Startseite Kinetics of pyrolysis and properties of carbon black from a scrap tire
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Kinetics of pyrolysis and properties of carbon black from a scrap tire

  • Z. Koreňová EMAIL logo , M. Juma , J. Annus , J. Markoš und L’. Jelemenský
Veröffentlicht/Copyright: 1. Dezember 2006
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Abstract

The pyrolysis of rubber from the sidewall and tread of a passenger car tire was carried out in a nitrogen flow at a wide range of final temperatures. Derivative thermogravimetric analysis (DTG) was applied to examine the kinetics at the different process conditions of completed pyrolysis. Two characteristic stages were observed in the DTG curves. The first stage corresponded to the decomposition of processing oil, plastifier, and additives, whereas the rubber polymer was decomposed in the second stage. Several properties of the carbon black formed by the pyrolysis such as ash content, specific surface area, and pore size distribution were determined. A change of the internal structure of the rubber particle in the meso-and macroregions of the pore size was observed.

[1] Sharma, V. K., Fortuna, F., Mincarini, M., Berillo, M., and Cornacchia, G., Appl. Energy 65, 381 (2000). http://dx.doi.org/10.1016/S0306-2619(99)00085-910.1016/S0306-2619(99)00085-9Suche in Google Scholar

[2] Leung, D. Y. C. and Wang, C. L., J. Anal. Appl. Pyrolysis 45, 153 (1998). http://dx.doi.org/10.1016/S0165-2370(98)00065-510.1016/S0165-2370(98)00065-5Suche in Google Scholar

[3] Koreňová, Z., Juma, M., Holíková, K., Jelemenský, L’., and Markoš, J., Petroleum & Coal 47, 1 (2005). Suche in Google Scholar

[4] Juma, M., Koreňová, Z., Markoš, J., Annus, J., and Jelemenský, L’., Petroleum & Coal 48 15 (2006). Suche in Google Scholar

[5] de Marco Rodriguez, I., Laresgoiti, M. F., Cabrero, M. A., Torres, A., Chomon, M. J., and Caballero, B., Fuel Process. Technol. 72, 9 (2001). http://dx.doi.org/10.1016/S0378-3820(01)00174-610.1016/S0378-3820(01)00174-6Suche in Google Scholar

[6] Zabaniotou, A. A. and Stavropoulos, G., J. Anal. Appl. Pyrolysis 70, 711 (2003). http://dx.doi.org/10.1016/S0165-2370(03)00042-110.1016/S0165-2370(03)00042-1Suche in Google Scholar

[7] Berrueco, C., Esperanza, E., Mastral, F. J., Ceamanos, J., and Garcia-Bacaicoa, P., J. Anal. Appl. Pyrolysis 74, 245 (2005). http://dx.doi.org/10.1016/j.jaap.2004.10.00710.1016/j.jaap.2004.10.007Suche in Google Scholar

[8] Conesa, J. A., Font, R., Fullana, A., and Caballero, J. A., Fuel 77, 1469 (1998). http://dx.doi.org/10.1016/S0016-2361(98)00068-410.1016/S0016-2361(98)00068-4Suche in Google Scholar

[9] Barbooti, M. M., Mohamed, T. J., Hussain, A. A., and Abas, F. O., J. Anal. Appl. Pyrolysis 72, 165 (2004). http://dx.doi.org/10.1016/j.jaap.2004.05.00110.1016/j.jaap.2004.05.001Suche in Google Scholar

[10] Pantea, D., Darmstadt, H., Kaliaguine, S., and Roy, C., J. Anal. Appl. Pyrolysis 67, 55 (2003). http://dx.doi.org/10.1016/S0165-2370(02)00017-710.1016/S0165-2370(02)00017-7Suche in Google Scholar

[11] Roy, C., Chaala, A., and Darmstadt, H., J. Anal. Appl. Pyrolysis 51, 201 (1999). http://dx.doi.org/10.1016/S0165-2370(99)00017-010.1016/S0165-2370(99)00017-0Suche in Google Scholar

[12] Chaala, A., Darmstadt, H., and Roy, C., Fuel Process. Technol. 46, 1 (1996). http://dx.doi.org/10.1016/0378-3820(95)00044-510.1016/0378-3820(95)00044-5Suche in Google Scholar

[13] Mui, E. L. K., Ko, D. C. K., and McKay, G., Carbon 42, 2789 (2004). http://dx.doi.org/10.1016/j.carbon.2004.06.02310.1016/j.carbon.2004.06.023Suche in Google Scholar

[14] Zabaniotou, A., Madau, P., Oudenne, P. D., Jung, C. G., Delplancke, M.-P., and Fontana, A., J. Anal. Appl. Pyrolysis 72, 289 (2004). http://dx.doi.org/10.1016/j.jaap.2004.08.00210.1016/j.jaap.2004.08.002Suche in Google Scholar

