Reaction between 8-Hydroxyquinoline and Salicylic Acid in Solid State and Solution
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N.B. Singh
8-Hydroxyquinoline reacts with salicylic acid both in solid state and solution forming a yellow coloured compound. Phase diagram studies have shown the formation of a 1:1 addition compound stable in solid state and dissociated in solution. Differential thermal studies have shown that the reaction products obtained from solution and solid state reaction are almost identical except that there is a possibility of entrapped solvent molecules when the product was prepared from benzene. Also the reaction product shows a thermochromic effect. X-ray diffraction studies have revealed some structural difference between the reaction product obtained from solution and solid state reaction. Spectroscopic studies show the possibility of hydrogen bonding in the reaction product.
The reaction in the solid state is slow and once a thin layer of reaction product is formed at the surface of salicylic acid crystals, the reaction rate becomes practically negligible. This may be due to the compactness of the product layer and unfavourable crystal packing in to the crystal lattice of salicylic acid. Microstructural studies have shown that there are structural changes during solid state reaction.
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- Studies on Hydrogen Bond Formation of Papaverine and Pentazocine
- Reaction between 8-Hydroxyquinoline and Salicylic Acid in Solid State and Solution
- Particle Entropies and Entropy Quanta. I. The Ideal Gas
- Dynamical and Quantumchemical Characteristics of Electronic Charge Density Transfer Processes
- Raman Spectroscopic Studies of Scandium(III) Hydration in Aqueous Solution - about the First Hydration Sphere of Sc(III) in Solution
- T,p-Dependence of Self-Diffusion in the Lower N-methylsubstituted Amides
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Articles in the same Issue
- A Dielectric Relaxation Study of Lithium Salt Solutions in Dimethylsulfoxide
- Quantitative Determination of Photokinetic Parameters for Reversible Photoisomerizations in Light Scattering Adsorbent-Adsorbates
- Studies on Hydrogen Bond Formation of Papaverine and Pentazocine
- Reaction between 8-Hydroxyquinoline and Salicylic Acid in Solid State and Solution
- Particle Entropies and Entropy Quanta. I. The Ideal Gas
- Dynamical and Quantumchemical Characteristics of Electronic Charge Density Transfer Processes
- Raman Spectroscopic Studies of Scandium(III) Hydration in Aqueous Solution - about the First Hydration Sphere of Sc(III) in Solution
- T,p-Dependence of Self-Diffusion in the Lower N-methylsubstituted Amides
- Time Necessary for Reaching Chemical Equilibrium: First Passage Time Approach
