Home Effects of charging conditions on the hydrogen related mechanical property degradation of a 3 Cr low alloyed steel
Article
Licensed
Unlicensed Requires Authentication

Effects of charging conditions on the hydrogen related mechanical property degradation of a 3 Cr low alloyed steel

  • Yongxin Lu , Hongyang Jing , Yongdian Han and Lianyong Xu
Published/Copyright: February 21, 2017
Become an author with De Gruyter Brill

Abstract

In this work, the susceptibility of a 3 Cr low alloyed steel to hydrogen degradation of its mechanical properties was investigated to simulate the outside pipeline environment condition by a series of electrochemical hydrogen permeation measurements, surface characterization and tensile tests. Results show that the amount of hydrogen charging into the 3 Cr low alloyed steel specimen is affected by the external charging conditions, such as the hydrogen charging time and charging current density. The diffusivity of hydrogen at room temperature in 3 Cr low alloyed steel has been determined as 2.87 × 10−8 cm2 × s−1. The reduction of ductility with charging time becomes obvious in the tensile experiments.

Kurzfassung

In der diesem Beitrag zugrunde liegenden Forschungsarbeit wurde die Anfälligkeit eines niedriglegierten 3-Cr-Stahls hinsichtlich der Erniedrigung seiner mechanischen Eigenschaften durch Wasserstoff untersucht, was die äußeren Pipelineumgebungsbedingungen simuliert, und zwar mittels einer Serie von elektrochemischen Permeationsversuchen, der Oberflächencharakterisierung und Zugversuchen. Die Ergebnisse zeigen, dass die Konzentration, mit der Wasserstoff von den Proben aus dem niedriglegierten 3-Cr-Stahl absorbiert wird, durch die externen Beladungsbedingungen beeinflusst wird, unter anderem durch die Beladungszeit und die Beladungsstromdichte. Die Diffusivität von Wasserstoff in dem niedriglegierten 3-Cr-Stahl wurde mit 2,87 × 10−8 cm2 × s−1 ermittelt. Die Reduzierung der Duktilität mit zunehmender Beladungsdauer wird in den Zugversuchen offensichtlich.


*Correspondence Address, Prof. Dr. Lianyong Xu, School of Materials Science and Engineering, Peiyang Park Campus, Tianjin University, 31-169, No.135 Yaguan Road, Tianjin, 300350, P. R. China, E-mail:

Yongxin Lu, born 1986, graduated with a master degree from the School of Material Science and Engineering, Lanzhou University of Technology, China, in 2010. He continued studying at the School of Material Science and Engineering, Tianjin University, China, in 2013. His main research areas are corrosion and protection of metal material welding joint, and environmental corrosion evaluation of welding joints.

Prof. Dr. Hongyang Jing, born 1966, graduated with an MSc from the School of Mechanical Engineering, Tianjin University, China, in 1988. He continued studying at the same faculty and became a Doctor of Science in 1993. He is Professor and Researcher at the School of Mechanical Engineering, Tianjin University. His main research areas are construction and materials interconnect technology, life prediction and extension of welding structures. He also studies the creep of welding structures, fracture and fatigue behavior assessments under high or low temperature, corrosion and other complex environments.

Dr. Yongdian Han, born 1983, graduated with an MSc from the School of Material Science and Engineering, Tianjin University, China, in 2007. He continued studying at the same faculty and received his PhD in 2010. He is Researcher at the School of Material Science and Engineering, Tianjin University. His main research areas are technology and reliability of electronic packaging materials, corrosion of welding structures as well as fatigue and fracture behavior assessments.

Prof. Dr. Lianyong Xu, born 1975, graduated with an MSc from the School of Material Science and Engineering, Tianjin University, China, in 2004. He continued studying at the same faculty and received his PhD in 2007. Currently, he is Associate Professor and Researcher at the same faculty. His main research areas are welding mechanics, welding residual stress, deformation control and finite element analysis of welding joints, integrity and life assessment of welded structures under high temperature as well as environmental corrosion evaluation of welding joints.


