Oxidation of thiophene over copper-manganese mixed oxides
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Małgorzata Szynkowska
,
Aneta Węglińska
Abstract
Commercial hopcalite calcined at different temperatures and hopcalite modified with noble metals (Pt, Pd, and Au) were studied in oxidation of thiophene. Surface and bulk properties of catalysts were studied using temperature-programmed reduction (TPRH2), X-ray diffraction method (XRD) and thermal analysis (TG-DTA-MS). It was shown that calcined samples displayed higher activity in comparison with commercial untreated hopcalite; however, a lower temperature of calcination was favourable. High temperature of thermal treatment induced an increase in the crystallinity and a decrease in the surface area of the samples, and, as a consequence, the loss of catalysts activity. Moreover, marked improvement in the catalytic performance of platinum and palladium modified catalysts in relation to base hopcalite was observed. The obtained results indicate that the higher activity of samples containing Pt and Pd was accompanied by better reducibility of the catalysts.
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© 2008 Institute of Chemistry, Slovak Academy of Sciences
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Artikel in diesem Heft
- Biosynthesis of methanol from methane by Methylosinus trichosporium OB3b
- Influence of reaction medium composition on enzymatic synthesis of galactooligosaccharides and lactulose from lactose concentrates prepared from whey permeate
- Immobilization of modified penicillin G acylase on Sepabeads carriers
- Granulation of activated sludge in a laboratory upflow sludge blanket reactor
- Investigation of the effect of fluid elasticity on a cake filtration process
- Lab-scale testing of a low-loaded activated sludge process with membrane filtration
- Calcium sulphate scaling in membrane distillation process
- Characterization and filtration performance of coating-modified polymeric membranes used in membrane bioreactors
- Informational analysis of the grinding process of granular material using a multi-ribbon blender
- Effects of vessel baffling on the drawdown of floating solids
- N2O catalytic decomposition — effect of pelleting pressure on activity of Co-Mn-Al mixed oxide catalysts
- Intelligent control of a pH process
- Influence of suspended solid particles on gas-liquid mass transfer coefficient in a system stirred by double impellers
- A three-phase nonequilibrium model for catalytic distillation
- Membrane processes used for separation of effluents from wire productions
- A simple and efficient synthesis of 3-substituted derivatives of pentane-2,4-dione
- Formation of hydrated titanium dioxide from seeded titanyl sulphate solution
- Pyrolytic and catalytic conversion of rape oil into aromatic and aliphatic fractions in a fixed bed reactor on Al2O3 and Al2O3/B2O3 catalysts
- Oxidation of thiophene over copper-manganese mixed oxides
- Study of partitioning and dynamics of metals in contaminated soil using modified four-step BCR sequential extraction procedure
- Preparation and properties of a new composite photocatalyst based on nanosized titanium dioxide
