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Magnetic Properties of Polyaniline/ZFe2O4 Nanocomposites Synthesized in CTAB as Surfactant and Ionic Liquid

  • Abdelkader Benabdellah , H. Belarbi , Hocine Ilikti , Tayeb Benabdallah and Mustapha Hatti
Published/Copyright: January 7, 2016
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 52 Issue 6

Abstract

Polyaniline (PANI-EB) containing ZFe2O4 (Z is an element in a divalent state; Z2+ = Fe2+, Co2+, Ni2+, Mn2+, and Zn2+) nanocomposites were successfully synthesized by using 1-butyl-3-methyl-imidazolium bromide [BMIM]Br and cetyl trimethylammonium bromide (CTAB) via in situ polymerization. Structural, morphological, spectroscopic and magnetic properties were investigated by transmission electron microscopy (TEM), X-ray powder diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR), vibrating sample magnetometry (VSM) respectively. The presence of polyaniline, [BMIM]Br and CTAB on the surface of the ZFe2O4 nanoparticles was confirmed with FTIR. The purity of the products was proved by XRD. The results of thermogravimetric analysis indicated that the addition of ZFe2O4 nanoparticles to PANI improved the thermal stability of the nanocomposites. The magnetization curves verify that the sample has ferromagnetic behavior at the temperature of 400 K. Magnetic measurements revealed that product has uniaxial anisotropy instead of expected cubic anisotropy according to the Stoner-Wohlfarth model.

Kurzfassung

Polyanilin (PANI-EB)/ZFe2O4-Nanocomposite (Z ist ein divalentes Ion; Z2+ = Fe2+, Co2+, Ni2+, Mn2+, und Zn2+) wurden erfolgreich mittels 1-Butyl-3-methylimidazoliumbromid ([BMIM]Br) und Cetyltrimethylammoniumbromid (CTAB) in einer in situ-Polymerisation synthetisiert. Die strukturellen, morphologischen, spektroskopischen und magnetischen Eigenschaften wurden mit der Transmissionselektronenmikroskopie (TEM), der Pulverröntgendiffraktomrie (XRD), der Fourier-Transformations-Infrarotspektroskopie (FT-IR) und der Vibrating Sample Magnetometry (VSM) untersucht. Die Anwesenheit von Polyanilin, [BMIM]Br und CTAB auf der Oberfläche der ZFe2O4-Nanopartikel wurde mit der FT-IR bestätigt. Die Reinheit der Produkte wurde mit der XRD überprüft. Die Ergebnisse der thermogravimetrischen Analyse ergaben, dass die Addition von ZFe2O4-Nanopartikeln zu PANI die thermische Stabilität der Nanopartikel verbesserte. Die Magnetisierungskurven bekräftigten, dass die Proben ein ferromagnetisches Verhalten bei einer Temperatur von 400 K besitzen. Die magnetischen Messungen zeigten, dass das Produkt eine uniaxiale Anisotropie hat anstatt der nach dem Stoner-Wohlfarth-Modell erwarteten kubischen Anisotropie.

Key words: Polyaniline; Nanocomposites; Ionic liquid; ZFe2O4; Magnetic properties
Stichwörter: Polyanilin; Nanocomposite; ionische Flüssigkeiten; ZFe2O4; magnetische Eigenschaften
*Correspondence address, Prof. Abdelkader Benabdellah, Synthesis and Catalysis Laboratory, Ibn Khaldoun University of Tiaret, Algeria, Renouvelables, CDER, Bou Ismail, 42415, W. Tipaza, Algeria. E-Mail:

Dr. Abdelkader Benabdellah was born in juin 1979. He completed his Post Graduation in 2003. He completed his Magister in 2006 and his Doctorate in 2013 from University of sciences and technology Oran (Algeria). At present he is working as a research professor at Ibn Khaldun University of Tiaret (Algeria). His area of research is “electrical systems based on conducting polymers and ionic liquids”.

Pr. H. Belarbi was born in 1965. He completed his Post Graduation in 1990. After completing his Ph.D. in 1997 from Montpellier II University France, he worked as Associate Professor in the Department of physics of Ibn Khaldoun University. At present he is working as full Professor and Dean of college of science and technology and materials science, Ibn Khaldoun University, Tiaret, (Algeria). His area of research is “electrical systems based on conducting polymers and ionic liquids”.

Pr. Hocine Ilikti was born in July 1958. He completed his Post Graduation in 1985. After completing his Magister 1992 and Doctorat in 2004 from University of sciences and technology Oran Algeria and University of Claude BERNARD, Lyon France, He is at present working as Professor in University of sciences and technology Oran Algeria. His area of research is “electrocatalytic hydrogenation of electrodes modifying by conductor polymers”.

Dr. Tayeb Benabdallah was born in 1957. He completed his Post Graduation in 1982. He completed his Ph.D. in 1988 at University of AIX-Marseille 2 France under the supervision Dr Dugulile Metti. At present he is working as Professor in University of sciences and technology Oran/Algeria.

Dr. Mustapha Hatti was born in November 1960. He completed his Post Graduation in 1988 after completing his Magister 2006 and Doctorat in 2010 from University of sciences and technology Oran (Algeria). At present he is working as Head of Division at Solar Equipment Development Unit, Bou Ismail, Tipaza, (Algeria). His area of research is “control and management of hybrid energy systems and fuel cells”.

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Received: 2015-01-11
Accepted: 2015-08-14
Published Online: 2016-01-07
Published in Print: 2015-11-16

© 2015, Carl Hanser Publisher, Munich

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https://doi.org/10.3139/113.110401
Keywords for this article
Polyaniline; Nanocomposites; Ionic liquid; ZFe2O4; Magnetic properties

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Hygiene and Washing
  4. Characterization of Microbial Communities in Household Washing Machines
  5. Hygiene in Domestic Laundering – Consumer Behavior in Germany
  6. Timesaving Washing of Textiles Utilizing 38 kHz Ultrasound
  7. Application
  8. Oil Extraction from Oil-Contaminated Drill Cuttings Using a Recyclable Single-Phase O/W Microemulsion
  9. Physical Chemistry
  10. Effect of Sodium Taurocholate on Aggregation Behavior of Amphiphilic Drug Solution
  11. Influence Prediction of Alkylamines Upon Electrical Percolation of AOT-based Microemulsions Using Artificial Neural Networks
  12. Effect of Tween 40 and Tween 60 on the Properties of a Cationic Slow-Set Emulsifier
  13. Magnetic Properties of Polyaniline/ZFe2O4 Nanocomposites Synthesized in CTAB as Surfactant and Ionic Liquid
  14. Novel Surfactants
  15. Ionic Liquid in Thin-Layer Chromatography of Anionic Surfactants: Selective Separation of Sodium Deoxycholate and Identification in Commercial Products
  16. Micellar Catalysis
  17. Combination of Best Promoter and Micellar Catalyst for Chromic Acid Oxidation of D-Arabinose in Aqueous Media at Room Temperature
  18. Environmental Chemistry
  19. Photocatalytic Degradation of Copper(II) Palmitates in Non Aqueous Media Using ZnO as Photocatalyst
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