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Surface Properties and Adsorption Behavior of Alkyl Glycoside Tartarate

  • Zhiyu Wu , Xiuquan Yang , Liang Bai , Jun Zhang und Yuan Zhou
Veröffentlicht/Copyright: 8. Juli 2020
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 57 Heft 4

Abstract

The equilibrium and dynamic surface properties and the adsorption behavior of alkyl glycosides and their derivatives alkyl glycoside tartarates at the air/water solution interface were investigated. The equilibrium surface tension and the critical micelle concentration were measured by Wilhelmy plate method and the dynamic surface tension was measured by maximum bubble pressure method. The data display that the surface tension of the alkyl glycoside tartarate surfactants was significantly reduced (24 mN m–1) compared to that of alkyl glycosides, which indicated that alkyl glycoside tartarates have a strong activity at the air/water interface. The study also found that the alkyl glycoside tartarates reach the meso-equilibrium region faster, adsorb more easily at the interface, and have a lower adsorption energy. In addition, the study further confirmed the existence of energy potential barrier.

Kurzfassung

Die Gleichgewichts- und die dynamischen Oberflächeneigenschaften sowie das Adsorptionsverhalten von Alkylglycosiden und ihren Derivaten, den Alkylglycosidtartaraten, an der Grenzfläche Luft/wässrige Lösung wurden untersucht. Die Gleichgewichts-Oberflächenspannung und die kritische Mizellenbildungskonzentration wurden mit der Wilhelmy-Plattenmethode gemessen; die dynamische Oberflächenspannung wurde mit der Methode des maximalen Blasendrucks gemessen. Die Daten zeigen, dass die Oberflächenspannung der Alkylglycosidtartarat-Tenside im Vergleich zu den Alkylglycosiden signifikant reduziert war (24 mN m–1), was darauf hinweist, dass Alkylglycosidtartarate an der Grenzfläche Luft/Wasser eine starke Aktivität aufweisen. Die Studie ergab auch, dass die Alkylglycosidtartarate den meso-Gleichgewichtsbereich schneller erreichten, leichter an der Grenzfläche absorbierten und eine geringere Adsorptionsenergie aufwiesen. Darüber hinaus bestätigte die Studie die Existenz einer Energiepotenzial-Barriere.

Key words: Alkyl glycoside tartarate surfactants; equilibrium surface tension; dynamic surface tension; effective diffusion coefficients
Stichwörter: Alkylglykosidtartarat-Tenside; Gleichgewichts-Oberflächenspannung; dynamische Oberflächenspannung; effektive Diffusionskoeffizienten
∗ Correspondence address Mr. Xiuquan Yang China Research Institute of Daily Chemistry, 34 Wenyuan Street, Taiyuan, Shanxi Province, 030001, P.R. China., Tel.: 86-15110309337, Fax: 0086-351-4040802, E-Mail:

Zhiyu Wu is a postgraduate student at the China Research Institute of Daily Chemistry. His instructor is Prof. Yang Xiuquan, Whoes main research field is the synthesis and properties of alkyl glycoside surfactants. Address: China Research Institute of Daily Chemistry, 34# Wenyuan Street, Taiyuan, Shanxi Province, 030001 P.R. China. E-Mail: .

Xiuquan Yang obtained his M. Sc. in fine chemicals from Dalian University of Technology in 1990. He is now the Vice-Chief Engineer at the China Research Institute of Daily Chemistry. His research focuses are on synthesis, application of natural-derived fine chemicals and the transfer of technological achievements. Address: China Research Institute of Daily Chemistry, 34# Wenyuan Street, Taiyuan, Shanxi Province, 030001 P.R. China. E-Mail: .

Liang Bai is a Senior engineer at the China Research Institute of Daily Chemistry. He received his M. Sc. from the China Research Institute of Daily Chemistry in 2010. His research focuses on the synthesis and investigation of natural-derived surfactant. E-Mail: .

Jun Zhang is a Senior engineer at the China Research Institute of Daily Chemistry. He received his M. Sc. from Shanxi University in 2009. His current research interests are surfactant analysis and formulation design. E-Mail: .

Yuan Zhou is a chemical engineer at the China Research Institute of Daily Chemistry. She received her M. Sc. from Shanxi University in 2011. Her research focuses on the synthesis and investigation of natural-derived surfactant. E-Mail: .

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Received: 2018-09-05
Accepted: 2018-11-06
Published Online: 2020-07-08
Published in Print: 2020-07-15

© 2020, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Novel Surfactants
  4. The Effects of the Glucose-Based Cationic-Nonionic Surfactant with Ag-SiO2 Nanocomposites on Interfacial and Foam Ability Properties
  5. Synthesis and Properties of Alkyl Polyglycoside Polyoxypropylene Ethers
  6. Surface Properties and Adsorption Behavior of Alkyl Glycoside Tartarate
  7. Micellar Catalysis
  8. Trivalent Ruthenium and Iridium Salt: Excellent Homogeneous Catalysts for Cyclic Alcohol Oxidation in Micellar Media
  9. Application
  10. Preparation and Release Properties of Cationic Flavor Microcapsules with Tetradecyl Allyldimethyl Ammonium Bromide (TADAB) as Main Shell Material
  11. Synthesis, Characterization, Flocculation and Antistatic Properties of Poly(Methacryloyloxyethyl trimethyl Ammonium Chloride)
  12. Physical Chemistry
  13. Removal of Toxic Eosin Y Dye from Water Samples by Cloud Point Extraction using Triton X-114 as Nonionic Surfactant
  14. Synthesis
  15. Synthesis and Properties of Cationic Gemini Surfactants with Amide Groups
  16. Synthesis, Characterization, and Properties of Acyl Glycine, Alanine, Valine, and Leucine Derived from Vegetable Oils and Beef Tallow
https://doi.org/10.3139/113.110693
Schlagwörter für diesen Artikel
Alkyl glycoside tartarate surfactants; equilibrium surface tension; dynamic surface tension; effective diffusion coefficients

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Novel Surfactants
  4. The Effects of the Glucose-Based Cationic-Nonionic Surfactant with Ag-SiO2 Nanocomposites on Interfacial and Foam Ability Properties
  5. Synthesis and Properties of Alkyl Polyglycoside Polyoxypropylene Ethers
  6. Surface Properties and Adsorption Behavior of Alkyl Glycoside Tartarate
  7. Micellar Catalysis
  8. Trivalent Ruthenium and Iridium Salt: Excellent Homogeneous Catalysts for Cyclic Alcohol Oxidation in Micellar Media
  9. Application
  10. Preparation and Release Properties of Cationic Flavor Microcapsules with Tetradecyl Allyldimethyl Ammonium Bromide (TADAB) as Main Shell Material
  11. Synthesis, Characterization, Flocculation and Antistatic Properties of Poly(Methacryloyloxyethyl trimethyl Ammonium Chloride)
  12. Physical Chemistry
  13. Removal of Toxic Eosin Y Dye from Water Samples by Cloud Point Extraction using Triton X-114 as Nonionic Surfactant
  14. Synthesis
  15. Synthesis and Properties of Cationic Gemini Surfactants with Amide Groups
  16. Synthesis, Characterization, and Properties of Acyl Glycine, Alanine, Valine, and Leucine Derived from Vegetable Oils and Beef Tallow
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