Startseite Corrosion behavior of welded Ni-Co-Cr-Si alloys during exposure in integrated coal gasification combined cycle syngas plants
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Corrosion behavior of welded Ni-Co-Cr-Si alloys during exposure in integrated coal gasification combined cycle syngas plants

  • Sungkyu Lee , Min Jung Kim , Jieun Lee , Joohyun Park , Suk-Hwan Kang , Seung-Jong Lee und Yongseung Yun
Veröffentlicht/Copyright: 22. Dezember 2016
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Abstract

The corrosion behavior of commercially available and welded Haynes® 160® Ni-Co-Cr-Si alloy samples was investigated by exposure to coal-gasifying integrated coal gasification combined cycle pilot plant facilities under typical conditions as 2.005 MPa and 160 to 300 °C. The morphological and microstructural analyses of the exposed samples were conducted using scanning electron microscopy and energy dispersive X-ray spectroscopy analysis on the external surface of the recovered corrosion test samples to obtain information of the corrosion scale. These analyses based on the pre- and post-exposure corrosion test samples combined with thermodynamic Ellingham-Pourbaix stability diagrams provided preliminary insight into the mechanism of the observed corrosion behavior prevailing in the piping materials that connected the particulate removal unit and the water scrubber of the integrated coal gasification combined cycle pilot plant. Uniform material wastage was observed after 46 hours of operation, and a preliminary corrosion mechanism was suggested: the observed material waste and corrosion behavior of the Haynes® 160® Ni-Co-Cr-Si alloy samples cut off from the coal syngas integrated coal gasification combined cycle plant were explained by the formation of discontinuous (complex) oxide phases and subsequent chlorine-induced active oxidation under the predominantly reducing environment encountered. This contribution supplements the already published studies of Haynes® 556® Fe-Ni-Cr-Co alloys and Haynes® 230® nickel-based superalloys and completes the comprehensive series of such coal-gasifying integrated coal gasification combined cycle pilot plant exposure tests using the facilities affiliated with the Institute for Advanced Engineering.

Kurzfassung

Für den vorliegenden Beitrag wurden Proben einer kommerziell erhältlichen und geschweißten Ni-Co-Cr-Si-Legierung Haynes® 160® untersucht, wobei sie den Betriebsbedingungen bei 2.005 MPa und 160 bis 300 °C der integrierten Kohlevergasung in Synthesegas-Kombikraftwerken ausgesetzt wurden. Die morphologischen und mikrostrukturellen Analysen der Proben wurden mittels Rasterelektronenmikroskopie und energiedispersiver Röntgenspektroskopie der externen Oberfläche nach den Korrosionsversuchen durchgeführt, um Informationen über die Korrosionsschichten zu gewinnen. Diese Analysen basierend auf Proben vor und nach dem Korrosionsversuchen kombiniert mit thermodynamischen Ellingham-Pourbaix-Stabilitätsdiagrammen ermöglichten eine begrenzte Einsicht in die Mechanismen des beobachteten Korrosionsverhaltens, das in den Rohrwerkstoffen vorherrscht, die zur Verbindung der speziellen Entnahmeeinrichtungen und dem Wasserreiniger in integrierten Kohlevergasungs-Kombikraftwerken verwendet werden. Es wurde ein gleichförmiger Materialabtrag nach 46 Betriebsstunden beobachtet und hierfür ein erster Korrosionsmechanismus vorgeschlagen. Der beobachtete Materialverlust und das Korrosionsverhalten der Nickellegierung Haynes® 160®, die der IGCC-Anlage entnommen wurde, wurden mit der Bildung von diskontinuierlichen komplexen Oxid-Phasen und nachfolgender Chlorgas-induzierter aktiver Oxidation unter überwiegend reduzierenden Umgebungsbedingungen erklärt. Der Beitrag schließt an eine bereits veröffentlichte Untersuchungn der Fe-Ni-Cr-Co-Legierung Haynes® 556® und der Nickel-Superlegierung Haynes® 230® an und vervollständigt damit die umfangreichen Versuchsreihen unter Nutzung der entsprechenden Einrichtungen zusammen mit dem Institute for Advanced Engineering in Korea.


*Correspondence Address, Dr. Sungkyu Lee, Plant Engineering Division, Institute for Advanced Engineering (IAE), 633-2 Goan-ri, Baegam-myeon, Cheoin-gu, Yongin-si, Gyeonggi-do 449-863 Korea, E-mail:

Sungkyu Lee, born 1959, received his BSc from the Hanyang University of Seoul, Korea, in 1982. He graduated with an MSc and PhD in Materials Science and Engineering from the University of Minnesota in Twin Cities, USA, in 1991 and 1994, respectively. Now, he is working as a principal engineer at the Plant Engineering Division, Institute for Advanced Engineering, Yongin-si, Gyeonggi-do, Korea.

Min Jung Kim, born 1983, received her BSc in Materials Science and Engineering from the Incheon National University, Incheon, Korea in 2007. Her MSc and PhD degrees were conferred in Materials Science and Engineering by Hongik University, Seoul, Korea and Sungkyunkwan University, Suwon, Korea in 2009 and 2013, respectively. She is currently working as a research fellow at the Advanced Materials Technology Research Center, Sungkyunkwan University, Suwon-si, Gyeonggi-do, Korea.

Jieun Lee, born 1984, received her BSc and MSc in Chemical Engineering and Chemical & Biological Engineering from the Seoul National University of Science & Technology, Korea, and Korea University, Seoul, Korea, in 2008 and 2011, respectively. Now, she is working as a researcher at the Plant Engineering Division, Institute for Advanced Engineering, Yongin-si, Gyeonggi-do, Korea.

Joohyun Park, born 1975, received his BSc from Yonsei University, Seoul, Korea, in 1997. He graduated with an MSc and PhD degree in Metallurgical Engineering from Yonsei University, Seoul, Korea, in 1999 and 2002, respectively. Now, he is working as Professor in the Department of Materials Engineering, Hanyang University, Ansan, Korea.

Suk-Hwan Kang, born 1971, received his BSc in Chemical & Biological Engineering & Chemical Engineering from the Hanbat National University in 1994. His MSc and PhD degrees were conferred in the field of Chemical Engineering by Chungnam National University, Daejeon, Korea, in 1997 and 2003, respectively. Now, he is working as a principal engineer at the Plant Engineering Division, Institute for Advanced Engineering, Yongin-si, Gyeonggi-do, Korea.

Seung-Jong Lee, born 1966, received his BSc and MSc in Chemistry and Organic Chemistry from the Yonsei University, Seoul, Korea in 1988 and 1990, respectively. His PhD was conferred in Systems Engineering by Ajou University, Suwon, Korea, in 2002. Now, he is working as a principal engineer at the Plant Engineering Division, Institute for Advanced Engineering, Yongin-si, Gyeonggi-do, Korea.

Yongseung Yun, born 1957, received his BSc in Chemical Engineering from the Yonsei University, Seoul, Korea in 1979. His MSc and PhD degrees were conferred in the field of Chemical Engineering by Korea Advanced Institute of Science and Technology, Daejeon, Korea and the University of Utah, Salt Lake City, USA, in 1981 and 1990, respectively. He is currently working as Executive Research Director of the Plant Engineering Division, Institute for Advanced Engineering, Yongin-si, Gyeonggi-do, Korea.


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Published Online: 2016-12-22
Published in Print: 2017-01-05

© 2017, Carl Hanser Verlag, München

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