Ester-Based Pyridinium Gemini Surfactants as Novel Inhibitors for Mild Steel Corrosion in 1 M HCl Solution
-
Mohammad Mobin
Abstract
The corrosion inhibition ability of ester based pyridinium Gemini surfactants (GS) with different hydrophobic character (14-Py and 16-Py) towards mild steel (MS) in 1 M HCl solution was investigated at various concentrations and temperatures (303–333 K). Potentiodynamic polarization, electrochemical impedance spectroscopy, weight loss, surface analysis (SEM/EDAX and AFM) and FT-IR were combined to investigate the corrosion inhibition behaviour of the surfactants. 14-Py and 16-Py were found to be efficient, mixed type inhibitors. The inhibition efficiencies increased with increasing concentration, hydrophobicity and solution temperature. The existence of a protective film of the adsorbed inhibitors on the MS surface was confirmed by SEM/EDX/AFM.
Kurzfassung
Die Fähigkeit von estergruppenhaltigen Pyridinium-Gemini-Tensiden (GS) mit unterschiedlichem hydrophobem Charakter (14-Py und 16-Py), die Korrosion gegenüber Weichstahl (MS) in 1 M HCl-Lösung zu inhibieren, wurde bei verschiedenen Konzentrationen und Temperaturen (303–333 K) untersucht. Potentiodynamische Polarisation, elektrochemische Impedanzspektroskopie, Gewichtsverlust, Oberflächenanalyse (SEM/EDAX und AFM) und FT-IR wurden kombiniert, um das Korrosionsinhibierungsverhalten der Tenside zu untersuchen. 14-Py und 16-Py agierten als effiziente Misch-Inhibitoren. Die Inhibitionswirkung stieg mit zunehmender Konzentration, Hydrophobie und Lösungstemperatur. Die Existenz eines Schutzfilms aus an der MS-Oberfläche adsorbierten Inhibitoren wurde durch SEM, EDX, AFM bestätigt.
References
1. Mallaiya, K., Subramaniam, R., Srikandan, S. S., Gowri, S., Rajasekaran, N. and Selvaraj, A.: Electrochemical, characterization of the protective film formed by the unsymmetrical Schiff's base on the mild steel surface in acid media, Electrochim. Acta56 (2011) 3857–3863. 10.1016/j.electacta.2011.02.036 Suche in Google Scholar
2. Negm, N. A., Kandile, N. G., BadrE.A. and MohammedM.A.: Gravimetric and electrochemical evaluation of environmentally friendly nonionic corrosion inhibitors for carbon steel in 1 M HCl, Corros. Sci.65 (2012) 94–103. 10.1016/j.corsci.2012.08.002Suche in Google Scholar
3. Mobin, M., Zehra, S. and Aslam, R.: L-Phenylalanine methyl ester hydrochloride as green corrosion inhibitor for mild steel in hydrochloric acid solution and effect of surfactant additive, RSC Adv., 6 (2016) 5890–5902. 10.1039/c5ra24630jSuche in Google Scholar
4. Ekanem, U. F., Umoren, S. A., Udousoro, I. I. and Udoh, A. P.: Inhibition of Mild Steel Corrosion in HCl Using Pineapple Leaves- (Ananas Comosus L.) Extract, J. Mater. Sci. 45 (2010) 5558–5566. 10.1007/s10853-010-4617-ySuche in Google Scholar
5. Obot, I. B. and Obi-Egbedi, N. O.: Adsorption properties and inhibition of mild steel corrosion in sulphuric acid solution by ketoconazole: experimental and theoretical investigation, Corros. Sci.52 (2010) 198–204. 10.1016/j.corsci.2009.09.002Suche in Google Scholar
6. Ahamad, I., Prasad, R. and Quraishi, M. A.: Inhibition of mild steel corrosion in acid solution by pheniramine drug: experimental and theoretical study, Corros. Sci.52 (2010) 3033–3041. 10.1016/j.corsci.2009.08.050Suche in Google Scholar
