Synthesis and Properties of Lauryl Phosphate Monoester
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Yaning Shi
Abstract
Lauryl phosphate monoester was synthesized from the starting materials lauryl alcohol and phosphoric acid without catalysts. Subsequently, the crude product was purified by recrystallization and characterized by Fourier transform infrared (FT-IR) and nuclear magnetic resonance (31P-NMR). From the results, it was apparent that the synthesized material was the desired target product. Lauryl monoester potassium phosphate reduced the surface tension of water to 25.08 mN/m at a critical micelle concentration (CMC) of 0.569 mmol/L. It showed a low contact angle and had a low surface tension, indicating a good hydrophilicity. Lauryl monoester potassium phosphate also showed excellent antistatic properties, however its emulsifying ability was not good. The size of the aggregates of lauryl monoester calcium phosphate in aqueous solution was 220 nm and their morphology was spherical.
Kurzfassung
Laurylphosphatmonoester wurde aus den Ausgangsmaterialien Laurylalkohol und Phosphorsäure ohne Katalysatoren synthetisiert. Anschließend wurde das Rohprodukt im Rekristallisationsverfahren gereinigt und mittels Fourier-Transformations-Infrarot (FT-IR) und Kernresonanz (31P-NMR) charakterisiert. Aus den Ergebnissen war ersichtlich, dass das synthetisierte Material das gewünschte Zielprodukt war. Laurylmonoester-Kaliumphosphat senkte die Oberflächenspannung von Wasser auf 25,08 mN/m bei einer kritischen Mizellenbildungskonzentration (CMC) von 0,569 mmol/l. Es zeigte einen geringen Kontaktwinkel und hatte eine niedrige Oberflächenspannung, was auf eine gute Hydrophilie hinweist. Laurylmonoester-Kaliumphosphat zeigte auch ausgezeichnete antistatische Eigenschaften, jedoch war seine Emulgierfähigkeit nicht gut. Die Größe der Aggregate von Laurylmonoesterkaliumphosphat in wässriger Lösung betrug 220 nm bei sphärischer Morphologie.
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© 2019, Carl Hanser Publisher, Munich
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Review Article
- Characteristic and Application of Anionic Dimeric Surfactants: A Review
- Body Care
- Reduction of Irritation Potential Caused by Anionic Surfactants in the Use of Various Forms of Collagen Derived from Marine Sources in Cosmetics for Children
- Environmental Chemistry
- Optimization of Biosorption Conditions for Surfactant Induced Decolorization by Anaerobic Sludge Granules
- Evaluation of Polyether Copolymer as Green Scale and Corrosion Inhibitor in Seawater
- Physical Chemistry
- Schiff' Bases as Corrosion Inhibitor for Aluminum Alloy in Hydrochloric Acid Medium
- Study on the Synergism of Binary Surfactant Mixtures containing N-lauroyl-N-methyl Taurine Sodium
- Effect of Spacer on Surface Activity and Foam Properties of Betaine Gemini Surfactants
- Study on the Complex System of Sodium Lauryl Diphenyl Ether Disulfonate and Dodecyl Dimethyl Hydroxyethyl Ammonium Chloride
- Synthesis
- Synthesis and Properties of 9,10-Dihydroxystearic Acid Ethoxylate
- Synthesis and Properties of Lauryl Phosphate Monoester
- Novel Surfactants
- Dehydroabietyl Glycidyl Ether Grafted Hydroxyethyl Chitosan: Synthesis, Characterization and Physicochemical Properties
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Review Article
- Characteristic and Application of Anionic Dimeric Surfactants: A Review
- Body Care
- Reduction of Irritation Potential Caused by Anionic Surfactants in the Use of Various Forms of Collagen Derived from Marine Sources in Cosmetics for Children
- Environmental Chemistry
- Optimization of Biosorption Conditions for Surfactant Induced Decolorization by Anaerobic Sludge Granules
- Evaluation of Polyether Copolymer as Green Scale and Corrosion Inhibitor in Seawater
- Physical Chemistry
- Schiff' Bases as Corrosion Inhibitor for Aluminum Alloy in Hydrochloric Acid Medium
- Study on the Synergism of Binary Surfactant Mixtures containing N-lauroyl-N-methyl Taurine Sodium
- Effect of Spacer on Surface Activity and Foam Properties of Betaine Gemini Surfactants
- Study on the Complex System of Sodium Lauryl Diphenyl Ether Disulfonate and Dodecyl Dimethyl Hydroxyethyl Ammonium Chloride
- Synthesis
- Synthesis and Properties of 9,10-Dihydroxystearic Acid Ethoxylate
- Synthesis and Properties of Lauryl Phosphate Monoester
- Novel Surfactants
- Dehydroabietyl Glycidyl Ether Grafted Hydroxyethyl Chitosan: Synthesis, Characterization and Physicochemical Properties
