Startseite Esperance: Multiple episodes of aqueous alteration involving fracture fills and coatings at Matijevic Hill, Mars
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Esperance: Multiple episodes of aqueous alteration involving fracture fills and coatings at Matijevic Hill, Mars

  • Benton C. Clark EMAIL logo , Richard V. Morris , Kenneth E. Herkenhoff , William H. Farrand , Ralf Gellert , Bradley L. Jolliff , Raymond E. Arvidson , Steven W. Squyres , David W. Mittlefehldt , Douglas W. Ming und Albert S. Yen
Veröffentlicht/Copyright: 7. Juli 2016
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Abstract

In the search for evidence of past aqueous activity by the Mars Exploration Rover Opportunity, fracture-filling veins and rock coatings are prime candidates for exploration. At one location within a segment of remaining rim material surrounding Endeavour Crater, a set of “boxwork” fractures in an outcrop called Esperance are filled by a bright, hydrated, and highly siliceous (SiO2 ~ 66 wt%) material, which has overall a montmorillonite-like chemical composition. This material is partially covered by patches of a thin, dark coating that is sulfate-rich (SO3 ~ 21 wt%) but also contains significant levels of Si, Fe, Ca, and Mg. The simultaneous presence of abundant S, Si, and Fe indicates significant mineralogical complexity within the coating. This combination of vein and coating compositions is unlike previous analyses on Mars. Both materials are heterogeneously eroded, presumably by eolian abrasion. The evidence indicates at least two separate episodes of solute precipitation from aqueous fluids at this location, possibly widely separated in time. In addition to the implications for multiple episodes of alteration at the surface of the planet, aqueous chemical environments such as these would have been habitable at the time of their formation and are also favorable for preservation of organic material.


Special collection papers can be found online at http://www.minsocam.org/MSA/AmMin/special-collections.html.


Acknowledgments

Digital data not presented in numerical form in this paper can be accessed through the NASA Planetary Data System Geosciences Node (http://pds-geosciences.wustl.edu/). We are indebted to NASA for their support, including the Jet Propulsion Laboratory and the many engineers and supporting scientists who have enabled continuation of the highly productive mission and discoveries of the MER Opportunity rover. Early recognition of the potential importance of the boxwork was championed by S.W. Ruff, and we thank him also for comments on an early draft of the manuscript. Bonnie Redding provided invaluable assistance in preparation of numerous products from MI images.

References Cited

Alberti, A., and Brigatti, M.F. (1985) Crystal chemical differences in Al-rich smectites. Clays and Clay Minerals, 33, 546–558.10.1346/CCMN.1985.0330610Suche in Google Scholar

Altheide, T.S., Chevrier, V.F., and Dobrea, E.N. (2010) Mineralogical characterization of acid weathered phyllosilicates with implications for secondary martian deposits. Geochimica et Cosmochimica Acta, 74, 6232–6248, 10.1016/j.gca.2010.08.005.Suche in Google Scholar

Arvidson, R.E., Squyres, S.W., Bell, J.F. III, Catalano, J.G., Clark, B.C., Crumpler, L.S., de Souza, P.A. Jr., Fairén, A.G., Farrand, W.H., Fox, V.K., and others. (2014) Ancient aqueous environments at Endeavour Crater, Mars. Science, 343, 1–8, 10.1126/science.1248097.Suche in Google Scholar PubMed

Arvidson, R.E., Squyres, S.W., Morris, R.V., Knoll, A.H., Gellert, R., Clark, B.C., Catalano, J.G., Jolliff, B.L., McLennan, S.M., Herkenhoff, K.E., and others. (2016) High concentrations of manganese and sulfur in deposits on Murray Ridge, Endeavour Crater, Mars. American Mineralogist, 101, 1389–1405.10.2138/am-2016-5599Suche in Google Scholar

Atkins, T., Overton, T., Rourke, J., Weller, M., and Armstrong, F. (2010) Inorganic Chemistry, 5th ed. Oxford University Press, U.K.Suche in Google Scholar

Bernal, J.D. (1951) The Physical Basis of Life. Routledge and Kegan Paul, London, 364p.Suche in Google Scholar

