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Removal of amitraz from aqueous solutions on clay by adsorption technique at industrial scale

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Veröffentlicht/Copyright: 22. Dezember 2016
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Abstract

Amitraz (AZ) that is used as acaricide was extracted by using clay adsorbent. The experimental data were modeled via Langmuir and Freundlich isotherms in which adsorption data fit well. The monolayer adsorption capacity was found as 28.53 mg × g−1 at a temperature of 30 °C. The effects of the phases contact time, the initial solution pH value and the initial pesticide concentration were investigated regarding the points of adsorption equilibrium and yield. The adsorption kinetics were investigated by applying pseudo-first-order, pseudo-second-order and intra-particle diffusion laws. Adsorption of AZ was found to be best fitted by the pseudo-second-order model. The intra-particle diffusion also plays an important role in adsorption phenomenon. This adsorption is a physical and spontaneous phenomenon. The pesticide removal by adsorption technique was successfully applied in industrial plants.

Kurzfassung

Amitraz (AZ), das als Akarizid verwendet wird, wurde unter Verwendung eines Ton-Adsorptionsmittel extrahiert. Die experimentellen Daten wurden mittels Langmuir- und Freundlich-Isothermen modelliert. Die Adsorptionsdaten stimmen gut mit den Langmuir- und Freundlich-Isothermen überein. Die Adsorptionskapazität der Monoschicht wurde mit 28,53 mg × g−1 bei einer Temperatur von 30 °C ermittelt. Die Wirkung der Phasenkontaktzeit, der pH-Wert der Ausgangslösung und die Anfangspestizidkonzentration wurden anhand der Punkte des Adsorptionsgleichgewichtes und anhand der Ausbeute untersucht. Die Adsorptionskinetik wurde durch die Anwendung von pseudo-erster Ordnung, pseudo-zweiter Ordnung und zwischenmolekularer Teilchen Diffusionsgesetzen untersucht. Es stellte sich heraus, dass die Adsorption von Amitraz am besten durch das Modell der pseudo-zweiten Ordnung dargestellt werden kann. Die zwischenmolekulare Partikel-Diffusion ist ebenfalls für die Adsorptionsphänomene von Bedeutung. Es handelt sich um eine physikalische Art der Adsorption, die spontan ist. Die Pestizidentfernung durch Adsorption wurde in Industrieanlagen erfolgreich angewendet.


*Correspondence Address, Assoc. Prof. Jale Gülen, Department of Chemical Engineering, Faculty of Chemical and Metallurgical Engineering, Yildiz Technical University, 34210 Esenler, Istanbul, Turkey, E-mail:

Jale Gülen is currently Associate Professor in the Department of Chemical Engineering at Yıldız Technical University in Istanbul, Turkey. She received her BSc, MSc and PhD degrees from Yıldız Technical University, in 1982, 1986 and 1994, respectively. Her main research interest includes physical chemistry.

Zehra Altın is Assistant Professor at Çankırı Karatekin University, Çankırı, Turkey.

Mahmure Özgür is Professor at Yıldız Technical University, Istanbul, Turkey.


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Published Online: 2016-12-22
Published in Print: 2017-01-05

© 2017, Carl Hanser Verlag, München

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