7. Yadav, M., Behera, D., Kumar, S. and Sinha, R. R.: Experimental and quantum chemical studies on the Corrosion Inhibition Performance of Benzimidazole Derivatives for mild steel in HCl, Ind. Eng. Chem. Res.52 (2013) 6318–6328. 10.1021/ie400099qSuche in Google Scholar
8. Fouda, A. S., Mostafa, H. A., El-Taib Haekel, F. and Elewady, G. Y.: Synergistic influence of iodide ions on the inhibition of corrosion of C-steel in sulphuric acid by some aliphatic amines, Corros. Sci.47 (2005) 1988–2004. 10.1016/j.corsci.2004.09.008Suche in Google Scholar
9. Dandia, A., Gupta, S. L., Quraishi, M. A. and Singh, P.: Ultrasound Assisted Synthesis of Pyrazolo[3,4-b]pyridines as Potential Corrosion Inhibitors for Mild Steel in 1.0 M HCl, ACS Sustainable Chem. Eng. 1 (2013) 1303–1310. 10.1021/sc400155uSuche in Google Scholar
10. Amin, M. A., Abd El-Rehim, S. S., El-Sherbini, E. E. F. and Bayoumi, R. S.: The inhibition of low carbon steel corrosion in hydrochloric acid solutions by succinic acid Part I. Weight loss, polarization, EIS, PZC, EDX and SEM studies, Electrochim. Acta52 (2007) 3588–3600. 10.1016/j.electacta.2006.10.019Suche in Google Scholar
11. Sorkhabi, H. A., Shaabani, B. and Seifzadeh, D.: Effect of some pyrimidinic Schiff bases on the corrosion of mild steel in hydrochloric acid solution, Electrochim. Acta50 (2005) 3446–3452. 10.1016/j.electacta.2004.12.019 Suche in Google Scholar
12. Singh, M. M., Banerjee, S. and Srivastava, V.: Chemically Modified Natural Polysaccharide as Green Corrosion Inhibitor for Mild Steel in Acidic Medium, Corros. Sci.59 (2012) 35–46. 10.1016/j.corsci.2012.02.009Suche in Google Scholar
13. Zhang, Q. B. and Hua, Y. X.: Corrosion inhibition of mild steel by alkylimidazolium ionic liquids in hydrochloric acid, Electrochim. Acta.54 (2009) 1881–1887. 10.1016/j.electacta.2008.10.025Suche in Google Scholar
14. Bentiss, F., Lebrini, M., Vezin, H. and Lagrenee, M.: Experimental and theoretical study of 3-pyridyl-substituted 1,2,4-thiadiazole and 1,3,4-thiadiazole as corrosion inhibitors of mild steel in acidic media, Mater. Chem. Phys. 87 (2004) 18–23. 10.1016/j.matchemphys.2004.05.040Suche in Google Scholar
15. Balbo, A. et al.: Corrosion inhibition by anionic surfactants of AA2198Li containing aluminium alloy in chloride solutions, Corros. Sci. (2013). 10.1016/j.corsci.2013.03.027Suche in Google Scholar
16. Malik, M. A., Hashim, M. A., Nabi, F., Al-Thabaiti, S. A. and Khan, Z.: Anti corrosion ability of surfactants: a review, Int. J. Electrochem. Sci.6 (2011) 1927–1948. http://www.electrochemsci.org/papers/vol6/6061927Suche in Google Scholar
17. Trabanelli, G.: Inhibitors. An old remedy for a new challenge, Corrosion47 (1991) 410–419. 10.5402/2012/971650Suche in Google Scholar
18. Xiao, L., Qiao, W., Guo, H. and Qu, J.: Synthesis of an Imidazoline phosphate surfactant and its application on corrosion inhibition, Tenside Surf. Det.45, 244–248. 10.3139/113.100380Suche in Google Scholar
19. Mobin, M. and Masroor, S.: Experimental and theoretical study on corrosion inhibition of mild steel in 20% formic acid solution using Schiff base-based cationic gemini surfactant, Tenside Surf. Det.53 (2016) 157–167. 10.3139/113.110421Suche in Google Scholar
20. Mobin, M. and Noori, S.: Adsorption and corrosion inhibition behaviour of zwitterionic gemini surfactant for mild steel in 0.5 M HCl, Tenside Surf. Det. 53 (2016) 357–367. 10.3139/113.110442Suche in Google Scholar
21. Tehrani-Bagha, A. R. and Holmberg, K.: Cationic ester-containing gemini surfactants: physical-chemical properties, Langmuir26 (2010) 9276–9282. 10.1021/la1001336Suche in Google Scholar PubMed
