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Activity and regenerability of dealuminated zeolite Y in liquid phase alkylation of benzene with 1-alkene

  • Michal Horňáček EMAIL logo , Pavol Hudec , Andrej Nociar , Agáta Smiešková and Tibor Jakubík
Published/Copyright: May 6, 2010
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Abstract

HY-zeolite and its deep-bed dealuminated and EFAL-extracted forms were tested in liquid phase alkylation of benzene with 1-hexadecene in a batch reactor at 120°C. Deep-bed dealumination of the HY-sample at 560 °C followed by careful selective extraction of extra-framework aluminium by hydrochloric acid increased the catalytic activity as well as oxidative regenerability of Y-zeolite.

[1] Bartková, A., Hudec, P., Smiešková, A., & Horňáček, M. (2006). Influence of synthesis conditions of ZSM-5 zeolite on particle properties and catalytic activity. In Proceeding of XIII. Polish Zeolite Meeting, 10–15 September 2006 (pp.158–163). Polanczyk, Poland. Search in Google Scholar

[2] Bordoloi, A., Devassy, B. M., Niphadkar, P. S., Joshi, P. N., & Halligudi, S. B. (2006). Shape selective synthesis of longchain linear alkyl benzene (LAB) with AlMCM-41/Beta zeolite composite catalyst. Journal of Molecular Catalysis A: Chemical, 253, 239–244. DOI: 10.1016/j.molcata.2006.03.045. http://dx.doi.org/10.1016/j.molcata.2006.03.04510.1016/j.molcata.2006.03.045Search in Google Scholar

[3] de Almeida, J. L. G., Dufaux, M., Ben Taarit, Y., & Naccache, C. (1994). Linear alkylbenzene. Journal of the American Oil Chemists’ Society, 71, 675–694. DOI: 10.1007/BF02541423. http://dx.doi.org/10.1007/BF0254142310.1007/BF02541423Search in Google Scholar

[4] Emeis, C. A. (1993). Determination of integrated molar extinction coefficients for infrared absorption bands of pyridine adsorbed on solid acid catalysis. Journal of Catalysis, 141, 347–354. DOI: 10.1006/jcat.1993.1145. http://dx.doi.org/10.1006/jcat.1993.114510.1006/jcat.1993.1145Search in Google Scholar

[5] Fichtner-Schmittler, H., Lohse, U., Miessner, H., & Maneck, H. E. (1990). Correlation between unit-cell parameter, skeletal stretching vibrations and molar fraction of aluminium of faujasite type zeolite for Si: Al = 1.1–1000. Zeitschrift für Physikalische Chemie — Leipzig, 271, 69–79. Search in Google Scholar

[6] Guisnet, M., & Magnoux, P. (1997). Deactivation by coking of zeolite catalysts. Prevention of deactivation. Optimal conditions for regeneration. Catalysis Today, 36, 477–483. DOI: 10.1016/S0920-5861(96)00238-6. http://dx.doi.org/10.1016/S0920-5861(96)00238-610.1016/S0920-5861(96)00238-6Search in Google Scholar

[7] Guisnet, M., & Magnoux, P. (1994). Fundamental description of deactivation and regeneration of acid zeolites. Studies in Surface Science and Catalysis, 88, 53–68. DOI: 10.1016/S0167-2991(08)62729-9. http://dx.doi.org/10.1016/S0167-2991(08)62729-910.1016/S0167-2991(08)62729-9Search in Google Scholar

[8] Horňáček, M., Hudec, P., Smiešková, A., & Jakubík, T. (2010). Alkylation of benzene with 1-alkenes over beta zeolites in liquid phase. Reaction Kinetics, Mechanisms and Catalysis, 99, 431–437. DOI: 10.1007/s11144-009-0109-y. 10.1007/s11144-009-0109-ySearch in Google Scholar

[9] Hudec, P., Nociar, A., Smiešková, A., & Jakubík, T. (2007). Liquid-phase alkylation of benzene by long-chain linear α-olefins over Y and mordenite type catalysts. Influence of Si/Al ratio. Studies in Surface Science and Catalysis, 158B, 1795–1802. DOI: 10.1016/S0167-2991(05)80540-3. 10.1016/S0167-2991(05)80540-3Search in Google Scholar

