Abstract
The garnet-biotite-sillimanite enclaves from El Hoyazo are quenched anatectic metapelites found within peraluminous dacites (Betic Cordillera, SE Spain), representing a residual lower crust in the area after 40–60% of melt extraction. Anatexis occurred concomitantly with deformation in a regional metamorphic setting during the Upper Miocene at the base of the continental crust. Previous studies have provided detailed information on the pressure-temperature evolution, the sequence of melting reactions, and associated melt proportions and compositions. They show that enclaves mostly record peak metamorphic assemblages, mineral compositions, and, likely, microstructures, with minor changes upon entrapment within the dacite magma and rapid ascent and extrusion. The enclaves still preserve a proportion of the primary melt, that solidified to glass in abundant melt inclusions (MI) and matrix melt, permitting the study of the microstructural relationships between melt and residue. This study focuses on the geometry of the glass network at the microscale that, combined with the previously reported anatectic history, helps shed light on the mechanisms and history of melt drainage from these rocks.
A representative sample of the enclaves was investigated by synchrotron μ-XRF and scanning electron microscopy to map the distribution of glass and minerals on three thin sections cut perpendicularly to the foliation. The combination of major and trace element μ-XRF distribution maps and detailed backscattered electron images evidence the presence of a pervasive and mostly interconnected glass network through the studied centimeter-scale sections. Interconnection is due to the crosscutting of films and glass-rich domains oriented parallel and at high angle with foliation. Although enclaves lost ~40–60% of melt, they still contain ~10–15% of glass, with a considerable proportion of it stored within the Mix, which is an aggregate of micrometer-sized fibrolitic sillimanite and glass. The distribution of glass (former melt) is not in textural equilibrium with the solid residue and resembles the interconnected network of deformation bands observed in migmatites of anatectic terranes at the mesoscale.
Microstructural studies of melt pseudomorphs in migmatites and granulites of anatectic terranes are scarce, but the following remarkable interpretations can be made combining our observations of these enclaves: melt formed an interconnected network during anatexis that permitted melt segregation and extraction, though melt-residue textural disequilibrium is the rule rather than the exception. The proportion of melt present in residual migmatites can be much higher than the permeability threshold for crustal protoliths; in this particular study, two reasons for this might be that (1) melt was still being produced and flowing through the residual migmatite right before disaggregation and inclusion within the host dacite, where additional melt drainage was impeded by the hydrostatic stress field, and (2) a particular microstructure produced at the onset of anatexis, such as the Mix, acted as a trap for melt impeding or delaying melt segregation.
Acknowledgments
This work was funded by the Proyecto FAPA, Universidad de Los Andes (Bogotá, Colombia); the Centro Nacional de Pesquisa em Energia e Materiais, Brazilian Synchrotron Light Laboratory (LNLS), proposal no. XAFS1-17105; the CARIPARO (Cassa di Risparmio di Padova e Rovigo) project MAKEARTH; and the European Union’s Horizon 2020 research and innovation program, under the Marie Sklodowska-Curie grant agreement No. 654606. We are grateful to Charles LeLosq for advice on granite glass properties, two anonymous reviewers that provided numerous comments and suggestions on a previous version of this manuscript, Bernardo Cesare, an anonymous reviewer for their thorough and positive reviews; all of them greatly improved the original manuscript. S. Penniston-Dorland is thanked for insightful review and very careful editorial handling.
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- Chemical fingerprints and residence times of olivine in the 1959 Kilauea Iki eruption, Hawaii: Insights into picrite formation
- Predicting olivine composition using Raman spectroscopy through band shift and multivariate analyses
- Dehydrogenation and dehydroxylation as drivers of the thermal decomposition of Fe-chlorites
- High-pressure granulite facies metamorphism (~1.8 GPa) revealed in silica-undersaturated garnet-spinel-corundum gneiss, Central Maine Terrane, Connecticut, U.S.A.
- Letter
- Raman elastic geobarometry for anisotropic mineral inclusions
- Synthesis and crystal structure of Mg-bearing Fe9O11: New insight in the complexity of Fe-Mg oxides at conditions of the deep upper mantle
Articles in the same Issue
- Highlights and Breakthroughs
- Probing planetary core structure and dynamics using density and sound velocity
- Mapping the distribution of melt during anatexis at the source area of crustal granites by synchrotron μ-XRF
- Geochemical constraints on residual metal and sulfide in the sources of lunar mare basalts
- High-temperature behavior of natural ferrierite: In-situ synchrotron X-ray powder diffraction study
- The crystal chemistry of the sakhaite–harkerite solid solution
- Quantitative analysis of H-species in anisotropic minerals by unpolarized infrared spectroscopy: An experimental evaluation
- Liquid properties in the Fe-FeS system under moderate pressure: Tool box to model small planetary cores
- Solution mechanisms of COHN fluids in melts to upper mantle temperature, pressure, and redox conditions
- Dating phosphates of the strongly shocked Suizhou chondrite
- Quantitative measurement of olivine composition in three dimensions using helical-scan X-ray micro-tomography
- Chemical fingerprints and residence times of olivine in the 1959 Kilauea Iki eruption, Hawaii: Insights into picrite formation
- Predicting olivine composition using Raman spectroscopy through band shift and multivariate analyses
- Dehydrogenation and dehydroxylation as drivers of the thermal decomposition of Fe-chlorites
- High-pressure granulite facies metamorphism (~1.8 GPa) revealed in silica-undersaturated garnet-spinel-corundum gneiss, Central Maine Terrane, Connecticut, U.S.A.
- Letter
- Raman elastic geobarometry for anisotropic mineral inclusions
- Synthesis and crystal structure of Mg-bearing Fe9O11: New insight in the complexity of Fe-Mg oxides at conditions of the deep upper mantle