Blake, D.F., Morris, R.V., Kocurek, G., Morrison, S.M., Downs, R.T., Bish, D., Ming, D.W., Edgett, K.S., Rubin, D., Goetz, W., Madsen, M.B., Sullivan, R., and 400 others. (2013) Curiosity at Gale Crater, Mars: Characterization and analysis of the Rocknest sand shadow. Science, 341, 10.1126/science.1239505.Suche in Google Scholar PubMed

Carter, J., Poulet, F., Bibring, J.-P., Mangold, N., and Murchie, S. (2013) Hydrous minerals on Mars as seen by the CRISM and OMEGA imaging spectrometers: Updated global view. Journal of Geophysical Research: Planets, 118, 831–858, 10.1029/2012JE004145.Suche in Google Scholar

Chan, Y., Van Nostrand, J.D., Zhouc, J., Pointinga, S.B., and Farrell, R.L. (2013) Functional ecology of an Antarctic dry valley. Proceedings of the National Academy of Sciences, 110, 8990–8995, 10.1073/pnas.1300643110.Suche in Google Scholar PubMed PubMed Central

Clark, B.C., and Kounaves, S.P. (2015) Evidence for the distribution of perchlorates on Mars. International Journal of Astrobiology, in press, 10.1017/S1473550415000385.Suche in Google Scholar

Clark, B.C., Morris, R.V., McLennan, S.M., Gellert, R., Jolliff, B., Knoll, A.H., Squyres, S.W., Lowenstein, T.K., Ming, D.W., Tosca, N.J., and others. (2005) Chemistry and mineralogy of outcrop at Meridiani Planum, Mars. Earth and Planetary Science Letters, 240, 73–94.10.1016/j.epsl.2005.09.040Suche in Google Scholar

Clark, B.C., Arvidson, R., Gellert, R., Morris, R.V., Ming, D.W., Richter, L., Ruff, S., Michalski, J., Farrand, W., Herkenhoff, K., and others. (2007) Evidence for montmorillonite or its compositional equivalent in Columbia Hills, Mars. Journal of Geophysical Research, 112, 1–19, 10.1029/2006JE00.Suche in Google Scholar

Clark, B.C., Gellert, R., Arvidson, R.E., Squyres, S.W., Ruff, S.W., Herkenhoff, K.E., Jolliff, B., and Yen, A.S. (2014) Esperance: Extreme aqueous alteration in fracture fills and coatings at Matijevic Hill, Mars. Lunar and Planetary Science Conference, Extended Abstract 1419.Suche in Google Scholar

Cloutis, E.A., Asher, P.M., and Mertzman, S.A. (2002) Spectral reflectance properties of zeolites and remote sensing implications. Journal of Geophysical Research, 107, 10.1029/2000JE001467.Suche in Google Scholar

Dorn, R.I. (1998) Rock coatings (Developments in Earth Surface Processes), 444 pp. Elsevier, Amsterdam.Suche in Google Scholar

Ehlmann, B.L., Mustard, J.F., Murchie, S.L., Bibring, J-P., Meunier, A., Fraeman, A.A., and Langevin, Y. (2011) Subsurface water and clay mineral formation during the early history of Mars. Nature, 479, 53–60.10.1038/nature10582Suche in Google Scholar PubMed

Farrand, W.H., Bell, J.F. III, Johnson, J.R., Squyres, S.W., Soderblom, J., and Ming, D.W. (2006) Spectral variability among rocks in visible and near infrared multispectral Pancam data collected at Gusev Crater: Examinations using spectral mixture analysis and related techniques. Journal of Geophysical Research: Planets, 111, E02S15, 10.1029/2005JE002495.Suche in Google Scholar

Farrand, W.H., Bell, J.F. III, Johnson, J.R., Joliff, B.L., Knoll, A.H., McLennan, S.M., Squyres, S.W., Calvin, W.M., Grotzinger, J.P., Morris, R.V., and others. (2007) Visible and near-infrared multispectral analysis of rocks at Meridiani Planum, Mars by the Mars Exploration Rover Opportunity. Journal of Geophysical Research: Planets, 112, E06S02, 10.1029/2006JE002773.Suche in Google Scholar

