Diffusion bonding of the Mo-base alloy TZM with interlayers
-
Karanam Bhanumurthy
und Rainer Schmid-Fetzer
Abstract
Molybdenum-base alloys have excellent high temperature mechanical properties and joining of these alloys as heat sink materials is envisaged in many structural applications of fusion reactors. TZM is an important Mo-base alloy and diffusion bonding experiments were carried out in a hot vacuum press by sandwiching interlayers, Ti, Ni, Mo and Ta between two pieces of the TZM alloy in the temperature range 900 to 1200 °C. Detailed metallurgical analysis was carried out using optical microscopy, scanning electron microscopy and by electron probe microanalyser. All the sandwiched diffusion couples consisting of TZM/X/TZM, (X = Ti, Ni, Mo, Ti) showed defect-free microstructures at the bonded interface at the optimised bonding conditions. Ti seems to be a more suitable interlayer compared to other interlayers in terms of bonding temperature and applied pressure. The TZM/Ni interface was marked by the presence of the intermetallic compound NiMo. The concentration profiles for diffusion couples TZM/Ti were asymmetric, whilst TZM/Mo and TZM/Ta were symmetric about the Matano Interface. The interdiffusion coefficients calculated using the Boltzmann–Matano method for TZM/Ti diffusion couples showed decreases in the values with increase in the Mo concentration.
References
[1] V.V.Rynin, D.L.Smith: J. Nucl. Mater.191-194(1992)30.10.1016/S0022-3115(09)80007-XSuche in Google Scholar
[2] T.Tanabe, N.Noda, Kakashima: J. Nucl. Mater.196–198(1992)92.10.1515/jom-1992-920212Suche in Google Scholar
[3] C.H.Wu, U.Mszanowaki: J. Nucl. Mater.218(1995)293.10.1016/0022-3115(94)00675-XSuche in Google Scholar
[4] K.Abe, T.Masuyama, M.Satou, M.L.Himiltom: Mater. Trans. JIM34(1993)1137.10.2320/matertrans1989.34.1137Suche in Google Scholar
[5] F.A.Garner, J.F.Stubbins: J. Nucl. Mater.218(1994)1298.10.1016/0022-3115(94)91039-1Suche in Google Scholar
[6] C.H.Cadden, B.C.OdegardJr.: J. Nucl. Mater.283–287(2000)1253.10.1016/S0022-3115(00)00178-1Suche in Google Scholar
[7] T.Mrotzek, A.HoffmannU.Martin: Int. J. Refract. Met. Hard Mater.24(2006)298.10.1016/j.ijrmhm.2005.10.003Suche in Google Scholar
[8] J.Wadsworth, G.R.Morse, P.M.Chewey: Mater Sci. Eng.59(1983)59.10.1016/0025-5416(83)90173-8Suche in Google Scholar
[9] H.G.Mayer, G.Haufler: Planseeberichte für Pulvermetallurgie26(1978)157.Suche in Google Scholar
[10] F.Marito: J. Less. Comm. Metals.146(1989)337.10.1016/0022-5088(89)90391-3Suche in Google Scholar
[11] H.Masumoto, A.Asada: Bull. Kurume Institute Tech.1-9(1991)15.Suche in Google Scholar
[12] G.Lovato, F.Moret, G.Chaumat, G.Cailletaut, P.Pilvin: Fusion Technology, Vol. 1, Elsevier Press, Amsterdam(1995)247.10.1016/B978-0-444-82220-8.50030-3Suche in Google Scholar
[13] J.L.Pouchou, F.Pichoir: Microbeam Analysis, San Francisco, CA, 1985.Suche in Google Scholar
[14] T.B.Massalski (Ed.) Binary Alloy Phase Diagram, ASM Int. Metals Park, OH(1986).Suche in Google Scholar
[15] A.Laik, G.B.Kale, K.Bhanumurthy: Metall. Mater. Trans, A37(2006)2919.10.1007/s11661-006-0173-0Suche in Google Scholar
[16] G.B.Kale, R.V.Patil: Mater. Trans. JIM35(1994)439.10.2320/matertrans1989.35.439Suche in Google Scholar
[17] I.Thibon, D.Ansel, M.Boliveau, J.Debuigne: Z. Metallkd.89(1998)187.Suche in Google Scholar
[18] A.Cohen, I.E.Klein, A.E.Yaniv: J. Mater. Sci. Lett.4(1985)1198.10.1007/BF00723458Suche in Google Scholar
