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Time Necessary for Reaching Chemical Equilibrium: First Passage Time Approach
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M. Solc
Published/Copyright:
September 25, 2009
The time necessary for reaching the macroscopic chemical equilibrium is defined as the time of first passage of system composition into the state of exact chemical equilibrium. The exact and approximate formulas for the first passage time in the case of reversible first order reaction with an arbitrary value of equilibrium constant are derived.
Published Online: 2009-09-25
Published in Print: 2000-02
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Articles in the same Issue
- A Dielectric Relaxation Study of Lithium Salt Solutions in Dimethylsulfoxide
- Quantitative Determination of Photokinetic Parameters for Reversible Photoisomerizations in Light Scattering Adsorbent-Adsorbates
- Studies on Hydrogen Bond Formation of Papaverine and Pentazocine
- Reaction between 8-Hydroxyquinoline and Salicylic Acid in Solid State and Solution
- Particle Entropies and Entropy Quanta. I. The Ideal Gas
- Dynamical and Quantumchemical Characteristics of Electronic Charge Density Transfer Processes
- Raman Spectroscopic Studies of Scandium(III) Hydration in Aqueous Solution - about the First Hydration Sphere of Sc(III) in Solution
- T,p-Dependence of Self-Diffusion in the Lower N-methylsubstituted Amides
- Time Necessary for Reaching Chemical Equilibrium: First Passage Time Approach
