Composition of synthetic tremolite-tschermakite solid solutions in amphibole + anorthiteand amphibole + zoisite-bearing assemblages
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Jens Najorka
,
Matthias Gottschalk
Abstract
The composition of synthetic amphiboles was investigated experimentally along the tremolitetschermakite join in the system CaO-MgO-Al2O3-SiO2-H2O-Br2. Compositions of these amphiboles were studied within the phase assemblages: amphibole-anorthite-quartz-diopside (I), amphiboleanorthite- quartz-talc (II), amphibole-anorthite-quartz-enstatite (III), amphibole-anorthite-talcclinochlore (IV), amphibole-zoisite-talc-quartz (V), and amphibole-zoisite-talc-clinochlore (VI). Assemblages were synthesized from oxide-hydroxide mixtures in the presence of a CaBr2-bearing solution between 600-800 °C and 200-2000 MPa. Solid phases were investigated using SEM, HRTEM, EMP, and XRD techniques. EMP data show that the amphiboles produced are solid solutions of the ternary system tremolite-tschermakite-cummingtonite. Enstatite, diopside, talc, and clinochlore showed small deviations from their respective end-member compositions due to incorporation of some Al.
The thermodynamic properties of the tschermakite end-member and the mixing properties along the tremolite-tschermakite join were extracted from corresponding exchange reactions of the unreversed synthesized phase assemblages I-VI. Various ideal mixing models were tested for Al-Mg and Al-Si substitution at octahedral M2 and M3 sites and at tetrahedral T1-sites. Best fits were obtained for a two-site coupled model, resulting in ΔfH0ts = -12528.3 ± 11.7 kJ/mol and S0ts = 556.5 ± 12.0 J/(mol·K) for the tschermakite end-member. Similar calculations were carried out for magnesiohornblende, and values of ΔfH0Mghb = -12418.7 ± 5.9 kJ/mol and S0Mghb = 562.8 ± 6.1 J/(mol·K) were extracted. Calculated phase relations and amphibole compositions agree well with experimental data if the derived thermodynamic data of tschermakite and a two-site mixing model for Al incorporation in amphibole solid solutions are applied.
© 2015 by Walter de Gruyter Berlin/Boston
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Artikel in diesem Heft
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- Local equilibrium in polymetamorphic gneiss and the titanium substitution in biotite
- The enthalpy of formation and internally consistent thermodynamic data of Mg-staurolite
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- Stability of corundum + quartz relative to kyanite and sillimanite at high temperature and pressure
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