New Mineral Names
-
Christopher Emproto
Abstract
This issue of New Mineral Names highlights some of the newly described minerals as reported by the IMA and recently published/in press articles from January–March 2024. The minerals included are: pfaffenbergite, pabellóndepicaite, allanite-(Sm), heflikite, kvačekite, and bimbowrieite.
Recently Approved
This section features just a few of the 30 minerals approved by the IMA-CNMNC for the period of January to April 2024; see Table 1 for the list and cursory details of all 30 minerals (Bosi et al. 2024a, 2024b).
New minerals approved by the IMA-CNMNC from January–March 2024a
Mineral | Formula | IMAb | Space group | Type locality area | Country | New RN | New ST |
---|---|---|---|---|---|---|---|
Ferrimuirite | Ba10(Ca2 |
2023-100 | P4mm | Gun claim | Canada | n | n |
Pabellóndepicaite | 2023-104 | Pnna | Pabellón de Pica | Chile | y | y | |
Tantalaeschynite-(Ce) | Ce(TiTa)O6 | 2023-058 | Pnma | Huangshan pegmatite | China | n | n |
Nipeiite-(Ce) | Ce9Fe3+(SiO4)6[SiO3(OH)](OH)3 | 2022-106a | R3c | Taiping | China | y | n |
Nigelcookite | 2023-113 | P21/m | Yushui deposit | China | y | n | |
Plumbojohntomaite | 2023-119 | P21/m | Yushui deposit | China | n | n | |
Kvacekite | NiSbSe | 2023-095 | P213 | Bukov mine | Czech Rep. | y | n |
Karlleuite | Ca2MnO4 | 2023-102 | I4/mmm | Caspar quarry | Germany | y | – |
Fluor-rewitzerite | [(H2O)K]Mn2(Al2Ti)(PO4)4(OF)(H2O)10·4 H2O | 2023-115 | P21/c | Hägendorf Süd pegmatite | Germany | n | n |
Sperlingite | (H2O)K(Mn2+Fe3+)(Al2Ti)(PO4)4[O(OH)][(H2O)9(OH)]·4 H2O | 2023-120 | P21/c | Hägendorf Süd pegmatite | Germany | y | – |
Pfaffenbergite | KNa3(Al4Si12)O32 | 2023-105 | P6/mmc | Pfaffenberg | Germany | y | n |
Moragite | Ca3TiSi2(Al2Si3)O14 | 2023-088 | P321 | Hartrurim basin | Israel | y | n |
Yamhamelachite | KCrP2O7 | 2023-103 | P21/c | Hartrurim basin | Israel | y | – |
Bacaferrite | BaCaFe4O8 | 2023-109 | P31m | Hartrurim basin | Israel | y | y |
Midbarite | Ca3Mg2(V2Si)O12 | 2023-110 | la3d | Hartrurim basin | Israel | y | n |
Shiranuiite | Cu+(Rh3+Rh4+)S4 | 2023-072a | Fd3m | Haraigawa | Japan | y | n |
Rinmanite-(Zn) | Zn2Sb2( |
2023-107 | P63mc | Near Nežilovo | N. Macedonia | n | n |
Cafeosite | 2021-022a | Cmce | Dhofar 225 meteorite | Oman | y | – | |
Allanite-(Sm) | CaSm(Al2Fe2+)(Si2O7)(SiO4)O(OH) | 2023-114 | P21/m | Jordanów serpentinite quarry | Poland | n | n |
Fluor-rossmanite | □(Al2Li)Al6(Si6O18)(BO3)3(OH)3F | 2023-111 | R3m | Krutaya pegmatite | Russia | n | n |
Manganohatertite | NaNaCa(MnFe3+)(AsO4)3 | 2023-098 | C2/c | Tolbachik volcano | Russia | n | n |
Vladkuzminite | K4CuZn3(AsO4)4 | 2023-106 | P21/n | Tolbachik volcano | Russia | y | y |
Geuerite | Ag2Tl4Pb4As22S40 | 2019-027a | P21/c | Lengenbach quarry | Switzerland | y | n |