Farrand, W.H., Bell, J.F. III, Johnson, J.R., Arvidson, R.E., Crumpler, L.S., Hurowitz, J.A., and Schröder, C. (2008) Rock spectral classes observed by the Spirit rover’s Pancam on the Gusev crater plains and in the Columbia Hills. Journal of Geophysical Research, 113, E12S38, 10.1029/2008JE003237.Suche in Google Scholar

Farrand, W.H., Bell, J.F. III, Johnson, J.R., Rice, M.S., Jolliff, B.L., and Arvidson, R.E. (2014) Observations of rock spectral classes by the Opportunity rover’s Pancam on northern Cape York and on Matijevic Hill, Endeavour Crater, Mars. Journal of Geophysical Research. Planets, 119, 10.1002/2014JE004641.Suche in Google Scholar

Ferris, J.P., Hill, A.R. Jr., Liu, R., and Orgel, L.E. (1996) Synthesis of long prebiotic oligomers on mineral surfaces. Nature, 381, 59–61.10.1038/381059a0Suche in Google Scholar PubMed

Gaines, R.V., Skinner, H.C.W., Foord, E.E., Mason, B., and Rosenzweig, A. (1997) Dana’s New Mineralogy. Wiley, New York.Suche in Google Scholar

Gellert, R., Rieder, R., Anderson, R.C., Brückner, J., Clark, B.C., Dreibus, G., Economou, T., Klingelhöfer, G., Lugmair, G.W., Ming, D.W., and others. (2004) Chemistry of rocks and soils in Gusev Crater from the alpha particle X-ray spectrometer. Science, 305, 829–832.10.1126/science.1099913Suche in Google Scholar PubMed

Gorevan, S.P., Myrick, T.M., Davis, K., Chau, J.J., Bartlett, P., Mukherjee, S., Anderson, R., Squyres, S.W., Arvidson, R.E., Madsen, M.B., and others. (2003) Rock abrasion tool: Mars Exploration Rover mission. Journal of Geophysical Research, 108, E12, p. 9-1–9-8.10.1029/2003JE002061Suche in Google Scholar

Grim, R.E., and Güven, N. (1978) Bentonites: Geology, mineralogy, properties and uses. Elsevier, Amsterdam.Suche in Google Scholar

Grim, R.E., and Kulbicki, G. (1961) Montmorillonite: High temperature reactions and classification. American Mineralogist, 46, 1329–1369.Suche in Google Scholar

Hanczyc, M.M., Fujikawa, S.M., and Szostak, J.W. (2003) Experimental models of primitive cellular compartments: Encapsulation, growth, and division. Science, 302, 618–622, 10.1126/science.1089904.Suche in Google Scholar PubMed PubMed Central

Hashizume, H. (2012) Role of clay minerals in chemical evolution and the origins of life. In M. Valaskova, Ed., Clay Minerals in Nature—Their characterization, modification and application, Chapter 10. InTech, Croatia.10.5772/50172Suche in Google Scholar

Ilton, E.S. (1999) Chromium. In C.P. Marshall and R.W. Fairbridge, Eds., Encyclopedia of Geochemistry. Kluwer, U.K.Suche in Google Scholar

Joshi, P.C., Aldersley, M.F., and Ferris, J.P. (2011) Progress in demonstrating total homochiral selection in montmorillonite-catalyzed RNA synthesis. Biochemical and Biophysical Research Communications, 413, 594–598.10.1016/j.bbrc.2011.09.008Suche in Google Scholar PubMed

Knoll, A.H., Carr, M., Clark, B., Des Marais, D.J., Farmer, J.D., Fischer, W.W., Grotzinger, J.P., McLennan, S.M., Malin, M., Schröder, C., and others. (2005) Astrobiological implications of Meridiani sediments. Earth and Planetary Science Letters, 240, 179–189.10.1016/j.epsl.2005.09.045Suche in Google Scholar