22. Patial, P., Shaheen, A. and Ahmad, I.: Synthesis of ester based cationic pyridinium gemini surfactants and appraisal of their surface active properties, J. Surfactants Deterg.16 (2013) 49–56. 10.1007/s11743-012-1380-xSuche in Google Scholar
23. Mobin, M., Aslam, J. and Al-LohedanH.A.: Study on the inhibition of mild steel corrosion by cationic gemini surfactant in 1 M HCl, J Dispers Sci Technol.37 (2014) 1002–1009. 10.1080/01932691.2015.1018425Suche in Google Scholar
24. Olasunkanmi, L. O., Obot, I. B., Kabanda, M. M. and Ebenso, E. E.: Some Quinoxalin-6-yl derivatives as corrosion inhibitors for mild steel in hydrochloric acid: experimental and theoretical studies, J. Phys. Chem. C119 (2015) 16004–16019. 10.1021/acs.jpcc.5b03285Suche in Google Scholar
25. Saleh, M. M.: Inhibition of mild steel corrosion by hexadecylpyridinium bromide in 0.5 M H2SO4, Mater. Chem. Phys. 98 (2006) 83–89. 10.1016/j.matchemphys.2005.08.069Suche in Google Scholar
26. Jeeva, M., Prabhu, G. V., Boobalan, M. S. and Rajesh, C. M.: Interactions and Inhibition Effect of Urea-Derived Mannich Bases on a Mild Steel Surface in HCl, J. Phys. Chem. C119 (2015) 22025–22043. 10.1021/acs.jpcc.5b05788Suche in Google Scholar
27. Mobin, M., Aslam, R., ZehraS. and AhmadM.: Bio-/Environment-friendly cationic gemini surfactant as novel corrosion inhibitor for mild steel in 1 M HCl solution, J Surfact Deterg.20 (2017) 57–74. 10.1007/s11743-016-1904-xSuche in Google Scholar
28. Adawy, A. I., Abbas, M. A. and Zakaria, K.: New Schiff base cationic surfactants as corrosion inhibitors for carbon steel in acidic medium: weight loss, electrochemical and SEM characterization techniques, Res Chem Intermed.42 (2016) 3385–3411. 10.1007/s11164-015-2219-7Suche in Google Scholar
29. Fouda, A. S., Elewady, Y. A., Abd El-Aziz, H. K. and Ahmed, A. M.: Corrosion inhibition of carbon steel in 0.5 M HCl solution using cationic surfactants, Int. J. Electrochem. Sci. 7 (2012) 10456–10475.Suche in Google Scholar
30. Atia, A. A. and Saleh, M. M.: Inhibition of acid corrosion of steel using cetylpyridinium chloride, J. App. Electrochem.33 (2003) 171–177. 10.1023/A:1024083117949Suche in Google Scholar
31. Shaban, S. M., Aiad, I., El-Sukkary, M. M., Soliman, E. A. and El-Awady, M. Y.: Inhibition of mild steel corrosion in acidic medium by vanillin cationic surfactants, J. Mol. Liq.203 (2015) 20–28. 10.1016/j.molliq.2014.12.033Suche in Google Scholar
32. Yadav, M., Kumar, S., Purkait, T., Olasunkanmi, L. O., Bahadur, I. and Ebenso, E. E.: Electrochemical, thermodynamic and quantum chemical studies of synthesized benzimidazole derivatives as corrosion inhibitors for N80 steel in hydrochloric acid, J. Mol. Liq.213 (2016) 122–138. 10.1016/j.molliq.2015.11.018Suche in Google Scholar
33. El Achouri, M., Kertit, S., Gouttaya, H. M., Nciri, B., Bensouda, Y., Perez, L., Infante, M. R., Elkacemi, K.: Corrosion inhibition of iron in 1 M HCl by some gemini surfactants in the series of alkanediyl-α,ω-bis-(dimethyl tetradecyl ammonium bromide), Prog org coat 43 (2001) 267–273. 10.1016/S0300-9440(01)00208-9Suche in Google Scholar
34. Feng, Y., Chen, S., You, J. and Guo, W.: Investigation of alkylamine self-assembled films on iron electrodes by SEM, FT-IR, EIS and molecular simulations, Electrochim. Acta53 (2007) 1743–1753. 10.1016/j.electacta.2007.08.035Suche in Google Scholar