[19] C.P.Heijwegen, G.D.Rieck: Acta Metall.22(1974)1269.10.1016/0001-6160(74)90140-0Suche in Google Scholar
[20] T.C.Chou, L.Link: Scripta Metall.34(1996)831.10.1016/1359-6462(95)00601-XSuche in Google Scholar
[21] L.Boltzmann: Annual. Phys.8(1894)959.10.1002/andp.18942891315Suche in Google Scholar
[22] A.D.Le Claire: Prog. Met. Phys.1(1949)306.10.1016/0502-8205(49)90009-XSuche in Google Scholar
[23] F.Guillemot, M.Boliveau, M.Bohn, J.Debuigne, D.Ansel: Int. J. Refract. Met Hard Mater.19(2001)183.10.1016/S0263-4368(01)00040-3Suche in Google Scholar
© 2008, Carl Hanser Verlag, München
Artikel in diesem Heft
- Contents
- Contents
- Basic
- On the reaction scheme and liquidus surface in the ternary system Al–Si–Ti
- Experimental study of the phase equilibria of the Ni – Zr system
- Tensile behaviour of micro-sized copper wires studied using a novel fibre tensile module
- Dislocation densities in soft and hard oriented grains of compression deformed textured NiAl polycrystals
- The influence of plastic instabilities on the mechanical properties of a high-manganese austenitic FeMnC steel
- Modeling of isothermal bainite formation based on the nucleation kinetics
- Application of the Kaptay model in calculation of ternary liquid alloys' viscosities
- The influence of the austenite dispersion on phase transformation during the austempering of ductile cast iron having a dual matrix structure
- Effect of trace Ti on the microstructure and mechanical properties of AM50 alloy
- Applied
- Diffusion bonding of the Mo-base alloy TZM with interlayers
- Amorphization, nanocrystallization and magnetic properties of mechanically milled Sm–Co magnetic powders
- Wear behavior of plasma nitrided AISI 420 stainless steel
- Hot extrusion of α and α/β-brass alloys
- Role of surface texture and roughness parameters in friction and transfer layer formation under dry and lubricated sliding conditions
- The emergence and disappearance of a high density of microcracks in nitrided Fe-4.65 at.% Al alloy
- Notifications
- DGM News
Artikel in diesem Heft
- Contents
- Contents
- Basic
- On the reaction scheme and liquidus surface in the ternary system Al–Si–Ti
- Experimental study of the phase equilibria of the Ni – Zr system
- Tensile behaviour of micro-sized copper wires studied using a novel fibre tensile module
- Dislocation densities in soft and hard oriented grains of compression deformed textured NiAl polycrystals
- The influence of plastic instabilities on the mechanical properties of a high-manganese austenitic FeMnC steel
- Modeling of isothermal bainite formation based on the nucleation kinetics
- Application of the Kaptay model in calculation of ternary liquid alloys' viscosities
- The influence of the austenite dispersion on phase transformation during the austempering of ductile cast iron having a dual matrix structure
- Effect of trace Ti on the microstructure and mechanical properties of AM50 alloy
- Applied
- Diffusion bonding of the Mo-base alloy TZM with interlayers
- Amorphization, nanocrystallization and magnetic properties of mechanically milled Sm–Co magnetic powders
- Wear behavior of plasma nitrided AISI 420 stainless steel
- Hot extrusion of α and α/β-brass alloys
- Role of surface texture and roughness parameters in friction and transfer layer formation under dry and lubricated sliding conditions
- The emergence and disappearance of a high density of microcracks in nitrided Fe-4.65 at.% Al alloy
- Notifications
- DGM News