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Study on the Synergism of Binary Surfactant Mixtures containing N-lauroyl-N-methyl Taurine Sodium

  • Fang Meng , Hujun Xu and Xiuying Chen
Published/Copyright: May 6, 2019
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Abstract

The surface tension of the two mixed systems had been investigated in 0.1 M NaCl solution at 298.15 K respectively, including the surface tension of the anionic surfactant N-lauroyl-N-methyl taurine sodium (SDMT) and of the cationic surfactant dodecyltrimethylammonium chloride (DTAC), and zwitterionic surfactant dodecyl betaine (BS-12). The chemical surface properties of the two mixed systems were studied and the regular solution theory was applied to the two mixed systems. The results showed that the binary surfactant mixtures of SDMT/DTAC and SDMT/BS-12 exhibited synergism in surface tension reduction effectiveness, surface tension reduction efficiency and the mixed micelle formation according to β values. It was also found that the results calculated by this theory agreed well with the experimental values.

Kurzfassung

Die Oberflächenspannung der beiden Mischsysteme wurde in 0,1 M NaCl bei 298,15 K untersucht, einschließlich der Oberflächenspannung des anionischen Tensids Natrium-N-lauroyl-N-methyltaurin (SDMT), des kationischen Tensids Dodecyltrimethylammoniumchlorid (DTAC) und des zwitterionischen Tensids Dodecylbetain (BS-12). Die oberflächenchemischen Eigenschaften der beiden Mischsysteme wurden untersucht und die reguläre Lösungstheorie auf die beiden Mischsysteme angewendet. Die Ergebnisse zeigten, dass die binären Tensidmischungen aus SDMT/DTAC und SDMT/BS-12 einen Synergismus in Bezug auf die Verringerung der Oberflächenspannung, die Verringerung der Oberflächenspannung und die Bildung der gemischten Mizellen gemäß den β-Werten zeigten. Es wurde auch gefunden, dass die berechneten Ergebnisse dieser Theorie gut mit experimentellen Werten übereinstimmen.


Correspondence address, Dr. Hujun Xu and Dr. Xiuying Chen, School of Chemical and Material Engineering Jiangnan University, Wuxi 214122, P.R. China, Dr. Hujun Xu, Tel.: +8613338103707, E-Mail: , Dr. Xiuying Chen, Tel.: +8613382888106, E-Mail:

Fang Meng is a postgraduate of Jiangnan University and is involved in synthesis and analysis of surfactants.

Hujun Xu is an associate professor of Jiangnan University, P.R. China. He received his Ph.D. degree in 2005 from Nanjing University of Science and Technology, P.R. China. He has been involved in surfactants and detergents for over 30 years. He has published over 60 papers in the field of surfactants and detergents.

Xiuying Chen is an associate professor of Jiangnan University, P.R. China. She received her Ph.D. degree in 2006 from state key laboratory of fine chemicals, Dalian University of Technology, P.R. China. She has published more than 20 papers in the field of synthesis of fine chemicals and fluorescent dyes.


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Received: 2018-01-09
Accepted: 2018-04-04
Published Online: 2019-05-06
Published in Print: 2019-05-15

© 2019, Carl Hanser Publisher, Munich

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