Giuşcăite | Ag2Tl4Pb4As20Sb2S40 | 2023-099 | Pn | Lengenbach quarry | Switzerland | y | n |
Reckibachite | Ag2Pb12As14Sb4S40 | 2019-071 | P21/c | Reckibach | Switzerland | y | n |
Rundqvistite-(Ce) | Na3(Sr3Ce)[Zn2Si8O24] | 2023-043 | P21/c | Dara-i-Pioz massif | Tajikistan | y | n |
Fanguangite | (MoO2)(PO3OH)·4H2O | 2023-112 | P1 | Freedom No. 2 mine | U.S.A. | y | y |
Siligiite | [Pb(H2O)5(SO4)][Zn9(OH)18] | 2023-117 | P21/n | Redmond mine | U.S.A. | y | y |
Ferriphoxite | [(NH4)2K(H2O)][Fe3+(HPO4)2(C2O4)] | 2023-096 | P21/c | Rowley mine | U.S.A. | y | y |
Carboferriphoxite | [(NH4)K(H2CO3)][Fe3+(HPO4)(H2PO4)(C2O4)] | 2023-097 | P1 | Rowley mine | U.S.A. | n | y |
Notes: The type locality names have been simplified for readability on a chart and are organized by type locality and country of origin. The “New RN” column conveys which mineral names introduce a new root name. The “New ST” column displays which minerals are new structure types. The dash symbol in the “New ST” column indicates cases where it is unclear if the structure is novel.
a All minerals have been approved by the IMA-CNMNC. For a complete listing of all IMA-validated unnamed minerals and their codes, see http://cnmnc.units.it/ (click “IMA list of minerals”). The data contained within this chart were derived from Newsletters 77 and 78 (Bosi et al. 2024a, 2024b); individual references for each mineral can be found within. b Published or in-press (as of May 2024).
Pfaffenbergite, KNa3(Al4Si12)O32
Pfaffenbergite (IMA2023-105), ideally KNa3(Al4Si12)O32, is a new mineral isostructural with kokchetavite and wodegongjieite (Ferrero et al. 2024). The structure of pfaffenbergite is hexagonal, space group P6/mmc with cell parameters a = 10.258(3) and c = 14.775(5) Å. Pfaffenbergite, kokchetavite, and wodegongjieite have a sheet silicate structure with a topology identical to that of cymrite, wherein two tetrahedral sheets are joined by bridging apical O atoms with no octahedral sheet (Romanenko et al. 2021; Mugnaioli et al. 2022). The type specimen was collected at Pfaffenberg in Saxony, Germany, and its location of discovery is the origin of the new mineral’s name. Pfaffenberg hosts exposures of the Paleozoic-aged Bohemian massif, the core of which consists of a suite of high-pressure rocks, including eclogite, granulite, and garnet peridotite units. Pfaffenbergite, kokchetavite, and wodegongjieite were all first discovered in high-pressure rocks (Hwang et al. 2004; Xiong et al. 2020; Borghini et al. 2024). Kokchetavite has been reported elsewhere in the Bohemian massif (Ferrero et al. 2016). Type material is deposited at the University of Cagliari Leonard De Prunner Museum of Mineralogy, Via Trentino, Cagliari, Italy, with the designation “FIB foil no. 6461.”