Kounaves, S.P., Carrier, B.L., O’Neil, G.D., Stroble, S.T., and Claire, M.W. (2013) Destruction of organics on Mars by oxychlorines: Evidence from Phoenix, Curiosity, and EETA 79001. European Planetary Science Congress (EPSC) Extended Abstracts, EPSC2013-799.Suche in Google Scholar

Kounaves, S.P., Chaniotakis, N.A., Chevrier, V.F., Carrier, B.L., Folds, K.E., Hansen, V.M., McElhoney, K.M., O’Neil, G.D., and Weber, A.W. (2014) Identification of the perchlorate parent salts at the Phoenix Mars landing site and possible implications. Icarus, 232, 226–231.10.1016/j.icarus.2014.01.016Suche in Google Scholar

Lanza, N.L., Ollila, A.M., Cousin, A., Hardgrove, C., Wiens, R.C., Mangold, N., Nachon, M., Fabre, C., Bridges, N., Johnson, J., and others. (2014) Manganese trends with depth on rock surfaces in Gale Crater, Mars. Lunar and Planetary Science Conference, Extended Abstract 2599.Suche in Google Scholar

Leshin, L.A., Mahaffy, P.R., Webster, C.R., Cabane, M., Coll, P., Conrad, P.G., Archer, P.D., Atreya, S.K., Brunner, A.E., Buch, A., Eigenbrode, J.L., Flesch, G.J., Franz, H.B., Freissinet, C., Glavin, D.P., McAdam, A.C., Miller, K.E., Ming, D.W., and 428 others. (2013) Curiosity Rover volatile, isotope, and organic analysis of Martian fines. Science, 341, 10.1126/science.1238937.Suche in Google Scholar PubMed

Martin M., Hanczyc, S.M., Fujikawa, M., and Szostak, J.W. (2003) Experimental models of primitive cellular compartments: Encapsulation, growth, and division. Science, 302, 618–622.10.1126/science.1089904Suche in Google Scholar PubMed PubMed Central

Ming, D.W., Morris, R.V., and Clark, B.C. (2007) The Martian Surface: Composition, mineralogy, and physical properties. In J.F. Bell III, Ed., The Martian Surface, Cambridge University Press, U.K.Suche in Google Scholar

Morris, R.V., Klingelhöfer, G., Schröder, C., Rodionov, D.S., Yen, A., Ming, D.W., de Souza, P.A. Jr., Fleischer, I., Wdowiak, T., Gellert, R., and others. (2006) Mössbauer mineralogy of rock, soil, and dust at Gusev Crater, Mars: Spirit’s journey through weakly altered olivine basalt on the Plains and pervasively altered basalt in the Columbia Hills. Journal of Geophysical Research, 111, E02S13, 10.1029/2005JE002584.Suche in Google Scholar

Morris, R.V., Klingelhöfer, G., Schröder, C., Fleischer, I., Ming, D.W., Yen, A.S., Gellert, R., Arvidson, R.E., Rodionov, D.S., Crumpler, L.S., and others. (2008) Iron mineralogy and aqueous alteration from Husband Hill through Home Plate at Gusev Crater, Mars: Results from the Mössbauer instrument on the Spirit Mars Exploration Rover. Journal of Geophysical Research, 113, E12S42, 10.1029/2008JE003201.Suche in Google Scholar

Morris, R.V., Ruff, S.W., Gellert, R., Ming, D.W., Arvidson, R.E., Clark, B.C., Golden, D.C., Siebach, K., Klingelhöfer, G., Schröder, C., and others. (2010) Identification of carbonate-rich outcrops on Mars by the Spirit Rover. Science, 329, 421–424.10.1126/science.1189667Suche in Google Scholar PubMed

Myrick, T.M., Bartlett, P., Carlson, L., Chu, P., Davis, K., Chau, J., Powderly, J., and Wilson, J. (2004) The RAT as a rock physical properties tool. AIAA 2004-6096, Space 2004 Conference, San Diego, California, U.S.A.10.2514/6.2004-6096Suche in Google Scholar

Newsom, H.E., Hagerty, J.J., and Thorsos, I.E. (2001) Location and sampling of aqueous and hydrothermal deposits in Martian impact craters. Astrobiology, 1, 71–88.10.1089/153110701750137459Suche in Google Scholar PubMed

