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Co-existing aluminum silicates in quartz veins: A quantitative approach for determining andalusite-sillimanite equilibrium in natural samples using oxygen isotopes
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Aaron J. Cavosie
,
Zachary D. Sharp
Published/Copyright:
March 28, 2015
Abstract
Massive quartz veins with large andalusite and sillimanite crystals in textural equilibrium were found in a Proterozoic province in the northern Colorado Front Range. The d18O values of the andalusite and sillimanite are identical, supporting the idea that these aluminum-silicate (AS) polymorphs crystallized at the same time. These data are consistent with the findings of Sharp (1995), who reported no fractionation associated with polymorphism of the aluminum silicates. Quartz-aluminum- silicate fractionations from veins in textural equilibrium and disequilibrium are 2.63-2.93 and 2.20-2.25‰, respectively. Temperature estimates from quartz-aluminum-silicate oxygen isotope fractionations range from 603-652 °C for equilibrium veins, and geologically unreasonable temperatures of 728-788 °C from veins in textural disequilibrium. Formation temperatures determined from isotope thermometry constrain the location of the veins on the andalusite = sillimanite univariant curve, thus defining a pressure range of 1.2-2.6 kbar for vein formation. The vein P-T estimates from this study agree well with previous host rock P-T estimates from nearby localities and, in conjunction with available Ar thermochronology, indicate that the veins likely formed during a Mesoproterozoic magmatic event in the Colorado Front Range.
Received: 2001-5-7
Accepted: 2001-12-6
Published Online: 2015-3-28
Published in Print: 2002-4-1
© 2015 by Walter de Gruyter Berlin/Boston
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Articles in the same Issue
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