35. Mu, G. and Li, X.: Inhibition of cold rolled steel corrosion by Tween-20 in sulfuric acid: Weight loss, electrochemical and AFM approaches, J Colloid Interface Sci.289 (2005) 184–192. 10.1016/j.jcis.2005.03.061Suche in Google Scholar PubMed
36. Ozkir, D., Kayakirilmaz, K., Bayol, E., Gurten, A. A. and Kandemirli, F.: The inhibition effect of Azure A on mild steel in 1 M HCl. A complete study: Adsorption, temperature, duration and quantum chemical aspects, Corros. Sci.56 (2012) 143–152. 10.1016/j.corsci.2012.03.044Suche in Google Scholar
37. Migahed, M. A., Farag, A. A., Elsaed, S. M., Kamal, R., Mostfa, M. and Abd El-BaryH.: Synthesis of a new family of Schiff base nonionic surfactants and evaluation of their corrosion inhibition effect on X-65 type tubing steel in deep oil wells formation water Mater. Chem. Phys.125 (2011) 125–135. 10.1016/j.matchemphys.2010.08.082Suche in Google Scholar
© 2017, Carl Hanser Publisher, Munich
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Application
- The Influence of Natural and Synthetic Additives in Mitigating Calcium Phosphate Scale in Industrial Water Systems
- Preparation and Application of Double-Hydrophilic Copolymer as Scale and Corrosion Inhibitor for Industrial Water Recycling
- Removal of Insoluble Slimes from Potash Ore Using Flotation
- Ester-Based Pyridinium Gemini Surfactants as Novel Inhibitors for Mild Steel Corrosion in 1 M HCl Solution
- Novel Surfactants
- Benzalkonium Salts of Amino Acids – Physicochemical Properties and Anti-Microbial Activity
- Synthesis, Characterizations and Multifunctional Activities of New Thiourea-Based Non-Ionic Surfactants
- Environmental Chemistry
- Extraction of Natural Surfactant Saponin from Soapnut (Sapindus mukorossi) and its Utilization in the Remediation of Hexavalent Chromium from Contaminated Water
- Electrocatalytic Hydrogenolysis of Chlorophenolic Compounds by Modified Electrodes in Aqueous Medium in the Absence and the Presence of Ionic Surfactant
- Physical Chemistry
- Enzymatic Synthesis and Characterization of Sucrose Erucate
- Study of the Complex System of Fatty Alcohol Polyoxyethylene Ether Carboxylate and Alkyl Betaine for Heavy Oil Recovery
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Application
- The Influence of Natural and Synthetic Additives in Mitigating Calcium Phosphate Scale in Industrial Water Systems
- Preparation and Application of Double-Hydrophilic Copolymer as Scale and Corrosion Inhibitor for Industrial Water Recycling
- Removal of Insoluble Slimes from Potash Ore Using Flotation
- Ester-Based Pyridinium Gemini Surfactants as Novel Inhibitors for Mild Steel Corrosion in 1 M HCl Solution
- Novel Surfactants
- Benzalkonium Salts of Amino Acids – Physicochemical Properties and Anti-Microbial Activity
- Synthesis, Characterizations and Multifunctional Activities of New Thiourea-Based Non-Ionic Surfactants
- Environmental Chemistry
- Extraction of Natural Surfactant Saponin from Soapnut (Sapindus mukorossi) and its Utilization in the Remediation of Hexavalent Chromium from Contaminated Water
- Electrocatalytic Hydrogenolysis of Chlorophenolic Compounds by Modified Electrodes in Aqueous Medium in the Absence and the Presence of Ionic Surfactant
- Physical Chemistry
- Enzymatic Synthesis and Characterization of Sucrose Erucate
- Study of the Complex System of Fatty Alcohol Polyoxyethylene Ether Carboxylate and Alkyl Betaine for Heavy Oil Recovery