NIST (2011) XCOM: Photon Cross Sections Database. NIST Standard Reference Database 8 (XGAM), http://www.nist.gov/pml/data/xcom/.Suche in Google Scholar

Ojha, L., Wilhelm, M.B., Murchie, S.L., McEwen, A.S., Wray, J.J., Hanley, J., Massé, M., and Chojnacki, M. (2015) Spectral evidence for hydrated salts in recurring slope lineae on Mars. Nature Geoscience, 8, 829–832.10.1038/ngeo2546Suche in Google Scholar

Pusch, R., and Yong, R.N. (2005) Microstructure of Smectite Clays and Engineering Performance. CRC Press, Boca Raton, Florida.10.1201/9781482265675Suche in Google Scholar

Rice, M.S., Bell, J.F. III, Cloutis, E.A., Wang, A., Ruff, S.W., Craig, M.A., Baily, D.T., Johnson, J.R., de Souza, P.A. Jr., and Farrand, W.H. (2010) Silica-rich deposits and hydrated minerals at Gusev crater, Mars: Vis-NIR spectral characterization and regional mapping. Icarus, 205, 375–395.10.1016/j.icarus.2009.03.035Suche in Google Scholar

Ross, C.S., and Hendricks, S.B. (1945) Minerals of the montmorillonite group: Their origin and relation to soils and clays. U.S. Geological Survey Professional Paper 205B.10.3133/pp205BSuche in Google Scholar

Summons, R.E., Amend, J.P., Bish, D., Buick, R., Cody, G.D., Des Marais, D.J., Dromart, G., Eigenbrode, J.L., Knoll, A.H., and Sumner, D.Y. (2011) Preservation of martian organic and environmental records: Final Report of the Mars Biosignature Working Group. Astrobiology, 11, 157–181.10.1089/ast.2010.0506Suche in Google Scholar PubMed

Velbel, M.A. (2012) Aqueous alteration in Martian meteorites: Comparing mineral relations in igneous-rock weathering of Martian meteorites and in the sedimentary cycle of Mars. In J. Grotzinger and R. Milliken, Eds., Sedimentary Geology of Mars, SEPM. Society for Sedimentary Geology Special Publication 102, 97–117.10.2110/pec.12.102.0097Suche in Google Scholar

Wang, A., Bell, J.F., Li, R., Johnson, J.R., Farrand, W.H., Cloutis, E.A., Arvidson, R.E., Crumpler, L., Squyres, S.W., McLennan, S.M., Herkenhoff, K.E., Ruff, S.W., Knudson, A.T., Chen, W., and Greenberger, R. (2008) Light-toned salty soils and coexisting Si-rich species discovered by the Mars Exploration Rover Spirit in Columbia Hills. Journal of Geophysical Research, 113, E12S40, http://doi.org/10.1029/2008JE003126.Suche in Google Scholar

Wray, J.J., Murchie, S.L., Squyres, S.W., Seelos, F.P., and Tornabene, L.L. (2009) Diverse aqueous environments on ancient Mars revealed in the southern highlands. Geology, 37, 1043–1046.10.1130/G30331A.1Suche in Google Scholar

Yen, A.S., Gellert, R., Schröder, C., Morris, R.V., Bell, J.F., Knudson, A.T., Clark, B.C., Ming, D.W., Crisp, J.A., Arvidson, R.E., and others. (2005) An integrated view of the chemistry and mineralogy of martian soils. Nature, 436, 49–54.10.1038/nature03637Suche in Google Scholar PubMed

Yen, A.S., Morris, R.V., Clark, B.C., Gellert, R., Knudson, A.T., Squyres, S., Mittlefehldt, D.W., Ming, D.W., Arvidson, R., McCoy, T., and others. (2008) Hydrothermal processes at Gusev crater: An evaluation of Paso Robles class soils. Journal of Geophysical Research, 113, E06S10.10.1029/2007JE002978Suche in Google Scholar

Received: 2015-10-1
Accepted: 2016-2-16
Published Online: 2016-7-7
Published in Print: 2016-7-1

© 2016 by Walter de Gruyter Berlin/Boston

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