Pabellóndepicaite,
C u 2 2 +
(N3C2H2)2(NH3)2(NO3)Cl·2H2O
Pabellóndepicaite (IMA2023-104), ideally
Allanite-(Sm), (CaSm)(AlAlFe2+)O[Si2O7][SiO4](OH)
Allanite-(Sm), ideally (CaSm)(AlAlFe2+)O[Si2O7][SiO4](OH), is a new Sm-dominant member of the epidote supergroup from a serpentinite quarry hosting granitic pegmatite dikes located near Jordanów Śląski, Poland (Pieczka et al. 2024a). With the addition of allanite-(Sm), there are now La, Ce, Nd, Sm, and Y members of the allanite group. Based on the lanthanide chemistry of known minerals, Gd and Yb end-members may also exist; however, light rare earth element (i.e., La, Ce, Nd) enrichment is more commonly encountered than heavy rare earth element (i.e., Y and Yb) enrichment in allanite. Middle rare earth element enrichment to an extent that warrants species status is extremely rare among minerals. Allanite-(Sm) is only the sixth mineral described to date with a middle rare earth element as an essential, site-defining element. Like other members of the epidote supergroup, allanite-(Sm) is monoclinic with P2/m symmetry. The cell parameters for allanite-(Sm) are a = 8.8923(6), b = 5.7005(3), c = 10.1280(8) Å, β = 115.445(9)°. Compared to the much more common group member allanite-(Ce) (a = 8.927, b = 5.761, c = 10.15 Å, β = 114.77°, V = 473.97 Å3), the unit-cell volume of allanite-(Sm) (463.59 Å3) is only marginally smaller than that of allanite-(Ce), an effect of lanthanide contraction. Based on experimental data, the unit-cell volume of (La,Y)-allanite decreases as Y concentration increases (Affholter 1987). Allanite-(Sm) is the first silicate mineral with essential Sm and the first middle rare earth element silicate mineral to be described. As such, the combination of Sm and Si alone makes the formula for allanite-(Sm) a currently unique combination of elements (www.mindat.org, retrieved May 2024). The serpentinite quarry where allanite-(Sm) was discovered is also the co-type locality for another chemically unusual member of the epidote supergroup—the new Sc-bearing mineral heflikite (Pieczka et al. 2024b). Type material is deposited at the University of Wrocław Mineralogical Museum in Wrocław, Poland, with catalog number MMUWr IV8151.
Recently Published
This section includes some of the minerals approved in 2023 and 2024 that have been recently published (or entered press).
Heflikite, Ca2(Al2Sc)(Si2O7)(SiO4)O(OH)
Heflikite, ideally Ca2(Al2Sc)(Si2O7)(SiO4)O(OH), is another new member of the epidote supergroup, also described from the serpentinite quarry near Jordanów Śląski, Poland (Pieczka et al. 2024b). Heflikite is the first Sc-bearing member of the epidote supergroup, and there are currently 23 minerals with essential Sc as of the time of writing. Heflikite occurs within granitic pegmatites that have intruded serpentinites of the Paleozoic-aged Ślęża ophiolite in the Bohemian massif. Sc-enriched epidote was first noted in scanning electron microscopy work in the late 1990s. More recent electron microprobe analyses identified Sc-rich zones within crystals that warranted its description as this new mineral. Pieczka et al. (2024) used focused ion beam (FIB) techniques to retrieve a foil of the Sc-rich zones for characterization. The structure of the heflikite holotype specimen was refined in space group P21/m with a = 8.9383(9) Å, b = 5.6830(5) Å, c = 10.1903(10) Å, β = 115.43(12)°. The holotype specimen is stored in the collections of the University of Wrocław Mineralogical Museum in Wrocław, Poland (catalog number MMUWr IV8120), and a co-type specimen is deposited in the collections of the Natural History Museum of the University of Oslo in Oslo, Norway, with catalog number KNR 44407.
