Skip to main content
Article
Licensed
Unlicensed Requires Authentication

Effect of Tween 40 and Tween 60 on the Properties of a Cationic Slow-Set Emulsifier

  • and
Published/Copyright: January 7, 2016
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 52 Issue 6

Abstract

The properties of a cationic slow-set emulsifier named INDULIN SBT in the absence and presence of Tween 40 and Tween 60 is investigated in this paper. After adding Tween 40 and Tween 60, the interfacial tension and dilatational modulus of SBT have remarkable changes. Compared with the pure SBT system, the interfacial properties of the mixed surfactant systems are improved obviously, especially if the ratio of the mixtures is 1 : 1. The Zeta potentials are also the lowest with favorable storage stability in these systems. At suitable ratios, synergistic adsorption may take place, resulting in remarkable enhanced interfacial properties. The combination of SBT and Tween 40 as well as Tween 60 could be used as surfactant mixtures applied in asphalt emulsions.

Kurzfassung

Die Eigenschaften des langsam brechenden kationischen Emulgators INDULIN SBT in An- und Abwesenheit der Tenside Tween 40 und Tween 60 wurden untersucht. Nach Zugabe von Tween 40 und Tween 60 änderten sich die Grenflächenspannung und der Dilatationsmodulus von SBT deutlich. Verglichen mit dem reinem SBT-System sind die Grenzflächeneigenschaften der Mischtensidsystem verbessert, speziell die der Systeme mit einem Mischungsverhältnis von 1 : 1. Diese Systeme weisen auch die niedrigsten Zeta-Potenziale mit einer positiven Lagerstabilität auf. Bei geeigneten Verhältnissen findet eine synergistische Adsorption statt, die zu deutlich erhöhten Grenzflächeneigenschaften führt. Die Kombination aus SBT und Tween 40 bzw. Tween 60 könnte als Tensidmischung in Asphaltemulsionen eingesetzt werden.

Key words: surfactant mixture; slow-set emulsifier; interfacial rheology; oil/water interface; asphalt
Stichwörter: Tensidmischungen; langsam brechender Emulgator; Grenzflächenrheologie; Öl/Wasser-Grenzfläche; Asphalt
*Correspondence address, Dr. Jinyu Pang, Xuefu street No. 79, Taiyuan, 030006, P. R. China. Tel.: 086-18234154686, Fax: 086-03516998129. E-Mail:

Dr. Zhenfeng Li was born in July 1968. He completed his Post Graduation in 2001. After completing his Ph.D. in 2005 from Tongji University, Shanghai. He is at present working as Professor in Taiyuan University of Science and Technology, Taiyuan (Shanxi).

Dr. Jinyu Pang was born in May 1985. After completing her Ph.D. in 2012 from Shandong University, she is at present working as Senior Engineer in Shanxi Transportation Research Institute, Taiyuan (Shanxi).

References

1. Kim, Y., Im, S. and Lee, H. D.: Impacts of Curing Time and Moisture Content on Engineering Properties of Cold In-Place Recycling Mixtures Using Foamed or Emulsified Asphalt, J. Mater. Civ. Eng.23 (2011)) 542–553. 0000209. 10.1061/(ASCE)MT.1943-5533.Search in Google Scholar

2. Zhang, L. Y., Lawrence, S., Xu, Z. and Masliyah, J. H.: Studies of Athabasca asphaltene Langmuir films at air-water interface, J. Colloid Interface Sci.264 (2003)) 128–140;. 10.1016/S0021-9797(03)00355-2.Search in Google Scholar

3. Zhang, L. Y., Xu, Z. and Masliyah, J. H.: Langmuir and Langmuir-Blodgett films of mixed asphaltene and a demulsifier, Langmuir19 (2003)) 9730–9741. 10.1021/la034894nSearch in Google Scholar

4. Spiecker, P. M. and Kilpatrick, P. K.: Interfacial Rheology of Petroleum Asphaltenes at the Oil-Water Interface, Langmuir20 (2004)) 4022–4032. 10.1021/la0356351Search in Google Scholar PubMed

5. Li, M., Xu, M., Ma, Y., Wu, Z. and Christy, A.: Interfacial Film Properties of Asphaltenes and Resins, Fuel21 (2002)) 1847–1853. 10.1016/S0016-2361(02)00050-9Search in Google Scholar

6. Bouriat, P., El Kerri, N., Graciaa, A. and Lachaise, A.Properties of a two-dimensional asphaltene network at the water-cyclohexane interface deduced from dynamic tensiometry, Langmuir20 (2004)) 7459–7464. 10.1021/la049017bSearch in Google Scholar PubMed

7. Aske, N., Orr, R., Sjoblom, J. and Kallevik, H.: Interfacial Properties of Water-Crude Oil Systems Using the Oscillating Pendant Drop. Correlations to Asphaltene Solubility by Near Infrared Spectroscopy, J. Dispersion Sci. Technol.25 (2004)) 263–275. 120037694. 10.1081/DIS-Search in Google Scholar

