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Trivalent Ruthenium and Iridium Salt: Excellent Homogeneous Catalysts for Cyclic Alcohol Oxidation in Micellar Media

  • Suman Chowdhury , Atanu Rakshit , Animesh Acharjee , Aniruddha Ghosh , Kalachand Mahali and Bidyut Saha
Published/Copyright: July 8, 2020
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 57 Issue 4

Abstract

Oxidation of cyclohexanol, a six membered cyclic alcohol, by Ce(IV) is a slow-moving reaction. Therefore, it was investigated in a comparative study whether the oxidation rate can be increased by adding trace amounts of Ru(III) and Ir(III) metal catalysts in anionic (sodium dodecyl sulfate) and cationic (cetylpyridinium chloride) micellar media. The kinetics of the oxidation of cyclohexanol with Ce(IV) in acidic medium has been studied spectrophotometrically at 28°C under pseudo 1st order reaction condition. Based on the spectroscopic evidence the mechanisms for the reactions taking place in the presence of these metal catalysts were proposed.

Kurzfassung

Die Oxidationreaktion des sechsgliedrigen zyklischen Alkohols Cyclohexanol durch Ce(IV) läuft nur langsam ab. Daher wurde in einer vergleichenden Studie untersucht, ob durch Zugabe von Ru(III)- und Ir(III)-Metallkatalysatoren in Spurenmengen die Oxidationsgeschwindigkeit in anionischen (Natriumdodecylsulfat) und kationischen (Cetylpyridiniumchlorid) mizellaren Medien erhöht werden kann. Die Kinetik der Oxidation von Cyclohexanol mit Ce(IV) in saurem Medium wurde spektrophotometrisch bei 28°C unter Reaktionsbedingungen Pseudo-1.-Ordnung untersucht, und anhand der spektroskopischen Nachweise wurden die Mechanismen für die in Gegenwart dieser Metallkatalysatoren ablaufenden Reaktionen vorgeschlagen.

Key words: Cyclohexanol oxidation; metal catalysis; micellar media; ionic interaction
Stichwörter: Cyclohexanol-Oxidation; Metallkatalyse; mizellare Medien; ionische Wechselwirkung
∗ Correspondence address Prof. Dr. Bidyut Saha Homogeneous Catalysis Laboratory, Department of Chemistry, The University of Burdwan, Burdwan, India, Mob.: +91 9476341691, Tel.:+91-342-2533913 (Office), Fax: +91-342-2530452 (Office), E-Mail:

Dr. Bidyut Saha: He was born in Birbhum, WB, India in 1975. He obtained his Ph.D degree from Visva Bharati University, India in 2007. He was a visiting scientist for the year 2009–2010 in the Department of Chemistry, UBC, Canada. Dr. Saha is presently working as a Professor in the Department of Chemistry, Burdwan University, India. His area of interests is bioremediation of toxic metal, micellar catalysis and inorganic reaction mechanism. He has already published thirty papers in international journals.

Suman Chowdhury was born in Hooghly, WB, India in 1991. He passed his M. Sc degree from the University of Burdwan in 2013 and got CSIR-NET JRF fellowship in the year 2017. He is working in homogeneous catalysis laboratory in the University of Burdwan.

Atanu Rakshit was born in East Barddhaman, WB, India in 1991. He passed his M. Sc degree from the University of Burdwan in 2015 and got NET-LS in the year 2016. He is working in homogeneous catalysis laboratory in the University of Burdwan.

Animesh Acharjee was born in Asansol, WB, India in 1989. He passed his M. Sc degree from the University of Burdwan in 2013. Presently he is working as an assistant professor of Hooghly Mohsin College and he is also working as a scholar in homogeneous catalysis laboratory in the University of Burdwan.

Aniruddha Ghosh was born in Raniganj, in 1988. He passed his M. Sc degree from the University of Burdwan in 2010 and got NET-UGC fellowship in the year 2010. He has obtained PhD degree from The University of Burdwan in the year 2016. He is pursuing post-doctoral degree from Kalyani University, WB, India.

Dr. Kalachand Mahali has completed his PhD and working as Assistant Professor in the university of Kalyani. He is doing research in the field of Inorganic Chemistry.

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Received: 2019-11-08
Accepted: 2020-01-16
Published Online: 2020-07-08
Published in Print: 2020-07-15

© 2020, Carl Hanser Publisher, Munich

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  1. Contents/Inhalt
  2. Contents
  3. Novel Surfactants
  4. The Effects of the Glucose-Based Cationic-Nonionic Surfactant with Ag-SiO2 Nanocomposites on Interfacial and Foam Ability Properties
  5. Synthesis and Properties of Alkyl Polyglycoside Polyoxypropylene Ethers
  6. Surface Properties and Adsorption Behavior of Alkyl Glycoside Tartarate
  7. Micellar Catalysis
  8. Trivalent Ruthenium and Iridium Salt: Excellent Homogeneous Catalysts for Cyclic Alcohol Oxidation in Micellar Media
  9. Application
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  11. Synthesis, Characterization, Flocculation and Antistatic Properties of Poly(Methacryloyloxyethyl trimethyl Ammonium Chloride)
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https://doi.org/10.3139/113.110696
Keywords for this article
Cyclohexanol oxidation; metal catalysis; micellar media; ionic interaction

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Novel Surfactants
  4. The Effects of the Glucose-Based Cationic-Nonionic Surfactant with Ag-SiO2 Nanocomposites on Interfacial and Foam Ability Properties
  5. Synthesis and Properties of Alkyl Polyglycoside Polyoxypropylene Ethers
  6. Surface Properties and Adsorption Behavior of Alkyl Glycoside Tartarate
  7. Micellar Catalysis
  8. Trivalent Ruthenium and Iridium Salt: Excellent Homogeneous Catalysts for Cyclic Alcohol Oxidation in Micellar Media
  9. Application
  10. Preparation and Release Properties of Cationic Flavor Microcapsules with Tetradecyl Allyldimethyl Ammonium Bromide (TADAB) as Main Shell Material
  11. Synthesis, Characterization, Flocculation and Antistatic Properties of Poly(Methacryloyloxyethyl trimethyl Ammonium Chloride)
  12. Physical Chemistry
  13. Removal of Toxic Eosin Y Dye from Water Samples by Cloud Point Extraction using Triton X-114 as Nonionic Surfactant
  14. Synthesis
  15. Synthesis and Properties of Cationic Gemini Surfactants with Amide Groups
  16. Synthesis, Characterization, and Properties of Acyl Glycine, Alanine, Valine, and Leucine Derived from Vegetable Oils and Beef Tallow
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