Kvačekite, NiSbSe
Kvačekite, ideally NiSbSe, is a new selenide member of the cobaltite group from the Bukov Mine, Vysočina Region, Czech Republic (Pauliš et al. 2024). Kvačekite is isometric with P213 symmetry, a = 6.0901(13) Å. Within the cobaltite group, the most direct chemical analog of kvačekite is its S analog, ullmanite (NiSbS). Prior to its discovery in nature, powder diffraction experiments on synthetic material had earlier described an ullmanite structure for NiSbSe (Foecker and Jeitschko 2001). Despite its chemical simplicity, kvačekite has a unique combination of essential elements among known minerals. In fact, minerals with any combination of Ni, Sb, or Se are uncommon. According to www.mindat.org (accessed May 2024), there are only 12 Ni-Se minerals, 18 Ni-Sb minerals, and 14 Sb-Se minerals (kvačekite is counted in all three metrics). Despite the chemical diversity within the cobaltite group, microprobe data indicate that the type material investigated by Pauliš et al. (2024) represents near-end-member kvačekite with an empirical formula of (Ni0.95Cu0.04Co0.03)Σ1.02Sb1.00(Se0.97S0.01)Σ0.98. Type material is stored in the collection of the National Museum, Prague, Czech Republic, with catalog number P1P 26/2023.
Bimbowrieite, NaMg
F e 5 3 +
(PO4)4(OH)6·2H2O
Bimbowrieite (IMA2020-006), ideally NaMg
References cited
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© 2024 by Mineralogical Society of America
Articles in the same Issue
- Fingerprinting the source and complex history of ore fluids of a giant lode gold deposit using quartz textures and in-situ oxygen isotopes
- Cu isotope fractionation between Cu-bearing phases and hydrothermal fluids: Insights from ex situ and in situ experiments
- Barium mobility in a geothermal environment, Yellowstone National Park
- Single-crystal elasticity of humite-group minerals by Brillouin scattering
- Sulfur speciation in dacitic melts using X-ray absorption near-edge structure spectroscopy of the S K-edge (S-XANES): Consideration of radiation-induced changes and the implications for sulfur in natural arc systems
- Ab initio calculations and crystal structure simulations for mixed layer compounds from the tetradymite series
- A fast open data reduction workflow for the electron microprobe flank method to determine Fe3+/ΣFe contents in minerals
- Machine learning applied to apatite compositions for determining mineralization potential
- Reconstructing volatile exsolution in a porphyry ore-forming magma chamber: Perspectives from apatite inclusions
- Incommensurate to normal phase transition in malayaite
- Raman spectroscopic measurements on San Carlos olivine up to 14 GPa and 800 K: Implications for thermodynamic properties
- Chemical and boron isotopic composition of tourmaline from the Yixingzhai gold deposit, North China Craton: Proxies for ore fluids evolution and mineral exploration
- Tourmaline chemical and boron isotopic constraints on the magmatic-hydrothermal transition and rare-metal mineralization in alkali granitic systems
- New Mineral Names
Articles in the same Issue
- Fingerprinting the source and complex history of ore fluids of a giant lode gold deposit using quartz textures and in-situ oxygen isotopes
- Cu isotope fractionation between Cu-bearing phases and hydrothermal fluids: Insights from ex situ and in situ experiments
- Barium mobility in a geothermal environment, Yellowstone National Park
- Single-crystal elasticity of humite-group minerals by Brillouin scattering
- Sulfur speciation in dacitic melts using X-ray absorption near-edge structure spectroscopy of the S K-edge (S-XANES): Consideration of radiation-induced changes and the implications for sulfur in natural arc systems
- Ab initio calculations and crystal structure simulations for mixed layer compounds from the tetradymite series
- A fast open data reduction workflow for the electron microprobe flank method to determine Fe3+/ΣFe contents in minerals
- Machine learning applied to apatite compositions for determining mineralization potential
- Reconstructing volatile exsolution in a porphyry ore-forming magma chamber: Perspectives from apatite inclusions
- Incommensurate to normal phase transition in malayaite
- Raman spectroscopic measurements on San Carlos olivine up to 14 GPa and 800 K: Implications for thermodynamic properties
- Chemical and boron isotopic composition of tourmaline from the Yixingzhai gold deposit, North China Craton: Proxies for ore fluids evolution and mineral exploration
- Tourmaline chemical and boron isotopic constraints on the magmatic-hydrothermal transition and rare-metal mineralization in alkali granitic systems
- New Mineral Names