References

1 M. A.Mohtadi-Bonab, J. A.Szpunar, R.Basu, M.Eskandari: The mechanism of failure by hydrogen induced cracking in an acidic environment for API 5L X70 pipeline steel, International Journal of Hydrogen Energy40 (2015), pp. 1096110710.1016/j.ijhydene.2014.11.057Search in Google Scholar

2 C.Dong, Z.Liu, X.Li, Y.Cheng: Effects of hydrogen-charging on the susceptibility of X100 pipeline steel to hydrogen-induced cracking, International Journal of Hydrogen Energy34 (2009), pp. 9879988410.1016/j.ijhydene.2009.09.090Search in Google Scholar

3 S.Papavinasam: Corrosion Control in the Oil and Gas Industry, 1st Ed., Elsevier Inc., USA (2014)10.1016/B978-0-12-397022-0.00001-7Search in Google Scholar

4 L.Xu, S.Guo, W.Chang, T.Chen, L.Hu, M.Lu: Corrosion of Cr bearing low alloy pipeline steel in CO2 environment at static and flowing conditions, Applied Surface Science270 (2013), pp. 39540410.1016/j.apsusc.2013.01.036Search in Google Scholar

5 F.Farelas, M.Galicia, B.Brown, S.Nesic, H.Castaneda: Evolution of dissolution processes at the interface of carbon steel corroding in a CO2 environment studied by EIS, Corrosion Science52 (2010), pp. 50951710.1016/j.corsci.2009.10.007Search in Google Scholar

6 S.Guo, L.Xu, L.Zhang, W.Chang, M.Lu: Corrosion of alloy steels containing 2 % chromium in CO2 environments, Corrosion Science63 (2012), pp. 24625810.1016/j.corsci.2012.06.006Search in Google Scholar

7 Z.Jiaa, X.Lib, C.Dub, Z.Liub, G.Jin: Effect of the carbon dioxide pressure on the electrochemical behavior of 3 Cr low alloyed steel at high temperature, Materials Chemistry & Physics136 (2012), pp. 97397910.1016/j.matchemphys.2012.08.035Search in Google Scholar

8 B.Kerman, D.Edmonds, J.Gonzales, G.Turconi, L.Scoppio, G.Dicken: Development of superior corrosion resistance 3 % Cr steels for downhole applications, Proc. of the Intern. Conf. Corrosion, NACE International, San Diego, California, USA (2003), pp. 1620Search in Google Scholar

9 L. D.Paolinelli: The incidence of chromium-rich corrosion products on the efficiency of an imidazoline-based inhibitor used for CO2 corrosion prevention, Materials Chemistry & Physics126 (2011), pp. 93894710.1016/j.matchemphys.2010.12.001Search in Google Scholar

10 M.Ueda, H.Takabe: The formation behavior of corrosion protective films of low Cr bearing steels in CO2 environments, Annals of Surgery244 (2001), pp. 700705Search in Google Scholar

11 R.Wang: Effects of hydrogen on the fracture toughness of a X70 pipeline steel, Corrosion Science51 (2009), pp. 2803281010.1016/j.corsci.2009.07.013Search in Google Scholar

12 D.Hardie, E. A.Charles, A. H.Lopez: Hydrogen embrittlement of high strength pipeline steels, Corrosion Science48 (2006), pp. 4378438510.1016/j.corsci.2006.02.011Search in Google Scholar

13 L. W.Tsay, M. Y.Chi, Y. F.Wu, J. K.Wu, D. Y.Lin: Hydrogen embrittlement susceptibility and permeability of two ultra-high strength steels, Corrosion Science48 (2006), pp. 1926193810.1016/j.corsci.2005.05.042Search in Google Scholar

14 P.Wang, Z.Lv, S.Zheng, Y.Qi, J.Wang, Y.Zheng: Tensile and impact properties of X70 pipeline steel exposed to wet H2S environments, International Journal of Hydrogen Energy40 (2015), pp. 115141152110.1016/j.ijhydene.2015.02.051Search in Google Scholar

15 P.Wang, J.Wang, S.Zheng, Y.Qi, M.Xiong, Y.Zheng: Effect of H2S/CO2 partial pressure ratio on the tensile properties of X80 pipeline steel, International Journal of Hydrogen Energy2 (2015), pp. 119251193010.1016/j.ijhydene.2015.04.114Search in Google Scholar

16 Z. Y.Liu, X. Z.Wang, C. W.Du, J. K.Li, X. G.Li: Effect of hydrogen-induced plasticity on the stress corrosion cracking of X70 pipeline steel in simulated soil environments, Materials Science & Engineering A658 (2016), pp. 34835410.1016/j.msea.2016.02.019Search in Google Scholar

17 J. P.Hirth: Effects of hydrogen on the properties of iron and steel, Metallurgical & Materials Transactions A11 (1980), pp. 86189010.1007/BF02654700Search in Google Scholar