[15] Murillo, R., Navarro, M. V., Lopez, J. M., Garcia, T., Callen, M. S., Aylon, E., and Mastral, A. M., J. Anal. Appl. Pyrolysis 71, 945 (2004). http://dx.doi.org/10.1016/j.jaap.2003.12.00510.1016/j.jaap.2003.12.005Suche in Google Scholar

[16] Darmstadt, H., Roy, C., and Kaliaguine, S., Carbon 33, 1449 (1995). http://dx.doi.org/10.1016/0008-6223(95)00096-V10.1016/0008-6223(95)00096-VSuche in Google Scholar

[17] Chen, F. and Qian, J., Waste Manage. 23, 463 (2003). http://dx.doi.org/10.1016/S0956-053X(03)00090-410.1016/S0956-053X(03)00090-4Suche in Google Scholar

[18] Conesa, J. A. and Marcilla, A., J. Anal. Appl. Pyrolysis 37, 95 (1996). http://dx.doi.org/10.1016/0165-2370(96)00942-410.1016/0165-2370(96)00942-4Suche in Google Scholar

[19] Williams, P. T. and Besler, S., Fuel 74, 1277 (1995). http://dx.doi.org/10.1016/0016-2361(95)00083-H10.1016/0016-2361(95)00083-HSuche in Google Scholar

[20] Galvagno, S., Casu, S., Casabianca, T., Calabrese, A., and Cornacchia, G., Waste Manage. 22, 917 (2002). http://dx.doi.org/10.1016/S0956-053X(02)00083-110.1016/S0956-053X(02)00083-1Suche in Google Scholar

[21] Teng, H., Serio, M. A., Wójtowicz, M. A., Bassilakis, R., and Solomon, P. R., Ind. Chem. Eng. Res. 34, 3102 (1995). http://dx.doi.org/10.1021/ie00048a02310.1021/ie00048a023Suche in Google Scholar

[22] Murrilo, R., Aranda, A., Aylon, E., Callen, M. S., and Mastral A. M., Ind. Eng. Chem. Res. 45, 1734 (2006). http://dx.doi.org/10.1021/ie050642110.1021/ie0506421Suche in Google Scholar

[23] Lin, J.-P., Chang, C.-Y., and Wu, C.-H., J. Hazard. Mater. 58, 227 (1998). http://dx.doi.org/10.1016/S0304-3894(97)00134-910.1016/S0304-3894(97)00134-9Suche in Google Scholar

[24] Aylón, E., Callén, M. S., López, J. M., Mastral, A. M., Murillo, R., Navarro, M. V., and Stelmach, S., J. Anal. Appl. Pyrolysis 74, 259 (2005). http://dx.doi.org/10.1016/j.jaap.2004.09.00610.1016/j.jaap.2004.09.006Suche in Google Scholar

[25] Chen, J. H., Chen, K. S., and Tong, L. Y., J. Hazard. Mater. 84, 43 (2001). http://dx.doi.org/10.1016/S0304-3894(01)00180-710.1016/S0304-3894(01)00180-7Suche in Google Scholar

[26] Chen, K. S., Yeh, R. Z., and Chang, Y. R., Combust. Flame 108, 408 (1997). http://dx.doi.org/10.1016/S0010-2180(96)00142-310.1016/S0010-2180(96)00142-3Suche in Google Scholar

[27] Kim, S. D., Park, J. K., and Chun, H. D., J. Environ. Eng. 121, 507 (1995). http://dx.doi.org/10.1061/(ASCE)0733-9372(1995)121:7(507)10.1061/(ASCE)0733-9372(1995)121:7(507)Suche in Google Scholar

[28] Yang, J., Tanguy, P. A., and Roy, C., Chem. Eng. Sci. 50, 1909 (1995). http://dx.doi.org/10.1016/0009-2509(95)00062-A10.1016/0009-2509(95)00062-ASuche in Google Scholar

[29] Žajdlík, R., PhD. Thesis. Slovak University of Technology, Bratislava, 2001. Suche in Google Scholar

[30] Žajdlík, R., Jelemenský, L’., Remiarová, B., and Markoš, J., Chem. Eng. Sci. 56, 1355 (2001). http://dx.doi.org/10.1016/S0009-2509(00)00358-410.1016/S0009-2509(00)00358-4Suche in Google Scholar

[31] Žajdlík, R., Markoš, J., Jelemenský, L’., and Remiarová, B., Chem. Pap. 54, 467 (2000). Suche in Google Scholar

[32] Ucar, S., Karagoz, S., Ozkan, A. R., and Yanik, J., Fuel 84, 1884 (2005). http://dx.doi.org/10.1016/j.fuel.2005.04.00210.1016/j.fuel.2005.04.002Suche in Google Scholar

[33] Kaminsky, W. and Mennerich, C., J. Anal. Appl. Pyrolysis 58–59, 803 (2001). http://dx.doi.org/10.1016/S0165-2370(00)00129-710.1016/S0165-2370(00)00129-7Suche in Google Scholar

Published Online: 2006-12-1
Published in Print: 2006-12-1

© 2006 Institute of Chemistry, Slovak Academy of Sciences

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