Startseite Micellization of Alkyl Trimethyl Ammonium Bromides in Aqueous Solutions–Part 1: Critical Micelle Concentration (CMC) and Ionization Degree
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Micellization of Alkyl Trimethyl Ammonium Bromides in Aqueous Solutions–Part 1: Critical Micelle Concentration (CMC) and Ionization Degree

  • Jarmila Oremusová
Veröffentlicht/Copyright: 1. März 2013
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 49 Heft 3

Abstract

Conductivities of alkyl trimethyl ammonium bromides (alkyl = hexyl-, octyl-, decyl-, dodecyl-, tetradecyl-, hexadecyl-, and octadecyl-) in aqueous solutions were measured as afunction of molarity of surfactants, length of chain and temperature. Critical micelle concentrations (CMC) were estimated from the dependence of the specific conductivity on molarity of the surfactants. It was determined that the temperature dependence of CMC is U-shaped with aminimum shifting toward higher temperatures with decreasing chain length of the alkyl group. Quantities characterizing behaviors of surfactants below and above CMC were calculated and compared from conductivity measurements. Measured and calculated values of studied compounds were also compared with results of many other authors. The paper has the form of a minireview. It is a comparison of the presented experimental data of alkyltrimethylammonium bromides (C6–C18) with earlier works reported.

Kurzfassung

Die Leitfähigkeiten von Alkyltrimethylammoniumbromiden (Alkyl = Hexyl, Octyl-, Decyl, Tetradecyl, Hexadecyl und Octadecyl) in wässriger Lösung wurden als Funktion der Tensidmolarität, der Kettenlänge und der Temperatur gemessen. Die kritische Mizellbildungkonzentration (CMC) wurde aus der Abhängigkeit der spezifischen Leitfähigkeit von der Molarität der Tenside berechnet. Es konnte gezeigt werden, dass die Temperatur als Funktion von der CMC einen U-förmigen Kurvenverlauf hat. Das Minimum bewegt sich zu höheren Temperaturen bei abnehmender Kettenlänge der Alkylgruppe. Größen, die das Verhalten der Tenside unter- und oberhalb der CMC charakterisieren, wurden berechnet und mit den Leitfähigkeitsmessungen verglichen. Die gemessenen und berechneten Werte der untersuchten Verbindungen wurden mit denen anderer Autoren verglichen. Dieser Beitrag ist ein Minireview. Die vorgestelleten experimentellen Daten für Alkyltrimethylammoniumbromide (C16–C18) werden mit den Ergebnissen aus früheren Arbeiten verglichen.

Key words:: Surfactants; quarternary ammonium salt; alkyl trimethyl ammonium bromides (C6–C18); critical micelle concentration (CMC); effect of temperature; ionization degree; degree of counterion binding
Stichwörter:: Tenside; quarternäre Ammoniumsalze; Alkyltrimethylammoniumbromide (C6–C18); kritische Mizellbildungskonzentration (CMC); Temperatureinfluss; Ionisierungsgrad; Grad der Gegenionenbindung
1 Jarmila Oremusová, Department of Physical Chemistry of DrugsFaculty of Pharmacy, Comenius University, Odbojárov 10, 832 32 Bratislava, Slovak Republic, Fax: +421250117100. E-mail:

Dr. Jarmila Oremusová, PhD., graduated from the Faculty of Chemical Technology, Slovak University of Technology in Bratislava, Slovakia, in 1983. She obtained PhD degree in 1990. Since 1989 she has been acting at the Department of Physical Chemistry of Drugs, Faculty of Pharmacy, Comenius University in Bratislava.

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Received: 2011-10-16
Revised: 2011-12-10
Published Online: 2013-03-01
Published in Print: 2012-05-01

© 2012, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. 7th European Detergents Conference (EDC)
  6. Biosurfactants as Antimicrobial Ingredients for Cleaning Products and Cosmetics
  7. Scientific Results and Economic Effects from the Centre for Surfactants Based on Natural Products (SNAP)
  8. Application
  9. Preparation and Performance of Catanionic Surfactants
  10. Environmental Chemistry
  11. Acrylic Acid-Allylpolyethoxy Carboxylate Copolymer Dispersant for Calcium Carbonate and Iron(III) Hydroxide Scales in Cooling Water Systems
  12. Novel Surfactants
  13. Lyotropic Liquid Crystals Formed in Brij35/Copolymer/Water System
  14. Physical Chemistry
  15. Micellization of Alkyl Trimethyl Ammonium Bromides in Aqueous Solutions–Part 1: Critical Micelle Concentration (CMC) and Ionization Degree
  16. Review
  17. Electrical Properties of PANI/Chalcogenide Junctions Doped with Ionic Liquids Anions
  18. Synthesis
  19. Synthesis of Quaternary Derivatives of Ortho-Coco Di-Amido Toluene and Investigation of these Compounds as Cationic Bitumen Emulsifier
  20. Synthesis and Surface Activity of Guerbet Betaine Surfactants with Ethylene Oxide Groups
  21. Research Group Portrait
  22. Investigations in the Stranski-Laboratorium of the TU Berlin – Physical Chemistry of Colloidal Systems – Going Towards Complexity and Functionality
https://doi.org/10.3139/113.110187
Schlagwörter für diesen Artikel
Surfactants; quarternary ammonium salt; alkyl trimethyl ammonium bromides (C6–C18); critical micelle concentration (CMC); effect of temperature; ionization degree; degree of counterion binding

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. 7th European Detergents Conference (EDC)
  6. Biosurfactants as Antimicrobial Ingredients for Cleaning Products and Cosmetics
  7. Scientific Results and Economic Effects from the Centre for Surfactants Based on Natural Products (SNAP)
  8. Application
  9. Preparation and Performance of Catanionic Surfactants
  10. Environmental Chemistry
  11. Acrylic Acid-Allylpolyethoxy Carboxylate Copolymer Dispersant for Calcium Carbonate and Iron(III) Hydroxide Scales in Cooling Water Systems
  12. Novel Surfactants
  13. Lyotropic Liquid Crystals Formed in Brij35/Copolymer/Water System
  14. Physical Chemistry
  15. Micellization of Alkyl Trimethyl Ammonium Bromides in Aqueous Solutions–Part 1: Critical Micelle Concentration (CMC) and Ionization Degree
  16. Review
  17. Electrical Properties of PANI/Chalcogenide Junctions Doped with Ionic Liquids Anions
  18. Synthesis
  19. Synthesis of Quaternary Derivatives of Ortho-Coco Di-Amido Toluene and Investigation of these Compounds as Cationic Bitumen Emulsifier
  20. Synthesis and Surface Activity of Guerbet Betaine Surfactants with Ethylene Oxide Groups
  21. Research Group Portrait
  22. Investigations in the Stranski-Laboratorium of the TU Berlin – Physical Chemistry of Colloidal Systems – Going Towards Complexity and Functionality
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