Combination of Best Promoter and Micellar Catalyst for Chromic Acid Oxidation of D-Arabinose in Aqueous Media at Room Temperature

Suzanna Malik; Bidyut Saha

doi:10.3139/113.110403

Article

Combination of Best Promoter and Micellar Catalyst for Chromic Acid Oxidation of D-Arabinose in Aqueous Media at Room Temperature

Suzanna Malik and Bidyut Saha

Published/Copyright: January 7, 2016

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From the journal Tenside Surfactants Detergents Volume 52 Issue 6

Abstract

The present paper describes the kinetics and mechanism for oxidation of D-arabinose by Cr(VI) in the presence of a micellar media. The anionic surfactant sodium dodecyl sulphate (SDS) and nonionic surfactant Triton-X-100 (TX-100) accelerate the process while the cationic surfactant N-cetylpyridinium chloride (CPC) retards the reaction. A suitable mechanism has been proposed. The reaction constants involved in different steps of the mechanism have been calculated. Formic acid and erythronic acid were reported as the products of oxidation of the sugar.

Kurzfassung

Dieser Beitrag beschreibt die Kinetik und den Mechanismus der Oxidation von D-Arabinose mit Cr(VI) im mizellaren Medium. Das anionische Tensid Natriumdodecylsulfat (SDS) und das nichtionische Tensid Triton X-100 beschleunigen den Prozess, während das kationische Tensid N-Cetylpyridiniumchlorid (CPC) die Reaktion behindert. Ein geeigneter Mechanismus wird vorgeschlagen. Die Konstanten der verschiedenen Schritte des Reaktionsmechanismus wurden berechnet. Ameisensäure und Erythronsäure sind die Oxidationsprodukte des Zuckers.

Key words: kinetics; oxidation; D-arabinose; Cr(VI); surfactant

Stichwörter: Kinetik; Oxidation; D-Arabinose; Cr(VI); Tenside

*Correspondence address, Dr. Bidyut Saha, Homogeneous Catalysis Laboratory, Department of Chemistry, The University of Burdwan, Burdwan 713104, WB, India. E-Mail: b_saha31@rediffmail.com

Susanta Malik: He was born in Kalna, Burdwan in 1988. He passed his M.Sc degree from the University of Burdwan in 2011 and got UGC-RGNF fellowship on the year 2012. He is working in my lab in “Homogeneous Catalysis” division.

Dr. Bidyut Saha: He was born in Birbhum, WB, India in 1975. He obtained his Ph.D degree from Visva Bharati University, India in 2007. He was a visiting scientist for the year 2009–2010 in the Department of Chemistry, UBC, Canada. Dr. Saha is presently working as an Associate Professor in the Department of Chemistry, Burdwan University, India. His area of interests is bioremediation of toxic metal, micellar catalysis and inorganic reaction mechanism. He has already published seventy papers in international journals.

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Received: 2015-10-22

Accepted: 2015-01-13

Published Online: 2016-01-07

Published in Print: 2015-11-16

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Articles in the same Issue

https://doi.org/10.3139/113.110403

Keywords for this article

kinetics; oxidation; D-arabinose; Cr(VI); surfactant