8. Fainerman, V. B. and Lucassen-Reynders, E. H.: Adsorption of single and mixed ionic surfactants at fluid interfaces, Adv. Colloid Interface Sci.96 (2002)) 295–323. 10.1016/S0001-8686(01)00086-0Search in Google Scholar PubMed

9. Lucassen-Reynders, E. H., Cagna, A. and Lucassen, J.: Gibbs elasticity, surface dilational modulus and diffusional relaxation in nonionic surfactant monolayers, Colloids Surf. A186 (2001)) 63–72. 10.1016/S0927-7757(01)00483-6Search in Google Scholar

10. Fan, Y., Simon, S. and Sjblom, J.: Influence of Nonionic Surfactants on the Surface and Interfacial Film Properties of Asphaltenes Investigated by Langmuir Balance and Brewster Angle Microscopy, Langmuir26 (2010)) 10497–10505. 10.1021/la100258hSearch in Google Scholar PubMed

11. Dicharry, C., Arla, D., Sinquin, A., Graciaa, A. and Bouriat, P.: Stability of water/crude oil emulsions based on interfacial dilatational rheology, J. Colloid Interface Sci.297 (2006)) 785–791. 10.1016/j.jcis.2005.10.069Search in Google Scholar PubMed

12. Sztukowski, D. M. and Yarranton, H. W.: Rheology of asphaltene-Toluene/water interfaces, Langmuir21 (2005)) 11651–11658. 10.1021/la051921wSearch in Google Scholar PubMed

13. Bauget, F., Langevin, D. and Lenormand, R.: Dynamic surface properties of asphaltenes and resins at the oil-air interface, J. Colloid Interface Sci.239 (2001)) 501–508. 10.1006/jcis.2001.7566Search in Google Scholar PubMed

14. Kang, W., Xu, B., Wang, Y., Li, Y., Shan, X., An, F. and Liu, J.: Stability mechanism of W/O crude oil emulsion stabilized by polymer and surfactant, Colloids Surf. A384 (2011)) 555–560. 10.1016/j.colsurfa.2011.05.017Search in Google Scholar

15. Ortiz, D. P., Baydak, E. N. and Yarranton, H. W.: Effect of surfactants on interfacial films and stability of water-in-oil emulsions stabilized by asphaltenes, J. Colloid Interface Sci.351 (2010)) 542–555. 10.1016/j.jcis.2010.08.032Search in Google Scholar PubMed

16. Chen, L., Zhao, X., Wang, Z., Tang, J., Feng, B. and Tang, M.: Research on the Emulsifying Ability of Surfactants in Crude Oil, Tenside Surfactants Detergents50 (2013)) 434–440. 10.3139/113.110277Search in Google Scholar

17. Kabir-ud, D., Naqvi, A. Z. and Khan, A. B.: Micellization and Interfacial Behaviour of Amitriptyline-Nonionic Surfactant Systems in Aqueous Medium, Tenside Surfactants Detergents47 (2010)) 318–324. 10.3139/113.110084Search in Google Scholar

18. Sharma, L. and Sharma, S. C.: Tween-20 Modified Acacia nelotica and Oryza sativa Biomass for Enhanced Biosorption of Cr(VI) in Aqueous Environment, Tenside Surfactants Detergents52 (2015)) 41–53. 10.3139/113.110347Search in Google Scholar

19. Aske, N., Orr, R. and Sjoblom, J.: Dilatational elasticity moduli of water-crude oil interfaces using the oscillating pendant drop, J. Dispersion Sci. Technol.23 (2002)) 809–825. 10.1081/DIS-120015978Search in Google Scholar

20. Freer, E. M., Svitova, T. and Radke, C. J.: The role of interfacial rheology in reservoir mixed wettability, J. Petrol. Sci Eng.39 (2003)) 137–158. 10.1016/S0920-4105(03)00045-7Search in Google Scholar

21. Wang, F., Liu, Y. and Hu, S.: Effect of early cement hydration on the chemical stability of asphalt emulsion, Construction and Building Materials42 (2013)) 146–151. 10.1016/j.conbuildmat.2013.01.009Search in Google Scholar

22. Ravera, F., Ferrari, M., Santini, E. and Liggieri, L.: Influence of surface processes on the dilational visco-elasticity of surfactant solutions, Adv. Colloid Interface Sci.117 (2005)) 75–100. 10.1016/j.cis.2005.06.002Search in Google Scholar PubMed

23. Stubenrauch, C., Fainerman, V. B., Aksenenko, E. V. and Miller, R.: Adsorption behavior and dilational rheology of the cationic alkyl trimethylammonium bromides at the water/air interface, J. Phys. Chem. B109 (2005)) 1505–1509. 10.1021/jp046525lSearch in Google Scholar PubMed

