Thermodynamic and structural behavior of analcime–leucite analogue systems
-
Guy L. Hovis
,
Jacques Roux
Abstract
Two synthetic solid-solution series, analcime to Rb-leucite and analcime to Cs-leucite (pollucite), have been investigated to understand more fully the thermodynamic and structural behavior of analcime- leucite and similar mineral systems. Unit-cell dimensions and volumes in these series expand with the substitution of analcime component in either Rb-leucite or pollucite, as H2O molecules structurally replace the smaller entities Rb+1 or Cs+1, respectively. Unit-cell volumes vary linearly as functions of composition, but with changing slopes over several segments of compositional space, akin to thermal expansion in K-, Rb-, and Cs-end-member materials studied by previous workers. When symmetry changes displacively from tetragonal to isometric, as in the Rb-bearing series, the slope of volume expansion changes. Once structures have reached full expansion, volume slopes flatten and are little affected by additional analcime component. Enthalpies of solution measured at 50 °C in 20.1 wt% hydrofluoric acid show single-slope linear relationships over the entire compositional ranges of both series. Thus, despite positive volumes of mixing, there are no enthalpies of mixing in either series, nor is there energetic evidence of displacive tetragonal/isometric inversion or the various stages of structural expansion. Overall, the data suggest that the analcime-leucite system also can be modeled as close to thermodynamically ideal. The limited solid solution between natural analcime and leucite must be attributed to energetically favored heterogeneous equilibria involving minerals such as feldspars and other feldspathoids, and not to immiscibility between the end-members.
© 2015 by Walter de Gruyter Berlin/Boston
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Articles in the same Issue
- Titanium in biotite from metapelitic rocks: Temperature effects, crystal-chemical controls, and petrologic applications
- Local equilibrium in polymetamorphic gneiss and the titanium substitution in biotite
- The enthalpy of formation and internally consistent thermodynamic data of Mg-staurolite
- Coexisting andalusite, kyanite, and sillimanite: Sequential formation of three Al2SiO5 polymorphs during progressive metamorphism near the triple point, Sivrihisar, Turkey
- Co-existing aluminum silicates in quartz veins: A quantitative approach for determining andalusite-sillimanite equilibrium in natural samples using oxygen isotopes
- Stability of corundum + quartz relative to kyanite and sillimanite at high temperature and pressure
- Andalusite-sillimanite replacement (Mazarrón, SE Spain): A microstructural and TEM study
- Hydroxyl-rich topaz in high-pressure and ultrahigh-pressure kyanite quartzites, with retrograde woodhouseite, from the Sulu terrane, eastern China
- Coesite exsolution from supersilicic titanite in UHP marble from the Kokchetav Massif, northern Kazakhstan
- Composition of synthetic tremolite-tschermakite solid solutions in amphibole + anorthiteand amphibole + zoisite-bearing assemblages
- Paragenesis and thermobarometry of Ca-amphiboles in the Barcroft granodioritic pluton, central White Mountains, eastern California
- B and Li in Proterozoic metapelites from the Black Hills, U.S.A.: Implications for the origin of leucogranitic magmas
- The role of Fe and cation order in the crystal chemistry of surinamite, (Mg,Fe2+)3(Al,Fe3+)3O[AlBeSi3O15]: A crystal structure, Mössbauer spectroscopic, and optical spectroscopic study
- Fe3+ and Fe2+ partitioning among silicates in metapelites: A synchrotron micro-XANES study
- Thermodynamic and structural behavior of analcime–leucite analogue systems
- In-situ synchrotron study of the kinetics, thermodynamics, and reaction mechanisms of the hydrothermal crystallization of gyrolite, Ca16Si24O60(OH)8·14H2O
- The crystal structures of grossular and spessartine between 100 and 600 K and the crystal chemistry of grossular-spessartine solid solutions
- The structures of becquerelite and Sr-exchanged becquerelite
- Elasticity and equation of state of orthoenstatite, MgSiO3
- Reidite: An impact-produced high-pressure polymorph of zircon found in marine sediments
- A new polymorph of eucryptite (LiAlSiO4), ε-eucryptite, and thermal expansion of α- and ε-eucryptite at high pressure
- Disordering during melting: An 17O NMR Study of crystalline and glassy CaTiSiO5 (titanite)
- Characterization of Mn oxides in cemented streambed crusts from Pinal Creek, Arizona, U.S.A., and in hot-spring deposits from Yuno-Taki Falls, Hokkaido, Japan
