Microstructural control of FeB-inoculated mottled low-alloy white iron by a design of experiments approach
  11. Applied
  12. Dislocation structure and crystallite size distribution in lath martensite determined by X-ray diffraction peak profile analysis
  13. Effect of minor addition of Pb upon interfacial reactions and mechanical properties at Sn-3.0Ag-0.5Cu/Cu and Sn-58Bi/Cu solder joints
  14. Elastic properties of braided ceramic matrix composites
  15. The influence of microstructural characteristics and contaminants on the mechanical properties and fracture topography of low cost Ti6Al4V alloy
  16. Microstructure and room temperature mechanical properties of Hf and Sn-doped Nb-20Ti-5Cr-3Al-18Si alloy
  17. The effect of alloying elements on constrained carbon equilibrium due to a quench and partition process
  18. Hardfacing behavior of Cr–Ni stainless steel with Co-based super alloys
  19. Development of SMD 32.768 kHz tuning fork-type crystals
  20. Notification
  21. DGM News
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