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Synthesis and Characterization of Saturated Cardanol Sulfonate Salt Gemini Surfactant

  • Yawen Zhou , Pengquan Su , Fu Han , Guiju Zhang and Baocai Xu
Published/Copyright: December 9, 2017
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 54 Issue 4

Abstract

The synthesis, structural analysis and properties of saturated cardanol sulfonate salt Gemini surfactant (Gemini-SCSS) were described and compared with saturated cardanol sulfonate salt (SCSS). The structure was characterized by infrared spectra and proton nuclear magnetic resonance. Gemini-SCSS reduced the surface tension of water to a minimum value of approximately 35 – 37 mN m−1 with concentrations of (0.9 − 2.0) × 10−4 mol L−1 and displayed low foamability and high emulsification, which were better than those of SCSS. Finally, Gemini-SCSS and SCSS both demonstrated good resistance to acid, alkali, hard water.

Kurzfassung

Die Synthese, die Struktur analyse und die Eigenschaften des gesättigten Cardanolsulfo natsalz-Geminitensids (Gemini-SCSS) wurden beschrieben und mit gesättigtem Cardanolsulfonatsalz-Tensid (SCSS) verglichen. Die Struktur wurde durch Infrarotspektren und Protonen-Kern resonanz charakterisiert. Gemini-SCSS reduzierte die Oberflächenspannung von Wasser auf einen Mindestwert von ca. 35 – 37 mN m−1, wobei die Gemini-SCSS-Konzentration (0,9 – 2,0) × 10−4 mol L−1 betrug. Gemini-SCSS zeigte ein geringes Schaumvermögen und eine hohe Emulsionsbildung, die besser als die von SCSS ist. Schließlich zeigten sowohl Gemini-SCSS als auch SCSS eine gute Resistenz gegen Säure, Alkali und hartes Wasser.

Key words: Gemini surfactant; surface activity; synthesis; cardanol
Stichwörter: Gemini-Tensid; Oberflächenaktivität; Synthese; Cardanol
*Correspondence address, Baocai Xu, School of Food and Chemical Engineering, Beijing Technology and Business University, No. 11 Fucheng Road, Haidian District, Beijing 100048, P.R. China, E-Mail:

Yawen Zhou received a M. S. in Applied Chemistry from China Research Institute of Daily Chemical Industry. She is an associate professor with a research field in synthesis and properties of surfactants.

Pengquan Su is a postgraduate student in Applied Chemistry in Beijing Technology and Business University. His research interests are synthesis and properties of surfactants.

Fu Han received a Ph.D. in Physicochemistry from Wuhan University. He is an associate professor with a research field in synthesis and properties of surfactants.

Guiju Zhang received a Ph.D. in Organic Chemistry from Technical Institute of Physics and Chemistry of the Chinese Academy of Sciences. She is a lecturer with a research field in synthesis and properties of surfactants.

Baocai Xu received a Ph.D. in Applied Chemistry from Beijing Institute of Technology. He is a professor at Beijing Key Laboratory of Flavor Chemistry, Beijing Higher Institution Engineering Research Center of Food Additives and Ingredients, with a research field in synthesis and properties of surfactants.

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Received: 2016-06-27
Accepted: 2016-11-08
Published Online: 2017-12-09
Published in Print: 2017-07-14

© 2017, Carl Hanser Publisher, Munich

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  2. Contents
  3. Detergent/Cleaning
  4. Consumers' Comprehension of the EU Energy Label for Washing Machines
  5. Effect of Washing Conditions on Cleaning Action of Linear Alkylbenzene Sulfonate in Hard Water
  6. Biosurfactants/Novel Surfactants
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  15. Application
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https://doi.org/10.3139/113.110504
Keywords for this article
Gemini surfactant; surface activity; synthesis; cardanol

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Detergent/Cleaning
  4. Consumers' Comprehension of the EU Energy Label for Washing Machines
  5. Effect of Washing Conditions on Cleaning Action of Linear Alkylbenzene Sulfonate in Hard Water
  6. Biosurfactants/Novel Surfactants
  7. Surface Activity Study of Water-Soluble Silk Fibroin Prepared using Cocoons and Ca(NO3)2 · 4H2O
  8. Experimental Design Procedure for Optimization of Saponin Extraction from Glycyrrhiza glabra: A Biosurfactant for Emulsification of Heavy Crude Oil
  9. Studies on Emulsification Properties of Glycolipids Biosurfactants
  10. Synthesis and Characterization of Saturated Cardanol Sulfonate Salt Gemini Surfactant
  11. Physical Chemistry
  12. Effect of Surface Dilatational Modulus on Foam Flow in a Porous Medium
  13. Oil-Water Interfacial Tensions of Silica Nanoparticle-Surfactant Formulations
  14. Interactions of Cationic, Anionic and Nonionic Surfactants with Cresol Red Dye in Aqueous Solutions: Conductometric, Tensiometric, and Spectroscopic Studies
  15. Application
  16. Physicochemical Properties of Amino Acid Surfactants and Their Use in Dyeing with Natural Plant Dyes
  17. Short Communication
  18. Demulsification of Water-in-Heavy Crude Oil Emulsion using Amphiphilic Ammonium Salts as Demulsifiers
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