24. He, F., Xu, G., Pang, J., Ao, M., Han, T. and Gong, H.Effect of Amino Acids on Aggregation Behaviors of Sodium Deoxycholate at Air/Water Surface: Surface Tension and Oscillating Bubble Studies, Langmuir27 (2011)) 538–545;. 10.1021/la103478c.Search in Google Scholar

25. Wu, D., Xu, G. Y., Feng, Y. J. and Li, Y. M.: Aggregation behaviors of gelatin with cationic gemini surfactant at air/water interface, Int. J. Biol. Macromol.40 (2007)) 345–350. 10.1016/j.ijbiomac.2006.09.004Search in Google Scholar PubMed

26. Ghosh, S. and Moulik, S. P.: Interfacial and Micellization Behaviors of Binary and Ternary Mixtures of Amphiphiles (Tween-20, Brij-35, and Sodium Dodecyl Sulfate) in Aqueous Medium, J. Colloid Interface Sci.208 (1998)) 357–366. 5752. 10.1006/jcis.1998.Search in Google Scholar

27. Ćirin, D. M., Poša, M. M. and KrstonošićV. S.: Interactions between Sodium Cholate or Sodium Deoxycholate and Nonionic Surfactant (Tween20 or Tween60) in Aqueous Solution, Industrial & Engineering Chemistry Research51 (2012)) 3670–3676. ie202373z. 10.1021/Search in Google Scholar

28. Stubenrauch, C. and Miller, R.: Stability of foam films and surface rheology: an oscillating bubble study at low frequencies, J. Phys. Chem. B108 (2004)) 6412–6421. 10.1021/jp049694e.Search in Google Scholar

Received: 2015-01-26
Accepted: 2015-04-21
Published Online: 2016-01-07
Published in Print: 2015-11-16

© 2015, Carl Hanser Publisher, Munich

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Hygiene and Washing
  4. Characterization of Microbial Communities in Household Washing Machines
  5. Hygiene in Domestic Laundering – Consumer Behavior in Germany
  6. Timesaving Washing of Textiles Utilizing 38 kHz Ultrasound
  7. Application
  8. Oil Extraction from Oil-Contaminated Drill Cuttings Using a Recyclable Single-Phase O/W Microemulsion
  9. Physical Chemistry
  10. Effect of Sodium Taurocholate on Aggregation Behavior of Amphiphilic Drug Solution
  11. Influence Prediction of Alkylamines Upon Electrical Percolation of AOT-based Microemulsions Using Artificial Neural Networks
  12. Effect of Tween 40 and Tween 60 on the Properties of a Cationic Slow-Set Emulsifier
  13. Magnetic Properties of Polyaniline/ZFe2O4 Nanocomposites Synthesized in CTAB as Surfactant and Ionic Liquid
  14. Novel Surfactants
  15. Ionic Liquid in Thin-Layer Chromatography of Anionic Surfactants: Selective Separation of Sodium Deoxycholate and Identification in Commercial Products
  16. Micellar Catalysis
  17. Combination of Best Promoter and Micellar Catalyst for Chromic Acid Oxidation of D-Arabinose in Aqueous Media at Room Temperature
  18. Environmental Chemistry
  19. Photocatalytic Degradation of Copper(II) Palmitates in Non Aqueous Media Using ZnO as Photocatalyst
https://doi.org/10.3139/113.110400
Keywords for this article
surfactant mixture; slow-set emulsifier; interfacial rheology; oil/water interface; asphalt

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Hygiene and Washing
  4. Characterization of Microbial Communities in Household Washing Machines
  5. Hygiene in Domestic Laundering – Consumer Behavior in Germany
  6. Timesaving Washing of Textiles Utilizing 38 kHz Ultrasound
  7. Application
  8. Oil Extraction from Oil-Contaminated Drill Cuttings Using a Recyclable Single-Phase O/W Microemulsion
  9. Physical Chemistry
  10. Effect of Sodium Taurocholate on Aggregation Behavior of Amphiphilic Drug Solution
  11. Influence Prediction of Alkylamines Upon Electrical Percolation of AOT-based Microemulsions Using Artificial Neural Networks
  12. Effect of Tween 40 and Tween 60 on the Properties of a Cationic Slow-Set Emulsifier
  13. Magnetic Properties of Polyaniline/ZFe2O4 Nanocomposites Synthesized in CTAB as Surfactant and Ionic Liquid
  14. Novel Surfactants
  15. Ionic Liquid in Thin-Layer Chromatography of Anionic Surfactants: Selective Separation of Sodium Deoxycholate and Identification in Commercial Products
  16. Micellar Catalysis
  17. Combination of Best Promoter and Micellar Catalyst for Chromic Acid Oxidation of D-Arabinose in Aqueous Media at Room Temperature
  18. Environmental Chemistry
  19. Photocatalytic Degradation of Copper(II) Palmitates in Non Aqueous Media Using ZnO as Photocatalyst
Downloaded on 16.4.2026 from https://www.degruyterbrill.com/document/doi/10.3139/113.110400/html
Scroll to top button