Abstract
The Apollo 14 high-Al basalt, 14053, is the most reduced lunar rock examined to date. Both fayalite in the mesostasis and spinel minerals have been extensively reduced in the exterior of the rock, whereas the interior contains relatively limited reduction. It is shown that these products are the effects of solar-wind hydrogen that was implanted on the exterior of the .normal. 14053 basalt after it originally crystallized and was weathered to become part of the regolith. Subsequent reheating, probably in an impact-ejecta blanket, caused extreme subsolidus hydrogen reduction, particularly of the weathered exterior of this rock. The limited permeability of the rock prevented the entire rock from being subjected to the same degree of reduction. It is proposed that this extreme reduction, especially of the mesostasis, also affected the phosphate minerals, F-Cl apatite and merrillite, each of which vary greatly in REE contents. This effect on the phosphate minerals could relate to the upset Sm-Nd radiogenetic systematics, whereas the Rb-Sr system may have been largely immune to the subsolidus reduction.
© 2015 by Walter de Gruyter Berlin/Boston
Articles in the same Issue
- First-principle study of polytype structures of 1:1 dioctahedral phyllosilicates
- Calorimetry of liquids in the system Na2O-Fe2O3-SiO2
- A Mössbauer study of the oxidation state of Fe in silicate melts
- Nanometer-scale measurements of Fe3+/ΣFe by electron energy-loss spectroscopy: A cautionary note
- The most reduced rock from the moon, Apollo 14 basalt 14053: Its unique features and their origin
- Quantitative analysis of ammonium in biotite using infrared spectroscopy
- Lizardite-chlorite structural relationships and an inferred high-pressure lizardite polytype
- V oxidation state and coordination number in silicate glasses by XAS
- Structure of the fluorapatite (100)-water interface by high-resolution X-ray reflectivity
- Origin of diffuse superstructure reflections in labuntsovite-group minerals
- Isosymmetric structural phase transition of orthoenstatite: Molecular dynamics simulation
- Crystal nucleation in hydrous rhyolite: Experimental data applied to classical theory
- Investigation of polytypes in lepidolite using electron back-scattered diffraction
- Iron partitioning between basaltic melts and clinopyroxene as a function of oxygen fugacity
- The synthesis of zeolite-P, Linde Type A, and hydroxysodalite zeolites from paper sludge ash at low temperature (80 °C): Optimal ash-leaching condition for zeolite synthesis
- High-pressure viscometry of polymerized silicate melts and limitations of the Eyring equation
- Biological control on calcite crystallization: AFM investigation of coccolith polysaccharide function
- Order parameter variation through the C2/m-P21/m phase transition in cummingtonite
- Arsenate sorption on schwertmannite
- Evidence on the structure of synthetic schwertmannite
- Crystal-chemical characterization of tourmalines from the English Lake District: Electron-microprobe analyses and Mössbauer spectroscopy
- Crystal chemistry and paragenesis of compositionally unique (Al-, Fe-, Nb-, and Zr-rich) titanite from Afrikanda, Russia
- Site distribution of Fe2+and Fe3+in the axinite mineral group: New crystal-chemical formula
- Epidote-rich talc-kyanite-phengite eclogites, Sulu terrane, eastern China: P-T-fO₂estimates and the significance of the epidote-talc assemblage in eclogite
- Quantitative mineralogy of the Yukon River system: Changes with reach and season, and determining sediment provenance
- Exsolution of thortveitite, yttrialite, and xenotime during low-temperature recrystallization of zircon from New Caledonia, and their significance for trace element incorporation in zircon
- Mineralogical characterization and genesis of hydrothermal Mn oxides from the flank of the Juan the Fuca Ridge
- Synchrotron X-ray diffraction study of the structure of shafranovskite, K2Na3(Mn,Fe,Na)4[Si9(O,OH)27](OH)2⋅nH2O, a rare manganese phyllosilicate from the Kola peninsula, Russia
- Letter. Coupled cation and oxygen-isotope exchange between alkali feldspar and aqueous chloride solution
Articles in the same Issue
- First-principle study of polytype structures of 1:1 dioctahedral phyllosilicates
- Calorimetry of liquids in the system Na2O-Fe2O3-SiO2
- A Mössbauer study of the oxidation state of Fe in silicate melts
- Nanometer-scale measurements of Fe3+/ΣFe by electron energy-loss spectroscopy: A cautionary note
- The most reduced rock from the moon, Apollo 14 basalt 14053: Its unique features and their origin
- Quantitative analysis of ammonium in biotite using infrared spectroscopy
- Lizardite-chlorite structural relationships and an inferred high-pressure lizardite polytype
- V oxidation state and coordination number in silicate glasses by XAS
- Structure of the fluorapatite (100)-water interface by high-resolution X-ray reflectivity
- Origin of diffuse superstructure reflections in labuntsovite-group minerals
- Isosymmetric structural phase transition of orthoenstatite: Molecular dynamics simulation
- Crystal nucleation in hydrous rhyolite: Experimental data applied to classical theory
- Investigation of polytypes in lepidolite using electron back-scattered diffraction
- Iron partitioning between basaltic melts and clinopyroxene as a function of oxygen fugacity
- The synthesis of zeolite-P, Linde Type A, and hydroxysodalite zeolites from paper sludge ash at low temperature (80 °C): Optimal ash-leaching condition for zeolite synthesis
- High-pressure viscometry of polymerized silicate melts and limitations of the Eyring equation
- Biological control on calcite crystallization: AFM investigation of coccolith polysaccharide function
- Order parameter variation through the C2/m-P21/m phase transition in cummingtonite
- Arsenate sorption on schwertmannite
- Evidence on the structure of synthetic schwertmannite
- Crystal-chemical characterization of tourmalines from the English Lake District: Electron-microprobe analyses and Mössbauer spectroscopy
- Crystal chemistry and paragenesis of compositionally unique (Al-, Fe-, Nb-, and Zr-rich) titanite from Afrikanda, Russia
- Site distribution of Fe2+and Fe3+in the axinite mineral group: New crystal-chemical formula
- Epidote-rich talc-kyanite-phengite eclogites, Sulu terrane, eastern China: P-T-fO₂estimates and the significance of the epidote-talc assemblage in eclogite
- Quantitative mineralogy of the Yukon River system: Changes with reach and season, and determining sediment provenance
- Exsolution of thortveitite, yttrialite, and xenotime during low-temperature recrystallization of zircon from New Caledonia, and their significance for trace element incorporation in zircon
- Mineralogical characterization and genesis of hydrothermal Mn oxides from the flank of the Juan the Fuca Ridge
- Synchrotron X-ray diffraction study of the structure of shafranovskite, K2Na3(Mn,Fe,Na)4[Si9(O,OH)27](OH)2⋅nH2O, a rare manganese phyllosilicate from the Kola peninsula, Russia
- Letter. Coupled cation and oxygen-isotope exchange between alkali feldspar and aqueous chloride solution