Ferruginous seawater facilitates the transformation of glauconite to chamosite: An example from the Mesoproterozoic Xiamaling Formation of North China
Abstract
Berthierine and chamosite are iron-rich clay minerals that share similar chemical compositions. Berthierine forms at low temperature (25–45 °C) during early diagenesis and may transfer to chamosite at temperatures of ≥70 °C. Because the formation of berthierine and chamosite requires significant amount of Fe2+ supply, their presence in marine sediments is often used as a mineral proxy for ferruginous conditions in porewater. Recent studies reveal that the Precambrian oceans were characterized by pervasive ferruginous water-column conditions that may favor the formation of iron-rich clay minerals like berthierine and chamosite. To evaluate if ferruginous water-column conditions in the Precambrian ocean played a role on iron-rich clay mineral formation, we conducted an integrated petrographic, mineralogical, and geochemical study on the chamosite- and glauconite-bearing strata of the Mesoproterozoic Xiamaling Formation (~1.40–1.35 Ga) in North China. Petrographic, XRD, SEM, and EDS analyses show that the chamosites of the Xiamaling Formation was transferred from glauconite, with berthierine as an intermediate mineral phase during early diagenesis. Geochemical analyses indicate that a complete transformation from glauconite-dominated to chamosite-dominated end-members (samples) requires an addition of a large amount of Fe (16.9 wt%), Mg (2.4 wt%), and a small amount of Al (1.4 wt%), but a simultaneous release of Si (11.8 wt%) and K (6.0 wt%). Considering that the glauconite- and chamosite-bearing strata are devoid of iron-rich detrital minerals (e.g., biotite and iron oxides) and lack evidence of hydrothermal alteration, the required Fe2+ for glauconite-berthierine-chamosite transformation was most likely from Fe2+-rich (ferruginous) seawater, which may have promoted glauconite-berthierine transformation at the very early diagenetic stage when Fe2+ exchange between porewater and seawater was still available. This interpretation is consistent with the high FeHR/FeT (but low Fepy/FeHR), Fe/Al, and V/Al ratios from the hosting strata that support ferruginous depositional environments. Because most Precambrian strata have passed the oil window temperature (>50–150 °C), the preservation of berthierine would be rare and chamosite should be the representative iron-rich clay mineral. Thus, the abundance of chamosite in fine-grained, marine siliciclastic sediments may be used as a mineral indicator of ferruginous water-column conditions.
Acknowledgments
The study was supported by the National Natural Science Foundation of China (Nos. 41672336 and 41402024). We thank Jianbai Ma for field assistance and sample preparation, Yong Han for her kind help in TEM analysis. We thank Warren Huff (Associate Editor), Peter Ryan, and an anonymous reviewer for their constructive comments that helped to improve the paper.
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- Ferruginous seawater facilitates the transformation of glauconite to chamosite: An example from the Mesoproterozoic Xiamaling Formation of North China
- Charleshatchettite, CaNb4O10(OH)2·8H2O, a new mineral from Mont Saint-Hilaire, Québec, Canada: Description, crystal-structure determination, and origin
- New Mineral Names
- Erratum
- Book Review
- Non-Traditional Stable Isotopes
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- Crystallization experiments in rhyolitic systems: The effect of temperature cycling and starting material on crystal size distribution
- Dolomite dissociation indicates ultra-deep (>150 km) subduction of a garnet-bearing dunite block (the Sulu UHP terrane)
- Microscopic strain in a grossular-pyrope solution anti-correlates with excess volume through local Mg-Ca cation arrangement, more strongly at high Ca/Mg ratio
- Ferruginous seawater facilitates the transformation of glauconite to chamosite: An example from the Mesoproterozoic Xiamaling Formation of North China
- Charleshatchettite, CaNb4O10(OH)2·8H2O, a new mineral from Mont Saint-Hilaire, Québec, Canada: Description, crystal-structure determination, and origin
- New Mineral Names
- Erratum
- Book Review
- Non-Traditional Stable Isotopes