[10] Lenarda, L., Storaro, L., Pellegrini, G., Piovesan, L., & Ganzerla, R. (1999). Solid acid catalysts from clays: Part 3: benzene alkylation with ethylene catalyzed by aluminum and aluminum gallium pillared bentonites. Journal of Molecular Catalysis A: Chemical, 145, 237–244. DOI: 10.1016/S1381-1169(99)00019-9. http://dx.doi.org/10.1016/S1381-1169(99)00019-910.1016/S1381-1169(99)00019-9Search in Google Scholar

[11] Li, Y., Xue, B., & He, X. (2009). Synthesis of ethylbenzene by alkylation of benzene with diethyl carbonate over parent MCM-22 and hydrothermally treated MCM-22. Journal of Molecular Catalysis A: Chemical, 301, 106–113. DOI: 10.1016/j.molcata.2008.11.018. http://dx.doi.org/10.1016/j.molcata.2008.11.01810.1016/j.molcata.2008.11.018Search in Google Scholar

[12] Liang, W., Jin, Y., Yu, Z., Wang, Z., Han, B., He, M., & Min, E. (1996). Alkylation of benzene with dodecene over HY zeolite: Deactivation, regeneration, and product distribution. Zeolites, 17, 297–303. DOI: 10.1016/0144-2449(96)00034-6. http://dx.doi.org/10.1016/0144-2449(96)00034-610.1016/0144-2449(96)00034-6Search in Google Scholar

[13] Pujado, P. R. (1986). Handbook of petroleum refining processes. New York, NY, USA: McGraw-Hill. Search in Google Scholar

[14] Sawant, D. P., & Halligudi, S. B. (2005). Alkylation of benzene with α-olefins over zirconia supported 12-silicotungstic acid. Journal of Molecular Catalysis A: Chemical, 237, 137–145. DOI: 10.1016/j.molcata.2005.04.042. http://dx.doi.org/10.1016/j.molcata.2005.04.04210.1016/j.molcata.2005.04.042Search in Google Scholar

[15] Smieskova, A., Bocan, J., Hudec, P., & Zidek, Z. (1994). Selective extraction of extraframework aluminum from USY zeolite. Zeolites, 14, 553–556. DOI: 10.1016/0144-2449(94)90190-2. http://dx.doi.org/10.1016/0144-2449(94)90190-210.1016/0144-2449(94)90190-2Search in Google Scholar

[16] Tian, L., Li, J., Li, Y., & Chen, B. (2008). Synthesis of dodecylbenzene with benzene and 1-dodecene over MCM-22 zeolite modified with phosphorus. Chinese Journal of Catalysis, 29, 889–894. DOI: 10.1016/S1872-2067(08)60070-4. http://dx.doi.org/10.1016/S1872-2067(08)60070-410.1016/S1872-2067(08)60070-4Search in Google Scholar

[17] Thomas, B., Das, B. B., & Sugunan, S. (2006). Rare earth exchanged (Ce3+, La3+ and RE3+) H-Y zeolites as solid acid catalysts for the synthesis of linear alkyl benzenes. Microporous and Mesoporous Materials, 95, 329–338. DOI: 10.1016/j.micromeso.2006.05.035. http://dx.doi.org/10.1016/j.micromeso.2006.05.03510.1016/j.micromeso.2006.05.035Search in Google Scholar

[18] Xin, H., Wu, Q., Han, M., Wang, D., & Jin, Y. (2005). Alkylation of benzene with 1-dodecene in ionic liquids [Rmim]+ Al2Cl6X− (R = butyl, octyl and dodecyl; X = chlorine, bromine and iodine). Applied Catalysis A: General, 292, 354–361. DOI: 10.1016/j.apcata.2005.06.012. http://dx.doi.org/10.1016/j.apcata.2005.06.01210.1016/j.apcata.2005.06.012Search in Google Scholar

[19] Zhang, J., Chen, B., Li, C., Zhu, Z., Wen, L., & Min, E. (2003). Kinetics of benzene alkylation with 1-dodecene over a supported tungstophosphoric acid catalyst. Applied Catalysis A: General, 249, 27–34. DOI: 10.1016/S0926-860X(03)00206-0. Chemical Papers http://dx.doi.org/10.1016/S0926-860X(03)00206-010.1016/S0926-860X(03)00206-0Search in Google Scholar

Published Online: 2010-5-6
Published in Print: 2010-8-1

© 2010 Institute of Chemistry, Slovak Academy of Sciences

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