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Kinetic analysis of cellulose pyrolysis: a short review

  • Cristina Şerbănescu EMAIL logo
Veröffentlicht/Copyright: 12. März 2014
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Chemical Papers
Aus der Zeitschrift Chemical Papers Band 68 Heft 7

Abstract

Since the 1950s, cellulose pyrolysis has been the subject of intense study, with kinetic analyses forming a major part of these studies. They represent useful tools for a better understanding of the physicochemical process and for the proper design of industrial pyrolysis units. Until recently, the methods most frequently used in these analyses were based on model-fitting, i.e. the fitting of the experimental data to a number of mathematical models. Nowadays, other methods, so-called “model-free” methods, are considered to be more suited. These are based on the principle that, at constant conversion, the reaction rate depends only on temperature. In its first part, this short review presents the particularities and drawbacks of the traditional model-fitting models. Subsequently, several main contributions in this field are listed and discussed. Finally, the more suited “model-free” (isoconversional) methods are explained and several main studies presented, as well as a comparison of this method with the model-fitting ones.

Keywords: cellulose pyrolysis; model-fitting kinetic methods; isoconversional methods; TGA

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Published Online: 2014-3-12
Published in Print: 2014-7-1

© 2013 Institute of Chemistry, Slovak Academy of Sciences

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https://doi.org/10.2478/s11696-013-0529-z
Schlagwörter für diesen Artikel
cellulose pyrolysis; model-fitting kinetic methods; isoconversional methods; TGA

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  1. Kinetic analysis of cellulose pyrolysis: a short review
  2. Simultaneous determination of ciprofloxacin hydrochloride and hydrocortisone in ear drops by high performance liquid chromatography
  3. Inhibition effect of free ammonia and free nitrous acid on nitrite-oxidising bacteria during sludge liquor treatment: influence of feeding strategy
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  8. Synthesis, crystal structures, spectral, electrochemical and magnetic properties of di-µ-phenoxido-bridged dinuclear copper(II) complexes with N-salicylidene-2-hydroxybenzylamine derivatives: axial coordination effect of dimethyl sulphoxide molecule
  9. Hemilabile imino-phosphine palladium(II) complexes: synthesis, molecular structure, and evaluation in Heck reactions
  10. Structure and vibrational spectra of copper(II) 2-pyridylmethanolate tetrahydrate
  11. Synthesis and characterization of a silylated Brazilian clay mineral surface
  12. Nano-titanium oxide doped with gold, silver, and palladium — synthesis and structural characterization
  13. Synthesis and insecticidal activity of 6,8-dichloro-quinazoline derivatives containing a sulfide substructure
  14. Effect of extraction method on phenolic content and antioxidant activity of mistletoe extracts from Viscum album subsp. abietis
  15. Synthesis of melamine-formaldehyde resin functionalised with sulphonic groups and its catalytic activities
  16. Synthesis, characterization, and application of a new tripodal ligand for the preparation of LSCF(6482) perovskite
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