Removal of amitraz from aqueous solutions on clay by adsorption technique at industrial scale
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Abstract
Amitraz (AZ) that is used as acaricide was extracted by using clay adsorbent. The experimental data were modeled via Langmuir and Freundlich isotherms in which adsorption data fit well. The monolayer adsorption capacity was found as 28.53 mg × g−1 at a temperature of 30 °C. The effects of the phases contact time, the initial solution pH value and the initial pesticide concentration were investigated regarding the points of adsorption equilibrium and yield. The adsorption kinetics were investigated by applying pseudo-first-order, pseudo-second-order and intra-particle diffusion laws. Adsorption of AZ was found to be best fitted by the pseudo-second-order model. The intra-particle diffusion also plays an important role in adsorption phenomenon. This adsorption is a physical and spontaneous phenomenon. The pesticide removal by adsorption technique was successfully applied in industrial plants.
Kurzfassung
Amitraz (AZ), das als Akarizid verwendet wird, wurde unter Verwendung eines Ton-Adsorptionsmittel extrahiert. Die experimentellen Daten wurden mittels Langmuir- und Freundlich-Isothermen modelliert. Die Adsorptionsdaten stimmen gut mit den Langmuir- und Freundlich-Isothermen überein. Die Adsorptionskapazität der Monoschicht wurde mit 28,53 mg × g−1 bei einer Temperatur von 30 °C ermittelt. Die Wirkung der Phasenkontaktzeit, der pH-Wert der Ausgangslösung und die Anfangspestizidkonzentration wurden anhand der Punkte des Adsorptionsgleichgewichtes und anhand der Ausbeute untersucht. Die Adsorptionskinetik wurde durch die Anwendung von pseudo-erster Ordnung, pseudo-zweiter Ordnung und zwischenmolekularer Teilchen Diffusionsgesetzen untersucht. Es stellte sich heraus, dass die Adsorption von Amitraz am besten durch das Modell der pseudo-zweiten Ordnung dargestellt werden kann. Die zwischenmolekulare Partikel-Diffusion ist ebenfalls für die Adsorptionsphänomene von Bedeutung. Es handelt sich um eine physikalische Art der Adsorption, die spontan ist. Die Pestizidentfernung durch Adsorption wurde in Industrieanlagen erfolgreich angewendet.
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© 2017, Carl Hanser Verlag, München
Artikel in diesem Heft
- Inhalt/Contents
- Contents
- Fachbeiträge/Technical Contributions
- Influence of casting skin on the fatigue lifetime of ferritic ductile cast iron
- Tensile properties of continuous E-glass and basalt fiber reinforced polypropylene composites
- Corrosion behavior of welded Ni-Co-Cr-Si alloys during exposure in integrated coal gasification combined cycle syngas plants
- Tensile properties of friction welded AISI 4340 joints
- Vergleich der Spannungsrissbeständigkeit von Polyethylen und Polyethylenterephthalat als Werkstoffe für Verpackungen zum Transport von Gefahrgütern
- A model for high-cycle fatigue crack propagation
- Influences of extrusion temperatures on the wear behavior of magnesium alloy AZ31 fabricated by the extrusion shear process
- The buckling resistance of welded plate girders taking into account the influence of post-welding imperfections – Part 1: Parameter study
- Effect of burnishing parameters on surface roughness and hardness
- Mechanical properties of friction stir welded 5083 aluminum alloys
- Application of the Taguchi technique for the optimization of surface roughness and tool life during the milling of Hastelloy C22
- Optimization of cutting parameters for surface roughness in turning of studs manufactured from AISI 5140 steel using the Taguchi method
- Preparation and properties of a long time durable superhydrophilic titanium dioxide film obtained by a sol-gel process
- Mechanical properties of aluminum powder reinforced polypropylene
- Removal of amitraz from aqueous solutions on clay by adsorption technique at industrial scale
Artikel in diesem Heft
- Inhalt/Contents
- Contents
- Fachbeiträge/Technical Contributions
- Influence of casting skin on the fatigue lifetime of ferritic ductile cast iron
- Tensile properties of continuous E-glass and basalt fiber reinforced polypropylene composites
- Corrosion behavior of welded Ni-Co-Cr-Si alloys during exposure in integrated coal gasification combined cycle syngas plants
- Tensile properties of friction welded AISI 4340 joints
- Vergleich der Spannungsrissbeständigkeit von Polyethylen und Polyethylenterephthalat als Werkstoffe für Verpackungen zum Transport von Gefahrgütern
- A model for high-cycle fatigue crack propagation
- Influences of extrusion temperatures on the wear behavior of magnesium alloy AZ31 fabricated by the extrusion shear process
- The buckling resistance of welded plate girders taking into account the influence of post-welding imperfections – Part 1: Parameter study
- Effect of burnishing parameters on surface roughness and hardness
- Mechanical properties of friction stir welded 5083 aluminum alloys
- Application of the Taguchi technique for the optimization of surface roughness and tool life during the milling of Hastelloy C22
- Optimization of cutting parameters for surface roughness in turning of studs manufactured from AISI 5140 steel using the Taguchi method
- Preparation and properties of a long time durable superhydrophilic titanium dioxide film obtained by a sol-gel process
- Mechanical properties of aluminum powder reinforced polypropylene
- Removal of amitraz from aqueous solutions on clay by adsorption technique at industrial scale