The thermal equation of state of FeTiO3 ilmenite based on in situ X-ray diffraction at high pressures and temperatures
-
E.J. Tronche
,
M. van Kan Parker
Abstract
We present in situ measurements of the unit-cell volume of a natural terrestrial ilmenite (Jagersfontein mine, South Africa) and a synthetic reduced ilmenite (FeTiO3) at simultaneous high pressure and high temperature up to 16 GPa and 1273 K. Unit-cell volumes were determined using energy-dispersive synchrotron X-ray diffraction in a multi-anvil press. Mössbauer analyses show that the synthetic sample contained insignificant amounts of Fe3+ both before and after the experiment. Results were fit to Birch- Murnaghan thermal equations of state, which reproduce the experimental data to within 0.5 and 0.7 GPa for the synthetic and natural samples, respectively. At ambient conditions, the unit-cell volume of the natural sample [V0 = 314.75 ± 0.23 (1σ) Å3] is significantly smaller than that of the synthetic sample [V0 = 319.12 ± 0.26 Å3]. The difference can be attributed to the presence of impurities and Fe3+ in the natural sample. The 1 bar isothermal bulk moduli KT0 for the reduced ilmenite is slightly larger than for the natural ilmenite (181 ± 7 and 165 ± 6 GPa, respectively), with pressure derivatives K0′ = 3 ± 1. Our results, combined with literature data, suggest that the unit-cell volume of reduced ilmenite is significantly larger than that of oxidized ilmenite, whereas their thermoelastic parameters are similar. Our data provide more appropriate input parameters for thermo-chemical models of lunar interior evolution, in which reduced ilmenite plays a critical role.
© 2015 by Walter de Gruyter Berlin/Boston
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- Natrolite may not be a “soda-stone” anymore: Structural study of fully K-, Rb-, and Cs-exchanged natrolite
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- XRD, micro-XANES, EMPA, and SIMS investigation on phlogopite single crystals from Mt. Vulture (Italy)
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