18 V.Olden, C.Thaulow, R.Johnsen, E.Østby, T.Berstad: Application of hydrogen influenced cohesive laws in the prediction of hydrogen induced stress cracking in 25 % Cr duplex stainless steel, Engineering Fracture Mechanics75 (2008), pp. 2333235110.1016/j.engfracmech.2007.09.003Search in Google Scholar

19 S. A.Shipilov, I. L.May: Structural integrity of aging buried pipelines having cathodic protection, Engineering Failure Analysis13 (2006), pp. 1159117610.1016/j.engfailanal.2005.07.008Search in Google Scholar

20 J.Capelle, J.Gilgert, I.Dmytrakh, G.Pluvinage: Sensitivity of pipelines with steel API X52 to hydrogen embrittlement, International Journal of Hydrogen Energy33 (2008), pp. 7630764110.1016/j.ijhydene.2008.09.020Search in Google Scholar

21 I.Moro, L.Briottet, P.Lemoine, E.Andrieu, C.Blanc, G.Odemer: Hydrogen embrittlement susceptibility of a high strength steel X80, Materials Science & Engineering A527 (2010), pp. 7252726010.1016/j.msea.2010.07.027Search in Google Scholar

22 Y.Lu, H.Jing, Y.Han, L.Xu: Effect of temperature on the 3 Cr low-alloyed steel initial corrosion behavior in CO2 solution, Materials Chemistry & Physics178 (2016), pp. 16017210.1016/j.matchemphys.2016.04.083Search in Google Scholar

23 L. N.Xu, S. Q.Guo, C. L.Gao, W.Chang, T. H.Chen, M. X.Lu: Influence of microstructure on mechanical properties and corrosion behavior of 3 % Cr steel in CO2 environment, Materials & Corrosion63 (2012), pp. 997100310.1002/maco.201106389Search in Google Scholar

24 J. L.Albarran, L.Martinez, H. F.López: The sour gas susceptibility of an X-80 steel for oil and gas transport, Scripta Materialia38 (1998), pp. 74975510.1016/S1359-6462(97)00544-7Search in Google Scholar

25 G. T.Park, S. U.Koh, H. G.Jung, K. Y.Kim: Effect of microstructure on the hydrogen trapping efficiency and hydrogen induced cracking of linepipe steel, Corrosion Science50 (2008), pp. 1865187110.1016/j.corsci.2008.03.007Search in Google Scholar

26 K.Chawla, J.Rigsbee, J.Woodhouse: Hydrogen-induced cracking in two linepipe steels, Journal of Materials Science21 (1986), pp. 3777378210.1007/BF00553429Search in Google Scholar

Published Online: 2017-02-21
Published in Print: 2017-03-02

© 2017, Carl Hanser Verlag, München

Articles in the same Issue

  1. Inhalt/Contents
  2. Contents
  3. Fachbeiträge/Technical Contributions
  4. Characteristics of modified martensitic stainless steel surfaces under tribocorrosion conditions
  5. Corrosion resistance and mechanical properties of quenched and tempered 28MnCrB5 steel in two acidic environments
  6. Statistical analysis of burst requirements from regulations for composite cylinders in hydrogen transport
  7. Effects of charging conditions on the hydrogen related mechanical property degradation of a 3 Cr low alloyed steel
  8. Characterization of hollow glass sphere reinforced epoxy composites: Dynamical mechanical analysis and morphology
  9. Effect of mechanical anisotropy on the energy absorption capacity in thin-walled tubes
  10. Effect of Ti as a trace element on mechanical properties and microstructural evolution in direct austempered ductile cast iron
  11. Effect of static strain aging on the fatigue behavior of S275JRC steel
  12. Evaluation of residual stresses present in spirally welded API grade pipeline steel using the hole drilling method
  13. Influence of U-O bending process parameters on the friction coefficient
  14. Mechanical behavior of internal pressurized composite pipes jointed with embedded tubular sleeves
  15. Effect of cutting parameters on surface roughness and wire consumption during wire electro-discharge machining
  16. Prediction and controlling of roundness during the BTA deep hole drilling process: Experimental investigations and fuzzy modeling
  17. Reliability and sensitivity of visible liquid penetrant NDT for inspection of welded components
  18. Mechanical properties of pipeline steel welds
Downloaded on 19.10.2025 from https://www.degruyterbrill.com/document/doi/10.3139/120.110989/html
Scroll to top button